Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides [PDF]
Nature Communications, 2019 Vinyl azides generally act as 3-atom synthon through the fast release of molecular nitrogen, whereas keeping the azide group intact is more challenging. Here, the authors show a copper-catalyzed enantioselective cycloaddition of two types of vinyl azides
Nuligonda Thirupathi +3 more
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Electrochemically Induced Synthesis of Imidazoles from Vinyl Azides and Benzyl Amines [PDF]
Molecules, 2022 An electrochemically induced synthesis of imidazoles from vinyl azides and benzyl amines was developed. A wide range of imidazoles were obtained, with yields of 30 to 64%.
Vera A. Vil’ +2 more
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Vinyl azides in organic synthesis: an overview. [PDF]
RSC Adv, 2023 This review focuses on the application of vinyl azide in organic synthesis and highlights new strategies and methods using this compound to produce heterocycles and other organic compounds.
Gholami F +3 more
europepmc +3 more sources
A sustainable strategy for the straightforward preparation of 2H-azirines and highly functionalized NH-aziridines from vinyl azides using a single solvent flow-batch approach [PDF]
Beilstein Journal of Organic Chemistry, 2021 The reported flow-batch approach enables the easy preparation of 2H-azirines and their stereoselective transformation into highly functionalized NH-aziridines, starting from vinyl azides and organolithium compounds.
Michael Andresini +2 more
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[3 + 2]-Cycloadditions of nitrile ylides after photoactivation of vinyl azides under flow conditions [PDF]
Beilstein Journal of Organic Chemistry, 2013 The photodenitrogenation of vinyl azides to 2H-azirines by using a photoflow reactor is reported and compared with thermal formation of 2H-azirines. Photochemically, the ring of the 2H-azirines was opened to yield the nitrile ylides, which underwent a [3
Stephan Cludius-Brandt +2 more
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Multistep flow synthesis of vinyl azides and their use in the copper-catalyzed Huisgen-type cycloaddition under inductive-heating conditions [PDF]
Beilstein Journal of Organic Chemistry, 2011 The multistep flow synthesis of vinyl azides and their application in the synthesis of vinyltriazoles is reported. The synthesis relies on a stable polymer-bound equivalent of iodine azide that serves to carry out 1,2-functionalization of alkenes in a ...
Lukas Kupracz +4 more
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Vinyl-aza-[3]cumulene intermediates induced polymerization for accessing E-dienyl poly(sulfonylamidines) towards pH-responsive drug delivery [PDF]
Nature CommunicationsThe development of reactive intermediates is very significant to construct functional compounds and polymers for multicomponent reactions and multicomponent polymerizations. Heterocumulenes as unique intermediates could be used for the rapid construction
Xuejian Li +3 more
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Catalyst-Free Synthesis of 2,4-Disubstituted‑1H‑imidazoles through [3 + 2] Cyclization of Vinyl Azides with Amidines [PDF]
ACS Omega, 2017 N. Naresh Kumar Reddy +3 more
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Linking of Alcohols with Vinyl Azides [PDF]
Organic Letters, 2016 A protocol to link alcohols with vinyl azides has been established through fluoro- or bromo-alkoxylation of vinyl azides to provide α-alkoxy-β-haloalkyl azides. A series of primary and secondary alcohols including natural products and their derivatives such as sugars and steroids were successfully anchored with vinyl azides. The as-prepared cyanine dye
Wang, Yi-Feng +4 more
openaire +3 more sources
Frontiers in Chemistry, 2022 A chemodivergent photocatalytic approach to 1-pyrrolines and 1-tetralones from alkyl bromides and vinyl azides has been developed through chemoselectively controllable intermolecular [3 + 2] and [4 + 2] cyclization.
Shijing Tu +9 more
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