Results 141 to 150 of about 653,448 (286)

Grain Boundary Space Charge Engineering of Solid Oxide Electrolytes: Model Thin Film Study

open access: yesAdvanced Functional Materials, EarlyView.
This study demonstrates unprecedented control of grain boundary electrical properties in solid electrolytes. Selective diffusion of cations through grain boundaries in thin films enables 12 orders of magnitude variation in ionic resistance, proving that systematic chemical modification of grain boundary electrical properties is feasible.
Thomas Defferriere   +5 more
wiley   +1 more source

Tailoring Microstructure in Copper‐Based Conductive Metal–Organic Frameworks for Enhanced Chemiresistive Sensing and Uptake of Sulfur Dioxide

open access: yesAdvanced Functional Materials, EarlyView.
Precursor‐ and solvent‐mediated synthesis yields four Cu3(HHTP)2 morphologies with distinct physicochemical, sorption, and sensing properties toward SO2. Uptake capacities correlate with BET surface area, while sensing performance scales with particle aspect ratio.
Patrick Damacet   +5 more
wiley   +1 more source

Microsphere Autolithography—A Scalable Approach for Arbitrary Patterning of Dielectric Spheres

open access: yesAdvanced Functional Materials, EarlyView.
MicroSphere Autolithography (µSAL) enables scalable fabrication of patchy particles with customizable surface motifs. Focusing light through dielectric microspheres creates well defined, tunable patches via a conformal poly(dopamine) photoresist. Nearly arbitrary surface patterns can be achieved, with the resolution set by the index contrast between ...
Elliott D. Kunkel   +3 more
wiley   +1 more source

Quantifying Spin Defect Density in hBN via Raman and Photoluminescence Analysis

open access: yesAdvanced Functional Materials, EarlyView.
An all‐optical method is presented for quantifying the density of boron vacancy spin defects in hexagonal boron nitride (hBN). By correlating Raman and photoluminescence signals with irradiation fluence, defect‐induced Raman modes are identified and established an relationship linking optical signatures to absolute defect densities. This enables direct
Atanu Patra   +8 more
wiley   +1 more source

Wafer‐Scale Synthesis of Mithrene and its Application in UV Photodetectors

open access: yesAdvanced Functional Materials, EarlyView.
A controlled tarnishing step on the silver surface precedes the solid‐vapor‐phase chemical transformation into silver phenylselenolate thin films. The approach yields crystals exceeding 1 µm with improved in‐plane orientation. Integration on graphene phototransistors demonstrates high photoresponsivity, positioning mithrene as a promising material for ...
Maryam Mohammadi   +8 more
wiley   +1 more source

High‐Rate FA‐Based Co‐Evaporated Perovskites: Understanding Rate Limitations and Practical Considerations to Overcome Their Impact

open access: yesAdvanced Functional Materials, EarlyView.
Vacuum‐based deposition is promising for perovskite solar cells to be successfully commercialized. However, co‐evaporation, the most common vapor phase deposition technique, suffers from very low deposition rates. In this work, we reveal that high deposition rates can lead to carbon flakes depositing into the perovskite absorber layers due to material ...
Thomas Feeney   +13 more
wiley   +1 more source

Electrochemical Formation of BiVO4/BiPO4 Photoanodes for Enhanced Selectivity toward H2O2 Generation

open access: yesAdvanced Functional Materials, EarlyView.
In acidic KPi, V dissolves from the BiVO4 lattice, while adsorbed phosphate reacts with the electrode under an external bias, forming a BiPO4 surface layer. This BiPO4 layer exhibits stronger bicarbonate adsorption, redirecting the water oxidation pathway toward two‐electron H2O2 production.
Kaijian Zhu   +12 more
wiley   +1 more source

Analysis of the Electrochemical Stability of Sulfide Solid Electrolyte Dry Films for Improved Dry‐Processed Solid‐State Batteries

open access: yesAdvanced Functional Materials, EarlyView.
An adapted processing for solvent‐free argyrodite solid electrolyte films based on insights into degradation mechanisms of the widely used binder polytetrafluoroethylene is presented. By adapting the dry film processing, long‐term cycling in Si||NMC pouch cells is demonstrated over more than 1000 cycles with a capacity retention of more than 80%, and ...
Maria Rosner   +10 more
wiley   +1 more source

Laser‐Based Sculpturing of Embedded Ultrathin Metal‐Oxide Nanopores for Enhanced Biomolecular Sensing

open access: yesAdvanced Functional Materials, EarlyView.
Controlled laser‐drilling of embedded HfO2 membranes creates three layer nanopores with Gaussian‐shaped cavities sculptured in the supporting layers. These embedded solid‐state nanopores slow DNA translocation by 12‐fold compared to SiNx pores, enabling high‐resolution, label‐free detection of short DNAs, RNAs, and proteins.
Jostine Joby   +4 more
wiley   +1 more source

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