Novel Furanoid α-Substitued α-Amino Acid as a Potent Turn Mimic in Peptide Synthesis
A stereoselective approach has been developed to the new sugar amino acid and potential potent turn mimic 5-O-(tert-butyldimethylsilyl)-3-deoxy-1,2-O- isopropylidene-3-methoxycarbonylamino-α-D-xylofuranose 3-C-carboxylic acid (12), via the [3,3 ...
Jana Raschmanová +2 more
doaj +1 more source
Copper and gold cyclic (alkyl)(amino)carbene complexes with sub-microsecond photoemissions: Structure and substituent effects on redox and luminescent properties [PDF]
Copper and gold halide and pseudo-halide complexes stabilized by methyl-, ethyl- and adamantyl-substituted cyclic (alkyl)(amino)¬carbene (CAAC) ligands are mostly linear monomers in the solid state, without aurophilic Au···Au interactions.
Back +64 more
core +1 more source
Synthesis, Characterization and Antibacterial Properties of Complex [Ag(SCN)(2-NH2py)] [PDF]
The reaction of AgSCN with 2-aminopyridine in ammonia solution produces the colorless crystal of catena-poly [Ag(SCN))(C6H5N2)]n. The crystals were characterized by FTIR analysis and single crystal X-Ray diffraction.
Mariyam Dewi +3 more
doaj +1 more source
Taste and flavour perceptions of glucosinolates, isothiocyanates, and related compounds [PDF]
Brassicaceae plants are renowned for their taste, aroma and trigeminal characteristics; predominantly bitter taste, sulfurous aroma and pungency. Compounds responsible for these sensations include the glucosinolates (GSLs) and their hydrolysis products ...
Abe +111 more
core +1 more source
To Cut the Mustard: Antimicrobial Activity of Selenocyanates on the Plate and in the Gas Phase
Organic selenocyanates (RSeCN) are among the most reactive and biologically active Se species, often exhibiting a pronounced cytotoxic activity against mammalian cells and microorganisms. Various aromatic selenocyanates have been synthesized and, similar
Muhammad Sarfraz +4 more
doaj +1 more source
Synthesis and reactivity of half-sandwich (η 5 -C 5 Me 5 )Ir(iii) complexes of a cyclometallated aryl phosphine ligand [PDF]
Reaction of the Ir(iii) dimer [(η 5 -C 5 Me 5 )IrCl 2 ] 2 with PMeXyl 2 (Xyl = 2,6-C 6 H 3 Me 2 ), in the presence of the poorly coordinating base 2,2,6,6-tetramethyl piperidine, gives a chloride complex 1-Cl, resulting from hydrogen chloride elimination
Campos Manzano, Jesús +2 more
core +1 more source
In the title compound, [Cd(NCS)2(C11H17N3)]n, the CdII atom is octahedrally coordinated by the N,N′,N′′-tridentate Schiff base ligand and one terminal thiocyanate N atom.
Nura Suleiman Gwaram +2 more
doaj +1 more source
Synthesis and biological evaluation of novel urea and thiourea derivatives of valacyclovir [PDF]
A series of novel urea and thiourea derivatives of valacyclovir were efficiently synthesized in high yields and evaluated their antiviral activity.
Katla Ramana Venkata +4 more
doaj +1 more source
Extracting accurate infrared lineshapes from weak vibrational probes at low concentrations
Fourier-transform infrared (FTIR) spectroscopy using vibrational probes is an ideal tool to detect changes in structure and local environments within biological molecules.
Raiza N.A. Maia +2 more
doaj +1 more source
THE IMPACT OF COAL WASTE HEAPS ON THE ENVIRONMENT OF SOKAL DISTRICT OF LVIV REGION [PDF]
The environmental situation in Sokal district is one of the most complicated in Lviv region, which is caused by man-made environmental impact of mining, coal preparation and chemical industries.
Popovych, Vasyl, Voloshchyshyn, Andriy
core

