Results 61 to 70 of about 16,308 (224)
We report a carbonylation‐homolysis process to access acyl radicals that can undergo decarboxylation or cyclization onto tethered alkenes. In both cases, ligands and additives are shown to influence the outcome to give saturated or unsaturated products, in some cases with isomerization of the initial products.
Jacob N. Hackbarth +4 more
wiley +1 more source
Endocrine disruptors in bottled mineral water : total estrogenic burden and migration from plastic bottles [PDF]
Background, aim, and scope Food consumption is an important route of human exposure to endocrine-disrupting chemicals. So far, this has been demonstrated by exposure modeling or analytical identification of single substances in foodstuff (e.g ...
Oehlmann, Jörg, Wagner, Martin
core +1 more source
Mapping molluscan endocrinology: a systematic and critical appraisal
ABSTRACT Historically, a vertebrate‐centric paradigm has framed our interpretation of molluscan endocrinology, with considerable research focusing on vertebrate‐type steroid hormones (e.g. oestrogens, testosterone). However, contradictory evidence on the occurrence of vertebrate‐type steroid hormones in molluscan tissues, and a lack of the specific ...
Konstantinos Panagiotidis +3 more
wiley +1 more source
Tin (Sn) is one of the heavy metals to which various functions in biological development are attributed in small quantities, for example, a role in cell structure, enzyme activities, and protein and carbohydrate metabolism in fish.
Aref Barkhordari +4 more
doaj +1 more source
Synthetic use of the primary kinetic isotope effect in hydrogen atom transfer: generation of α-aminoalkyl radicals. [PDF]
addresses: School of Biosciences, University of Exeter, Geoffrey Pope Building, Stocker Road, Exeter, UKEX4 4QD. m.e.wood@exeter.ac.uktypes: Journal Article; Research Support, Non-U.S.
Bissiriou, S +7 more
core +1 more source
Selective Scrambling of Phenyl‐Stannanes: Main Group Catalysis With Aromatic Phosphorus Heterocycles
Phosphinine–borane Lewis pairs catalyze the selective scrambling of phenylstannanes into SnPh4, H2, and elemental Sn. The reaction proceeds via transient SnH4 formation through reversible hydride and phenyl transfer steps within three interconnected cycles and enabled by an intrinsically weak P→B bond.
Samantha Frank +7 more
wiley +1 more source
Effect of Tributyltin on the Sex Ratio in Guppy (Poecilia reticulata)
In this study, the effect of tributyltin (TBT) on the sex ratio in guppy (Poecilia reticulata) during the labile period covering both embryonic and post hatching periods was investigated.
Seval Dernekbaşı +2 more
doaj +1 more source
Prioritising research on endocrine disruption in the marine environment: a global perspective
ABSTRACT A healthy ocean is a crucial life support system that regulates the global climate, is a source of oxygen and supports major economic activities. A vast and understudied biodiversity from micro‐ to macro‐organisms is integral to ocean health.
Patricia I. S. Pinto +23 more
wiley +1 more source
Tributyltin: A Bottom–Up Regulator of the Crangon crangon Population?
The restrictions and the concerted action of the global ban on the use and presence of tributyltin (TBT) in marine applications to protect ecosystems in the marine environment in 2008 was mainly based on the economic impact on shellfish industries and ...
Koen F. V. Parmentier +11 more
doaj +1 more source
Light‐Induced Reactions of Small‐Membered Cyclic Carbonyl Compounds
This review highlights recent advances in the synthesis and photochemical reactivity of cyclopropenone and cyclobutenedione. These compounds undergo photolysis upon direct excitation, and in some cases, through indirect excitation by photocatalysts. The resulting photogenerated species exhibit unique reactivity profiles that are strongly influenced by ...
Kenji Mishiro
wiley +1 more source

