Results 191 to 200 of about 177,361 (268)

Hyperpolarization of Pyridine 15N‐Oxide Molecular Probes Enabled by Parahydrogen

Angewandte Chemie, EarlyView.
Pyridine 15N‐oxides are introduced as motifs for hyperpolarization studies and biochemical applications are demonstrated. ABSTRACT Magnetic resonance (MR) is a powerful non‐invasive technique for probing structural, functional, and metabolic processes with high spatial and temporal resolution.
Ruhuai Mei, Lisa Maria Fries, Gonzalo Gabriel Rodriguez, Charlotte von Petersdorff‐Campen, Leander Konstantin May, Julius Frederik Matz, Sergey Korchak, Grysette Daher, Stefan Glöggler   +8 more
wiley   +1 more source

Erratum: Further correction: Reductive annulations of arylidene malonates with unsaturated electrophiles using photoredox/Lewis acid cooperative catalysis. [PDF]

Chem Sci
Betori RC, McDonald BR, Scheidt KA.
europepmc   +1 more source

Heterobimetallic Janus Catalysts for the One‐Pot Synthesis of Polar‐Apolar Block Copolymers

Angewandte Chemie, EarlyView.
Heterobimetallic Janus catalysts act as bifunctional initiators, combining two distinct polymerisation mechanisms in one pot to deliver well‐defined apolar‐polar block copolymers. Combining Earth abundant Ti and Al catalysts for respective α‐olefin and lactone polymerisation, the orthogonal activity is enabled by unprecedented initiation from a Ti ...
Raju Chambenahalli, Gary S. Nichol, Jennifer A. Garden   +2 more
wiley   +1 more source

Longitudinal multi-omics evidence reveals lung injury and concurrent disruption of intestinal flora and serum metabolism by cigarette smoke and influenza virus. [PDF]

Front Cell Infect Microbiol
Liu Z, Li H, Xiang Y, Ren S, Pan W, Ling Z, Dong J, Liang Z, Quan J, Fan L, Lin L, Wu L, Yu X.   +12 more
europepmc   +1 more source

Modulating Local Coordination in Single‐Atom Catalysts: From Fundamental Concepts to Emerging Breakthroughs in Electrocatalysis

Angewandte Chemie, EarlyView.
This review summarizes atomic‐level design strategies for single‐atom catalysts, emphasizing modulation of the local coordination environment, active‐site geometry, and metal‐support interactions to optimize catalytic activity and stability in electrocatalytic energy conversion applications.
Ashwani Kumar, Harun Tüysüz
wiley   +1 more source

A Wagner–Meerwein‐Like Rearrangement Generates a Vinyl Group in the Biosynthesis of the Polychlorinated Lipopeptides Fischerazoles

Angewandte Chemie, EarlyView.
The fischerazoles, unusual cyanobacterial chlorinated lipopeptides are reported. During their biosynthesis, a linear fatty acyl‐acyl carrier protein (ACP) precursor is rearranged through the action of the S‐adenosyl‐methionine (SAM)‐dependent methyltransferase FshF, to generate a pendant vinyl group.
Sandra A. C. Figueiredo, Kathleen Abt, Konrad Viehrig, Peter J. Jervis, Teresa P. Martins, Iñaki Lacomba, Chuhan Li, Daniele Castagnolo, Pedro N. Leão   +8 more
wiley   +1 more source

Selenol-containing two-dimensional perovskite promotes visible-light-driven selective reduction of unsaturated ketones. [PDF]

Chem Sci
Li W, Liao L, Yao G, Liu J, Zhang Y, Li J, Qiu W, Zeng T, Zhao X, Yang Z.   +9 more
europepmc   +1 more source

Fundamental Understanding of Oxidative Stability in Fluorinated Asymmetric Ethers for Li Batteries

Angewandte Chemie, EarlyView.
To improve Li‐metal battery electrolytes, we analyze fluorinated 1‐ethoxy‐2‐methoxyethane (FxEME) oxidative stability via density functional theory (DFT) and molecular dynamics (MD). Fluorination strengthens ethoxy C–H bonds and alters solvent orientation at the cathode, weakening interfacial interactions.
Liang‐Ting Wu, Norio Takenaka, Jyh‐Chiang Jiang, Atsuo Yamada   +3 more
wiley   +1 more source

Serum Untargeted Metabolomics Profiling of Esophageal Squamous Cell Carcinoma in High-Incidence Areas of China. [PDF]

Int J Gen Med
Li Y, Zhou L, Huang R, Wu Z, Guan J, Qiao X, Kong Y, Gan Y, Zhang Y, Li J.   +9 more
europepmc   +1 more source

Iridium‐Catalyzed Ionic Hydrogenation of Multi‐Aza Heterocycles

Angewandte Chemie, EarlyView.
Saturated nitrogen‐containing heterocycles are ubiquitous in bioactive molecules and are thus attractive synthetic targets. A readily accessible cyclometalated iridium(III) complex reduces 14 different aromatic aza heterocycles to (partially)saturated multi aza‐heterocycles enlarging accessible chemical space while displaying high tolerance toward ...
Arthur Despois, Nicolai Cramer
wiley   +1 more source