Results 91 to 100 of about 208,746 (285)

Modular One‐Pot Access to π‐Expanded Tetrakis(Phenothiazinyl)‐Silanes With Broadly Tunable Redox and Emission Properties

open access: yesChemistry – A European Journal, EarlyView.
A library of 21 tetrakis(phenothiazinyl)‐substituted silanes with broadly variable substituent decoration, which are fully reversible multistage redox systems with intense tunable emission from deep blue to yellow–green (441–533 nm), was rapidly synthesized by bromine–lithium exchange/borylation–Suzuki coupling of tetrakis(4‐bromophenyl)silane or by ...
Thomas P. M. Merke   +4 more
wiley   +1 more source

Modeling and Calibration for Crack Detection in Circular Shafts Supported on Bearings Using Lateral and Torsional Vibration Measurements

open access: yesAdvances in Mechanical Engineering, 2012
In this paper the requisite foundational numerical and experimental investigations that are carried out, to model the “uncracked and cracked” shaft and to identify its bending and torsional vibration responses, are reported. The cylindrical shaft used in
A. Tlaisi   +3 more
doaj   +1 more source

Interplay of Bridge Topology and Conformation in Phenylene‐Bridged Trityl Diradicals

open access: yesChemistry – A European Journal, EarlyView.
We present a meta‐phenylene‐bridged trityl diradical that exhibits an unexpectedly weak antiferromagnetic exchange coupling J with a strong environment‐dependent magnitude. Combined VSM, EPR, DFT, and MD studies reveal that structural flexibility modulates σ‐, π‐, and through‐space exchange contributions, highlighting the crucial role of geometry in ...
Kevin Lars Kopp   +4 more
wiley   +1 more source

Investigation of Lumped-Mass Method on Coupled Torsional-longitudinal Vibrations for a Marine Propulsion Shaft with Impact Factors

open access: yesJournal of Marine Science and Engineering, 2019
Severe vibrations of the marine propulsion shaft can evidently affect the dynamical response of the propulsion system and degrade the performance of a ship.
Qianwen Huang, Haiyun Liu, Jiyin Cao
doaj   +1 more source

Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV

open access: yesChemistry – A European Journal, EarlyView.
Syntheses of pentafluoroethyl substituted plumbanes in the formal oxidation states +II, +III, and +IV are reported. The compounds were characterized by multinuclear NMR spectroscopy, including 207Pb NMR spectroscopy, mass spectrometry and single‐crystal x‐ray diffraction experiments. ABSTRACT Mono‐, bis‐, and tris(pentafluoroethyl)plumbanes of the type
Michael Grasse   +4 more
wiley   +1 more source

Raman Optical Activity as a Tool to Monitor Polynucleotide Conformation in Solutions

open access: yesChemistry – A European Journal, EarlyView.
Raman optical activity (ROA) studies of nucleic acids have been hindered by limited computational tools to link the spectra to the structure. The study shows that accurate density functional simulations are possible for model nucleotides, bringing more information about molecular geometry and dynamics in solutions.
Mohammed Siddhique Para Kkadan   +5 more
wiley   +1 more source

Torsional Vibration Suppression in Multi-Condition Electric Propulsion Systems Through Harmonic Current Modulation

open access: yesActuators
Electric helicopters represent a pivotal component in the advancement of urban air mobility (UAM), with considerable potential for future development. The electric propulsion system (EPS) is the core component of these systems.
Hanjie Jia   +4 more
doaj   +1 more source

Electrochemiluminescence of Heteroleptic Iridium(III) Complexes Featuring Substituted 2,4‐diphenylpyridinato Ligands

open access: yesChemistry – A European Journal, EarlyView.
Five heteroleptic iridium(III) complexes bearing cyclometalated 2,4‐diphenylpyridinato ligands were synthesized and their electrochemiluminescence (ECL) investigated. Two different coreactants were evaluated: tri‐n‐propylamine and benzoyl peroxide under anodic and cathodic potentials, respectively.
Ovini Jayawardana   +6 more
wiley   +1 more source

Iso‐Tellurazole N‐Oxides Assemble Adaptively Folded Macrocyclic Dodecamers

open access: yesChemistry – A European Journal, EarlyView.
Te…O Chalcogen bonding links twelve molecules into a ring that wraps itself around molecular guests. ABSTRACT Self‐assembled macrocyclic dodecamers were found in the crystals of new pseudo‐polymorphs of iso‐tellurazole N‐oxides. These structures are formed by molecules connected by NTe…O chalcogen bonds and are folded in a pattern that defines 89–153 ...
Jin Z. Wang   +4 more
wiley   +1 more source

Nonlinear Torsional Vibrations of Thin-Walled Beams of Open Section

open access: yes, 1975
An attempt has been made to derive and solve the governing differential equation of large amplitude torsional vibrations of simply supported doubly symmetric thin-walled beams of open section.
C. Kameswara Rao
core   +1 more source

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