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Collective Total Syntheses of Five Lycopodium Alkaloids
Angewandte Chemie International Edition, 2022AbstractIt is reported herein that by exploiting the commonly shared bicyclic decahydroquinoline motif, a gold‐catalyzed enamide–alkyne cycloisomerization reaction is developed to access tricyclic cores in a simple way. These tricyclic cores further serve as an advanced platform for the divergent enantioselective collective total syntheses of five ...
Feifei He +7 more
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Collective total synthesis of botryanes
Tetrahedron, 2019Abstract The collective total synthesis of a series of botryanes, which are an important group of sesquiterpene antibiotics isolated from the metabolites of the fungus Botrytis cinerea, has been reported. The highly functionalized hydrindane skeleton of the botryanes was efficiently synthesized via an unusual intramolecular Diels-Alder reaction ...
Chuang Qiao +4 more
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Enantioselective and Collective Total Syntheses of Xanthanolides
Angewandte Chemie International Edition, 2017AbstractAn enantioselective synthesis of (+)‐8‐epi‐xanthatin hinging on a chiral phosphoric acid catalyzed tandem allylboration/lactonization reaction is reported. With (+)‐8‐epi‐xanthatin as the precursor, the collective synthesis of a series of synthetically challenging xanthanolides was also accomplished. Among them, xanthipungolide, one of the most
Juan Feng +6 more
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