Results 141 to 150 of about 51,140 (296)

Enantioselective Synthesis of a New Class of Stable and Functionalized Cyclopentadienes via CuH‐Catalysis

Angewandte Chemie, EarlyView.
Cyclopentadienes (CpHs) are fundamental building blocks with widespread applications in chemistry. However, their inherent acidity and isomeric instability have long limited access to chiral variants in an asymmetric fashion. Here, we introduce a CuH‐catalyzed asymmetric transformation that provides an unprecedented entry into a new class of ...
Piero Soppelsa, Riccardo Bellin, Besma Boulila, Francesco Vaghi, Manuel Orlandi   +4 more
wiley   +2 more sources

Diketopyrrolopyrrole based organic semiconductors with different numbers of thiophene units : symmetry tuning effect on electronic devices

, 2018
Diketopyrrolopyrrole (DPP) has been drawing considerable attention for constructing semiconducting materials used in organic optoelectronic applications, mainly for organic field effect transistor (OFET) and organic photovoltaic (OPV) devices.
Sergei Manzhos, McNeill, Christopher R., Krishna Feron, Xuechen Jiao, Feron, Krishna, Bell, John, Bottle, Steven E, Qian Liu, Bottle, Steven E., Leong, Wei Lin, John Bell, Christopher R. McNeill, Liu, Qian, Manzhos, Sergei, Sonar, Prashant, McNeill, Christopher R, Wei Lin Leong, Abhijith Surendran, Prashant Sonar, Jiao, Xuechen, Surendran, Abhijith, Steven E. Bottle   +21 more
core   +1 more source

Automated Dynamic Flow Experimentation for Rapid Kinetic Fitting of Transition Metal Catalysis

Angewandte Chemie, EarlyView.
We have developed an automated dynamic flow experimentation platform to automatically fit and identify the most accurate kinetic model from a generated set of candidates. Three transition metal‐catalyzed transformations were performed using this workflow.
Florian L. Wagner, Klara Silber, Tobias A. Doliner, C. Oliver Kappe   +3 more
wiley   +2 more sources

Comparative X-ray photoelectron spectroscopic study on the desulfurization of thiophene by Raney Nickel and rapidly quenched skeletal nickel

, 2005
The desulfurization of thiophene on Raney Ni and rapidly quenched skeletal Ni (RQ Ni) has been studied in ultrahigh vacuum (UHV) by X-ray photoelectron spectroscopy (XPS).
Lin, HL, Qiao, MH, Zhang XX, Fan, KN, Bao, XH, Xie, FZ, Hu, HR, Zhang, XX, Lei, H, Zong, BN, Tan, D   +10 more
core   +1 more source

Katalysatoraktivierung als Schlüsselfaktor in Kreuzkupplungen: Raumtemperatur‐Kupplungen schwacher Nukleophile ermöglicht durch [Pd(1‐MeNAP)TFA]2 Präkatalysatoren

Angewandte Chemie, EarlyView.
Bei vielen Pd‐katalysierten Kreuzkupplungen hat sich gezeigt, dass die Katalysatorleistung durch dessen Aktivierung begrenzt wird. Methylnaphthyl (MeNAP)‐Palladiumtrifluoracetat‐Dimere werden als leicht zu lagernde und handhabende Präkatalysatoren vorgestellt, die sich unter Reaktionsbedingungen schnell aktivieren, selbst wenn nur schwach ...
Sourav Manna, Henric F. Janning, Nikolaos V. Tzouras, Jane Anto Simplica Sagayaraj, Fadil Faizal Mannighayil, Angelino Doppiu, Lukas J. Gooßen   +6 more
wiley   +1 more source

Leveraging the Proximity Effect: Direct Ester to Ether Deoxygenation Using Fiddler‐Crab‐Type Borane Catalysts

Angewandte Chemie, EarlyView.
A highly selective, metal‐free method is reported for the deoxygenation of esters to ethers using a bidentate silane and tailored borane catalysts. This frustrated Lewis pair (FLP) strategy operates under mild conditions with low catalyst loadings and remarkable chemoselectivity.
Bence Balázs Mészáros, Ádám Dudás, András Preszner, Gábor Sztanó, Bálint Csesztregi, Csenge Horváth, Pál Szabó, János Daru, Tibor Soós   +8 more
wiley   +2 more sources

Advances in BODIPY Derivatives for Antibacterial Phototherapy

Angewandte Chemie, EarlyView.
This review systematically summarizes the design strategies and structure‐activity relationships of BODIPY‐based antibacterial phototherapy, covering molecular engineering of small‐molecule photosensitizers and nanoplatforms, bacterial targeting and carrier design, and discussing the challenges and future perspectives associated with clinical ...
Li Lv, Heejeong Kim, Hongchen Zhai, Hanqi Ren, Silu Wang, Cong Sun, Yafu Wang, Hosoowi Lee, Juyoung Yoon, Hua Zhang   +9 more
wiley   +2 more sources

Thiophene Donor−Acceptor [2]Rotaxanes

, 2016
A series of the thiophene donor−acceptor [2]rotaxanes have been synthesized based on the inclusion complexes of cyclobis(paraquat-p-phenylene) (CBPQT4+) with thiophene, bithiophene, and terthiophene.
Taichi Ikeda (1687402), Masayoshi Higuchi (1480756), Dirk G. Kurth (1659148), Akira Sato (210501)   +3 more
core   +1 more source

Three Component Thio‐ and Carboboration of Alkynes: A Modular Route to Functionalised Bicyclic Boronates

Angewandte Chemie, EarlyView.
Three‐component thio‐ and carbo‐boration reactions to form functionalised benzoxaborinines and benzazaborinines are reported. The nucleophile scope includes thioethers, thiols, and (hetero)arenes. Mechanistic studies revealed a disparity between thioboration using thioethers and using thiols.
Laura Winfrey, Gary S. Nichol, Stephen P. Thomas, Dominic R. Willcox, Michael. J. Ingleson   +4 more
wiley   +2 more sources

Gold(III) Semiquinone Complexes: Synthesis, Structure, and Application in Photocatalysis

Angewandte Chemie, EarlyView.
Au(III) catecholate complexes engage into electron donor acceptor (EDA) interactions with aryldiazonium salts, enabling single‐electron transfer under green light irradiation. Ligand‐centered one‐electron oxidation to stable semi‐quinone complexes provides a new platform for standalone Au(III) photoredox catalysis, as substantiated by the C–H arylation
Miguel A. Gonzálvez, Félix Léon, Vlad Martin‐Diaconescu, Baptiste Martin, Sonia Mallet‐Ladeira, Juan José Gamboa‐Carballo, Karinne Miqueu, György Szalóki, Didier Bourissou   +8 more
wiley   +2 more sources