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Synthesis of New Pinane-Type Hetarylsulfides
Chemistry of Natural Compounds, 2014© 2014 Springer Science+Business Media New York. New bicyclic thioterpenoids with heterocyclic fragments were prepared via reactions of (-)-β-pinene and its oxide with 1-phenyl-1H-tetrazole-5-thiol, 1-methylimidazole-2-thiol, and 4,6-dimethyl-2-pyrimidinesulfenylchloride.
Startseva V. +6 more
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Synthesis of new carbamate-type harmicines
2022Harmine is a naturally occurring β-carboline alkaloid that possesses a broad range of biological activities, including antitumor and antimalarial. We designed and prepared several series of hybrid compounds in which harmine was covalently linked to other biologically active compounds: cinnamic acid derivatives (CADs, harmicines), quinolines (harmiquins)
Marinović, Marina, Rajić, Zrinka
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Stereocontrolled Synthesis of Ara‐Type Cyclohexenyl Nucleosides.
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
Jing, Wang +3 more
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A New Type of Corrin Synthesis
Angewandte Chemie International Edition in English, 1969AbstractWork towards a synthesis of vitamin B12 has inspired a new type of corrin synthesis. The key step is a light‐induced 1,16‐hydrogen transfer leading to an antarafacial (π→σ)‐cycloisomerization of a seco‐corrinoid metal complex. The construction of the seco‐corrinoid ligand system is achieved by coupling monocyclic ring precursors in their ...
Y, Yamada +7 more
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Spectral synthesis for Euler type operators
Analysis Mathematica, 1989Let A be the square matrix \((a_{i_ j})\) U be a domain in \(C^ k\), and H(u) be the space of holomorphic functions in U with the locally uniform convergence topology. The author proves that under some stated conditions on the matrix A, and the domain U, the invariant subspace \(W\subset H(U)\) admits a spectral synthesis.
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Biogentic-type synthesis of cularine
Bioorganic Chemistry, 1971Abstract The phenolic oxidation of 1,2,3,4-tetrahydro-8-hydroxy-1-(3-hydroxy-4-methoxy-benzyl)-7-methoxy-2-methylisoquinoline ( 2 ) with alkaline ferricyanide gave a demethylcularine ( 4 ) and its isomer ( 5 ). The former was converted into cularine ( 1 ).
T. Kametani, K. Fukumoto, M. Fujihara
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Asymmetric Synthesis of Scillascillin-Type Homoisoflavonoid
Organic LettersThe first asymmetric synthesis of a scillascillin-type homoisoflavonoid was reported. Key reactions for the asymmetric synthesis of benzocyclobutene include catalytic reductive desymmetrization of malonic ester and an intramolecular C-H activation of the methyl group.
Huachao Wang +7 more
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Synthesis of samanine type alkaloids
Tetrahedron Letters, 1973Aus dem bekannten Cyan-aldehyd (I) kann durch Reduktion und Tosylierung das Nitriltosylat (II) erhalten und zu (III) cyclisiert werden.
R.Balaji Rao, Larry Weiler
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Synthesis of cadinane type sesquiterpenes
Journal of the Chemical Society, Chemical Communications, 1979A new and convenient synthesis of cadinane type sesquiterpenes is reported from the tricyclo-[4.4.0.02,5]decane photoadduct (1).
John R. Williams, James F. Callahan
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Enantioselective Synthesis of Acenaphthene-Type Monohydrosilanes
Organic LettersAcenaphthene and its analogues are privileged frameworks in medicinal chemistry and material science. However, the properties of silicon-substituted acenaphthene-type scaffolds are poorly understood. Here, we report a rhodium-catalyzed intramolecular C(sp3)-H silylation for enantioselective synthesis of acenaphthene-type scaffolds with excellent ...
Delong Mu, Xinrui Zhu, Jiean Chen
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