Results 121 to 130 of about 1,204,200 (341)

Innovative Processing of Compacted Waste Aluminum Alloy Powders via Controlled Remelting and Solidification

open access: yesAdvanced Engineering Materials, EarlyView.
This study demonstrates an efficient recycling route for out‐of‐spec AlSi10Mg atomized powders through compaction and arc remelting followed by suction casting. By correlating compaction load, cooling rate, and resulting microstructure, we show that intermediate pressures (50–80 kN) and rapid cooling refine dendrites, reduce porosity, and enhance ...
Mila Christy de Oliveira   +4 more
wiley   +1 more source

Microwave Assisted Synthesis, Spectral and Antifungal Studies of 2-Phenyl-N,N′-bis(pyridin-4-ylcarbonyl)butanediamide Ligand and Its Metal Complexes

open access: yesThe Scientific World Journal, 2014
2-Phenyl-N,N′-bis(pyridin-4-ylcarbonyl)butanediamide ligand with a series of transition metal complexes has been synthesized via two routes: microwave irradiation and conventional heating method.
Rayees Ahmad Shiekh   +4 more
doaj   +1 more source

Transmetalation from Magnesium–NHCs—Convenient Synthesis of Chelating π-Acidic NHC Complexes

open access: yesInorganics, 2019
The synthesis of chelating N-heterocyclic carbene (NHC) complexes with considerable π-acceptor properties can be a challenging task. This is due to the dimerization of free carbene ligands, the moisture sensitivity of reaction intermediates or ...
Julian Messelberger   +5 more
doaj   +1 more source

Pharmacological Activity of a Few Transition Metal Complexes: A Short Review

open access: yes, 2016
Transition metals have an important place within medicinal inorganic chemistry. Transition metals exhibit different oxidation states and can interact with a number of negatively charged molecules.
M. Selvaganapathy, N. Raman
semanticscholar   +1 more source

A review on versatile applications of transition metal complexes incorporating Schiff bases

open access: yesBeni-Suef University Journal of Basic and Applied Sciences, 2015
Schiff bases and their complexes are versatile compounds synthesized from the condensation of an amino compound with carbonyl compounds and widely used for industrial purposes and also exhibit a broad range of biological activities including antifungal ...
A. Abu‐Dief, I. M. Mohamed
semanticscholar   +1 more source

Trialkylborane-Assisted CO_2 Reduction by Late Transition Metal Hydrides [PDF]

open access: yes, 2011
Trialkylborane additives promote reduction of CO_2 to formate by bis(diphosphine) Ni(II) and Rh(III) hydride complexes. The late transition metal hydrides, which can be formed from dihydrogen, transfer hydride to CO_2 to give a formateborane adduct.
Bercaw, John E.   +2 more
core   +1 more source

Rapid and Precise Determination of Zero-Field Splittings by Terahertz Time-Domain Electron Paramagnetic Resonance Spectroscopy

open access: yes, 2017
Zero-field splitting (ZFS) parameters are fundamentally tied to the geometries of metal ion complexes. Despite their critical importance for understanding the magnetism and spectroscopy of metal complexes, they are not routinely available through general
Belvin, Carina   +9 more
core   +1 more source

Interactions between Molten High‐Silicon Electrical Steels and Carbon‐Bonded MgO Refractories Based on Recyclates

open access: yesAdvanced Engineering Materials, EarlyView.
This study examines how several molten high‐silicon electrical steels interact with both conventional and recycled MgO–C refractories. For this, various immersion experiments are conducted. In addition to infiltration, a number of mechanisms are identified and explained that control the corrosion of the refractory material.
Lukas Neubert   +7 more
wiley   +1 more source

Synthesis, characterization and antibacterial activities of novel mixed ligands (azo anils and oxalate ion) copper(II) complexes

open access: yesBulletin of the Chemical Society of Ethiopia, 2015
Three azo anils ligands; 4-[(4-nitrophenyl)diazenyl]-2-[(phenylimino)met-hyl]phenol (L1), 2-{[(2-methylphenyl)-imino]-methyl}-4-[(4-nitrophenyl)diazenyl]phenol (L2) and 2-[(naphthalen-1-ylimino)-methyl]-4-[(4-nitrophenyl)diazenyl]-phenol (L3) were ...
M. Ameen   +4 more
doaj   +1 more source

Quantum and Thermal Phase Transitions of Halogen-Bridged Binuclear Transition-Metal Complexes

open access: yes, 2001
Aiming to settle the controversial observations for halogen-bridged binuclear transition-metal (MMX) complexes, finite-temperature Hartree-Fock calculations are performed for a relevant two-band Peierls-Hubbard model.
Bellitto C.   +25 more
core   +1 more source

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