Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application
Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley +1 more source
2-(Methoxycarbonyl)thiophen-3-yl-diazonium Salts: Efficient Precursors for the Formation of C-C Bonds in Thiophene-Containing Heterocyclic Systems. [PDF]
Ostapiuk YV +5 more
europepmc +1 more source
Mechanochemical Hydrodeoxygenations
A silver‐catalyzed mechanochemical hydrodeoxygenation with triethylsilane as reductant allows to convert ketones to the corresponding methylene derivatives in good yields after a short reaction time. Selected examples show that also alcohols, ethers, and sulfoxides can react. In this work, a mechanochemical hydrodeoxygenation (HDO) was developed. Using
Lena M. Hanek, Carsten Bolm
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Resonator-based add-drop filters enabled by flexible polymorphic crystals with TADF-RTP motifs. [PDF]
Pattanayak P +8 more
europepmc +1 more source
This work describes the synthesis of lactose‐ and glucose‐derived chiral ligands and their application in the catalytic enantioselective Friedel–Crafts alkylation of indole with a series of trans‐β‐nitrostyrenes. The optimal ligand was an acetate protected, lactose‐derived pyridyl imine and its zinc complex afforded ees up to 93% and yields up to 93 ...
Sandra Bulawa +2 more
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Thiophene Esters Are Not Selective for H2S and Undergo Thiol and Esterase Cleavage. [PDF]
Smith HM +4 more
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Photochemical Decatungstate‐Catalyzed Hydroacylation of Maleimides
A photocatalytic protocol to access substituted succinimides via tetra‐n‐butylammonium decatungstate photocatalysis is reported. This direct radical‐driven hydroacylation of a variety of N‐substituted maleimides shows tolerance to various aldehydes (or alkanes), affording differentially substituted succinimides in high yields. Succinimides constitute a
Manos V. G. Lantzanakis +2 more
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Photoactive Thiophene-Enriched Tetrathienonaphthalene-Based Covalent Organic Frameworks. [PDF]
Xue T +11 more
europepmc +1 more source
The one‐pot synthesis of 3‐benzylidenbenzo[c]thiophen‐1‐amines was achieved through the nickel‐catalyzed three‐component coupling reaction of 1‐ethynyl‐2‐iodobenzenes, tert‐butyl isocyanide, and hexamethyldisilathiane. This procedure is applicable to the preparation of secondary thioamides using aryl iodides.
Norio Sakai +4 more
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Decoding the Role of Porosity and N,S-Doping in Covalent Triazine Framework-Derived Carbons and Their Carbon Nano-Onion Hybrids for Superior Supercapacitors. [PDF]
Kolodziejczyk J +5 more
europepmc +1 more source

