Results 211 to 220 of about 38,014 (298)

Syntheses of Thiophene Derivatives. I

open access: yesYAKUGAKU ZASSHI, 1953
Tetsuji Kametani, Yoshiro Akazawa
openaire   +2 more sources

Mechanochemical Hydrodeoxygenations

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A silver‐catalyzed mechanochemical hydrodeoxygenation with triethylsilane as reductant allows to convert ketones to the corresponding methylene derivatives in good yields after a short reaction time. Selected examples show that also alcohols, ethers, and sulfoxides can react. In this work, a mechanochemical hydrodeoxygenation (HDO) was developed. Using
Lena M. Hanek, Carsten Bolm
wiley   +1 more source

Design and Synthesis of Lactose‐Derived Ligands and Their Application in Asymmetric Friedel–Crafts Alkylation

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This work describes the synthesis of lactose‐ and glucose‐derived chiral ligands and their application in the catalytic enantioselective Friedel–Crafts alkylation of indole with a series of trans‐β‐nitrostyrenes. The optimal ligand was an acetate protected, lactose‐derived pyridyl imine and its zinc complex afforded ees up to 93% and yields up to 93 ...
Sandra Bulawa   +2 more
wiley   +1 more source

Photochemical Decatungstate‐Catalyzed Hydroacylation of Maleimides

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A photocatalytic protocol to access substituted succinimides via tetra‐n‐butylammonium decatungstate photocatalysis is reported. This direct radical‐driven hydroacylation of a variety of N‐substituted maleimides shows tolerance to various aldehydes (or alkanes), affording differentially substituted succinimides in high yields. Succinimides constitute a
Manos V. G. Lantzanakis   +2 more
wiley   +1 more source

Nickel‐Catalyzed Three‐Component Coupling Reactions of Iodobenzenes, an Isocyanide, and a Disilathiane: Access to Cyclic Thioimidates and Secondary Thioamides

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The one‐pot synthesis of 3‐benzylidenbenzo[c]thiophen‐1‐amines was achieved through the nickel‐catalyzed three‐component coupling reaction of 1‐ethynyl‐2‐iodobenzenes, tert‐butyl isocyanide, and hexamethyldisilathiane. This procedure is applicable to the preparation of secondary thioamides using aryl iodides.
Norio Sakai   +4 more
wiley   +1 more source

Antibacterial Hydrogel Dressing With Ca2+‐Dependent Hyaluronidase Responsiveness for Accelerating Wound Healing via On‐Demand Release of AIE Photosensitizers

open access: yesExploration, EarlyView.
This study innovates a Ca2+‐responsive hydrogel dressing that releases AIE photosensitizers on‐demand. Low Ca2+ enhances bacterial hyaluronidase (HAase) activity, degrading hyaluronic acid dressing to trigger antibacterial ROS release, while high Ca2+ inhibits HAase, preventing overdosing.
Rongwei Cui   +12 more
wiley   +1 more source

Flexible white thermally activated delayed fluorescence polymer with alkyl spacer and side‐chain encapsulation for efficient solution‐processed white organic light‐emitting diodes

open access: yesFlexMat, EarlyView.
A “gemstone‐necklace” FASCE strategy synthesizes single‐component white polymers (PTF‐Qx) by alternating rigid TADF units with flexible alkyl chains. The non‐doped rigid device achieves a high EQE of 15.66% with stable white emission (CIE: 0.36, 0.46).
Wenhao Zhang   +7 more
wiley   +1 more source

Strengthened inter‐chain π–π contacts in amorphous diketopyrrolopyrrole polymers for robust flexible organic thin‐film transistors

open access: yesFlexMat, EarlyView.
Vinylene‐linked DPP polymers with expanded thiophene donors achieve strengthened interchain π‐π stacking in near‐amorphous films, enabling high charge mobility and outstanding mechanical stability for flexible organic thin‐film transistors. Abstract Flexible organic thin‐film transistors (OTFTs) based on multi‐vinylene‐linked diketopyrrolopyrrole (DPP)
Yanlin Chen   +11 more
wiley   +1 more source

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