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EPR and pulsed ENDOR study of intermediates from reactions of aromatic azides with group 13 metal trichlorides [PDF]
Beilstein Journal of Organic Chemistry, 2010 The reactions of group 13 metal trichlorides with aromatic azides were examined by CW EPR and pulsed ENDOR spectroscopies. Complex EPR spectra were obtained from reactions of aluminium, gallium and indium trichlorides with phenyl azides containing a ...
Giorgio Bencivenni +4 more
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Azides in the Synthesis of Various Heterocycles
Molecules, 2022 In this review, we focus on some interesting and recent examples of various applications of organic azides such as their intermolecular or intramolecular, under thermal, catalyzed, or noncatalyzed reaction conditions.
AbdElAziz A. Nayl +8 more
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SulfoxFluor-enabled deoxyazidation of alcohols with NaN3
Nature Communications, 2022 Azides are common moieties in chemical synthesis. Here the authors present a methodology to synthesize alkyl azides in one step from simple alcohols under mild conditions.
Junkai Guo +4 more
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Ortho-Phosphinoarenesulfonamide-Mediated Staudinger Reduction of Aryl and Alkyl Azides
Molecules, 2022 Conventional Staudinger reductions of organic azides are sluggish with aryl or bulky aliphatic azides. In addition, Staudinger reduction usually requires a large excess of water to promote the decomposition of the aza-ylide intermediate into phosphine ...
Xingzhuo Li +5 more
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Nature Communications, 2022 Catalytic kinetic resolution of racemates is among the best ways to prepare enantiopure compounds, but this process is difficult with organic azides given the small size of the azido group.
Pengbo Ye +5 more
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Reactive & Efficient: Organic Azides as Cross-Linkers in Material Sciences
Molecules, 2020 The exceptional reactivity of the azide group makes organic azides a highly versatile family of compounds in chemistry and the material sciences. One of the most prominent reactions employing organic azides is the regioselective copper(I)-catalyzed ...
Marvin Schock, Stefan Bräse
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Synthesis of 1,2,3-triazoles using Grignard reactions through the protection of azides
Frontiers in Chemistry, 2023 An efficient method to prepare organomagnesium intermediates having a protected azido group is reported. Protection of azido groups with di-(tert-butyl)(4-(dimethylamino)phenylphosphine (amphos) and following iodine–magnesium exchange realized the ...
Rina Namioka +3 more
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Taming tosyl azide: the development of a scalable continuous diazo transfer process [PDF]
, 2016 Heat and shock sensitive tosyl azide was generated and used on demand in a telescoped diazo transfer process. Small quantities of tosyl azide were accessed in a one pot batch procedure using shelf stable, readily available reagents. For large scale diazo
Collins, SG +5 more
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Beilstein Journal of Organic Chemistry, 2020 N-Sulfonyl amidines bearing 1,2,3-triazole, isoxazole, thiazole and pyridine substituents were successfully prepared for the first time by reactions of primary, secondary and tertiary heterocyclic thioamides with alkyl- and arylsulfonyl azides.
Vladimir Ilkin +7 more
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Noncanonical Amino Acids in the Interrogation of Cellular Protein Synthesis [PDF]
, 2011 Proteins in living cells can be made receptive to bioorthogonal chemistries through metabolic labeling with appropriately designed noncanonical amino acids (ncAAs).
Ngo, John T., Tirrell, David A.
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