Results 241 to 250 of about 278,215 (318)

Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations

Angewandte Chemie, EarlyView.
Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera, Francesco Basoccu, Andrea Porcheddu   +2 more
wiley   +1 more source

Room temperature synthesis of α,β-unsaturated nitriles by manganese-catalysed base-free coupling of α-saturated nitriles with aldehydes. [PDF]

Chem Sci
Thiyagarajan S, Luo J, Liang Y, Efremenko I, Montag M, Milstein D.   +5 more
europepmc   +1 more source

Programmable Solid‐Electrolyte Interfaces for Efficient and Selective Electrochemical Hydrogenations

Angewandte Chemie, EarlyView.
Poly(ionic liquid) binders are shown to actively control the electrode microenvironment, strongly enhancing electrochemical hydrogenation compared to traditional binders. The work redefines the binder as an active component of catalytic electrode design, reshaping local potential gradients and interfacial ion distribution to modulate adsorbed H ...
Anastasios Orestis Grammenos, Jessica Brandt, Yu Zhang, Zeen Wu, Mateusz M. Marzec, Sotirios Sotiropoulos, Piotr Jeleń, Jiayin Yuan, Markus Antonietti, Mateusz Odziomek   +9 more
wiley   +1 more source

Fatty Acid Composition, at Equivalent Lipid Exposure, Dictates Human Macrophage Polarization via PPARγ Signaling. [PDF]

Cells
AlSaeed H, Almusallam H, Menezes S, Almelaifi H, Alonaizi H, Almejaimi M, Ahmad R, Al-Rashed F.   +7 more
europepmc   +1 more source

Kinetic Analysis of Transmetalation at Prototypical Nickel(II) Catalyst Species: Rates, Mechanisms, and Implications for Catalysis

Angewandte Chemie, EarlyView.
A 31P{1H} NMR method enabling direct measurement of transmetalation at Ni(II) is disclosed, providing an extensive kinetic dataset. Rates span five orders of magnitude and exhibit strong ligand dependence, with monodentate ligands promoting transmetalation.
Nicholas S. D. Solomon, Xuechun Huang, Christopher Richardson, Sinead T. Keaveney   +3 more
wiley   +1 more source

Fundamental Understanding of Oxidative Stability in Fluorinated Asymmetric Ethers for Li Batteries

Angewandte Chemie, EarlyView.
To improve Li‐metal battery electrolytes, we analyze fluorinated 1‐ethoxy‐2‐methoxyethane (FxEME) oxidative stability via density functional theory (DFT) and molecular dynamics (MD). Fluorination strengthens ethoxy C–H bonds and alters solvent orientation at the cathode, weakening interfacial interactions.
Liang‐Ting Wu, Norio Takenaka, Jyh‐Chiang Jiang, Atsuo Yamada   +3 more
wiley   +1 more source

Longitudinal multi-omics evidence reveals lung injury and concurrent disruption of intestinal flora and serum metabolism by cigarette smoke and influenza virus. [PDF]

Front Cell Infect Microbiol
Liu Z, Li H, Xiang Y, Ren S, Pan W, Ling Z, Dong J, Liang Z, Quan J, Fan L, Lin L, Wu L, Yu X.   +12 more
europepmc   +1 more source

Catalytic Functionalization of Unactivated π‐Bonds Enabled by Bidentate Directing Auxiliaries

Angewandte Chemie, EarlyView.
This review explores how bidentate directing auxiliaries have advanced transition‐metal catalysis for unactivated alkene/alkyne functionalization. By leveraging chelated intermediates, bidentate directing auxiliaries enable precise hydrofunctionalization, difunctionalization, and C─H activation of π‐bonds with unique selectivity and reactivity.
Seunghyeon Cho, Al Vicente Riano D. Lisboa, Juntao Sun, Taeho Kang, Keary M. Engle   +4 more
wiley   +1 more source

Integrated Transcriptomic and Metabolomic Analysis Deciphers the Molecular and Metabolic Mechanisms Underlying Growth Rate Divergence in Dezhou Donkeys. [PDF]

Animals (Basel)
Zhang X, Li H, Zhou X, Cao X, Dou M, Wang C, Li W.   +6 more
europepmc   +1 more source

Synergistic Lewis Acid Photocatalysis Over Cluster‐Defect‐Engineered UiO‐66 for Efficient Liquid Biomass Upgrading

Angewandte Chemie, EarlyView.
A cluster‐defect engineering strategy is presented for the rational design of Zn‐incorporated UiO‐66 photocatalysts. Selective acid etching mediates hierarchical porosity and abundant Lewis acid sites, tailoring the electronic structure and enhancing light harvesting.
Hao Wang, Li‐Long Zhang, Haimei Xu, Baohua Jia, Liqun Ye, Tianyi Ma, Heng Zhang   +6 more
wiley   +1 more source