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Functionalization of Supramolecular Complexes by Hybridization of Transition Metal Transition Metal Complexes with Biomoleculesopenaire
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Transition-metal difluorocarbene complexes
Chemical Communications, 2021We review the recent developments in the chemistry of transition-metal difluorocarbenes, including bonding and utility of MCF2complexes.
Wei Zhou +6 more
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Transition Metal Carbide Complexes
Chemical Reviews, 2021Carbide complexes remain a rare class of molecules. Their paucity does not reflect exceptional instability but is rather due to the generally narrow scope of synthetic procedures for constructing carbide complexes. The preparation of carbide complexes typically revolves around generating LnM-CEx fragments, followed by cleavage of the C-E bonds of the ...
Anders Reinholdt, Jesper Bendix
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Transition metals and metal complexes in autophagy and diseases
Journal of Cellular Physiology, 2021AbstractTransition metals refer to the elements in the d and ds blocks of the periodic table. Since the success of cisplatin and auranofin, transition metal‐based compounds have become a prospective source for drug development, particularly in cancer treatment. In recent years, extensive studies have shown that numerous transition metal‐based compounds
Yuping Luo +3 more
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Transition metal borylene complexes
Chemical Society Reviews, 2013Borylene ligands (:BR) are isolobal to CO and other iconic organometallic ligands. As such, borylene ligands enjoy some parallels to these ligands, but in many ways, their chemistry is distinct. This tutorial review gives an introduction to the synthesis, properties and reactivity of the major classes of transition metal borylene complexes, including ...
Holger Braunschweig +2 more
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Transition Metal Complexes of Boron
Angewandte Chemie - International Edition, 1998Rapid advances have been made over the past few years in the chemistry of transition metal complexes with σ-bonded boryl and borylene ligands. The use of suitable substituents on boron has made possible both the synthesis and complete characterization of numerous compounds of this type, and the analysis of spectroscopic data provides the first insight ...
exaly +2 more sources
π-Complexes of the transition metals
Journal of Organometallic Chemistry, 1965Abstract The products formed by the action of p -tolylmagnesium bromide on CrCl 3 -(THF) 3 , ratio 3:1 in diethyl ether, and in the rearrangement of tri- p -tolylchromium in diethyl ether suspension have been isolated and characterized. The significance of these results with respect to the mechanism of the rearrangement of σ-bonded organochromium ...
R.P.A. Sneeden, F. Glockling, H. Zeiss
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Journal of Organometallic Chemistry, 1993
The invention relates to transition metal complexes of general formulas (Ia) or (Ib) in which the substituents and indices have the following meanings: M represents titanium, zirconium, hafnium, vanadium, niobium or tantalum or an element of the third subgroup of the periodic table or of the lanthanides; X represents fluorine, chlorine, bromine, iodine,
U. Denninger +5 more
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The invention relates to transition metal complexes of general formulas (Ia) or (Ib) in which the substituents and indices have the following meanings: M represents titanium, zirconium, hafnium, vanadium, niobium or tantalum or an element of the third subgroup of the periodic table or of the lanthanides; X represents fluorine, chlorine, bromine, iodine,
U. Denninger +5 more
openaire +1 more source