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Intramolecular Schmidt Reaction of Vinyl Azides with Cyclic Ketones

Organic Letters, 2018
Cyclic ketones tethered with a vinyl azide group undergo a Schmidt-hydrolysis sequence to give secondary lactams bearing a ketone side chain. Secondary lactams are obtained in a regioselective manner that is not possible in a conventional Schimdt reaction.
Peng Chen   +6 more
openaire   +2 more sources

Reactions of vinyl azides and β‐haloalkyl azides with active methylene compounds. Synthesis of 1‐vinyl‐1,2,3‐triazoles

Journal of Heterocyclic Chemistry, 1970
AbstractA general synthetic approach to the yet unknown class of 1‐vinyl‐1,2,3‐triazoles is the condensation of active methylene compounds with vinyl azides or their precursors, the β‐haloalkyl azides, in the presence of an alkoxide. Triazole‐4‐carboxylic acids prepared in this manner are decarboxylated smoothly on heating above their melting point ...
G. L'abbé, Alfred Hassner
openaire   +1 more source

The reaction of vinyl azides with sulfoxonium ylids. Synthesis of n-vinyl triazolines and vinyl aziridines.

Tetrahedron Letters, 1981
Abstract Vinyl azides 1 react with dimethylsulfoxonium ylid 3 at the azide function to produce in high yield 1-vinyl-4,5-unsubstituted-Δ-1, 2 -1,2,3-triazolines 4 . Vacuum flash pyrolysis of 4 furnished N-vinylaziridines 7 without formation of pyrolines.
Alfred Hassner   +3 more
openaire   +1 more source

ChemInform Abstract: REACTIONS OF VINYL AZIDES

Chemischer Informationsdienst, 1976
AbstractÜbersicht (Thermolyse, Photolyse, Cycloaddition; Reaktivität gegenüber nucleophilen, elektrophilen und 1,3‐dipolaren Verbindungen).
openaire   +1 more source

C2H3N3 Vinyl azide

2005
G. Graner   +6 more
openaire   +1 more source

The Isomerization of a Vinyl Azide to a Triazole

Journal of the American Chemical Society, 1967
John S. Meek, Joanna S. Fowler
openaire   +1 more source

Highly Enantioselective Iridium-Catalyzed Coupling Reaction of Vinyl Azides and Racemic Allylic Carbonates

Journal of the American Chemical Society, 2020
Peng Cao, Yuanji Gao, Tao Jia
exaly  

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