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Titrimetry at a metrological level
Metrologia, 2003In the 1990s the CCQM (Comite consultatif pour la quantite de la matiere) defined the term 'primary method'. It also identified some methods that are considered to be primary. One of these methods is titrimetry. In this paper, the principle of titrimetry and two practical examples performed at the highest metrological level in the frame of key ...
Felber, Helene +2 more
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Titrimetry with solid titrants
Mikrochimica Acta, 1968The technique of solid titrant titrimetry has been described and its advantages enumerated. Precision and time required have been determined to be comparable with those of conventional titrimetry. Investigations with solid titrants have been made of the photometric titrations of Cu with EDTA, Fe(II) with KMnO4, As(III) with KMnO4, and Fe(III) with ...
H. Flaschka, R. Weiss
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2014
The application of coordination chemistry to volumetric analysis is a newer approach than the other major classes, largely because it is based on the use of synthetic polydentate ligands such as EDTA. In this chapter a summary of coordination chemistry is presented which is contextualised by the following practical activities: standardisation of EDTA ...
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The application of coordination chemistry to volumetric analysis is a newer approach than the other major classes, largely because it is based on the use of synthetic polydentate ligands such as EDTA. In this chapter a summary of coordination chemistry is presented which is contextualised by the following practical activities: standardisation of EDTA ...
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2014
Redox reactions play a major role in modern volumetric analysis and have found application in the analysis of many commercial products. In this chapter a summary of redox chemistry is presented which is contextualised by the following practical activities: standardisation of potassium permanganate; determination of iron in spinach; standardisation of ...
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Redox reactions play a major role in modern volumetric analysis and have found application in the analysis of many commercial products. In this chapter a summary of redox chemistry is presented which is contextualised by the following practical activities: standardisation of potassium permanganate; determination of iron in spinach; standardisation of ...
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1973
Publisher Summary This chapter discusses the applications and the theory of thermal titrimetry. For thermal titrimetry, a concentrated reagent, B, is added to the material, A, at a constant rate. The heat change generated by the reaction is recorded as a function of time or concentration of B added.
Mario A Marini, Charles J Martin
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Publisher Summary This chapter discusses the applications and the theory of thermal titrimetry. For thermal titrimetry, a concentrated reagent, B, is added to the material, A, at a constant rate. The heat change generated by the reaction is recorded as a function of time or concentration of B added.
Mario A Marini, Charles J Martin
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2014
Precipitation reactions are an interesting and often invaluable application of equilibrium concepts to analytical chemistry. In this chapter a summary of solubility equilibrium chemistry is presented which is contextualised by the following practical activities: standardisation of silver nitrate; determination of the salt content of isotonic sports ...
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Precipitation reactions are an interesting and often invaluable application of equilibrium concepts to analytical chemistry. In this chapter a summary of solubility equilibrium chemistry is presented which is contextualised by the following practical activities: standardisation of silver nitrate; determination of the salt content of isotonic sports ...
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1996
WHEN AN ANALYTE IS QUANTIFIED by measuring the volume (or, on rare occasions, the weight) of a solution that reacts with it, we call the process volumetric analysis or titrimetry. Generally, the reaction in question proceeds to its equilibrium point or to some reproducibly measurable point near equilibrium, whereupon the addition of reactant solution ...
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WHEN AN ANALYTE IS QUANTIFIED by measuring the volume (or, on rare occasions, the weight) of a solution that reacts with it, we call the process volumetric analysis or titrimetry. Generally, the reaction in question proceeds to its equilibrium point or to some reproducibly measurable point near equilibrium, whereupon the addition of reactant solution ...
openaire +1 more source