Linking of Alcohols With Vinyl Azides [PDF]
Organic Letters, 2016 A protocol to link alcohols with vinyl azides has been established through fluoro- or bromo-alkoxylation of vinyl azides to provide α-alkoxy-β-haloalkyl azides.
Ming Hu, Bengang Xing, Yi-Feng Wang
exaly +5 more sources
Application of Vinyl Azides in Chemical Synthesis: A Recent Update [PDF]
Journal of Organic Chemistry, 2017 Among organic azides, vinyl azides have shown versatile chemical reactivities in the recent development of new synthetic methodologies mainly for nitrogen-containing molecules. This synopsis highlights and discusses recent advances on use of vinyl azides
Atsushi Kaga, Shunsuke Chiba
exaly +5 more sources
Electrochemically Induced Synthesis of Imidazoles from Vinyl Azides and Benzyl Amines [PDF]
Molecules, 2022 An electrochemically induced synthesis of imidazoles from vinyl azides and benzyl amines was developed. A wide range of imidazoles were obtained, with yields of 30 to 64%.
Vera A. Vil’ +2 more
doaj +2 more sources
Vinyl azides in organic synthesis: an overview. [PDF]
RSC Adv, 2023 This review focuses on the application of vinyl azide in organic synthesis and highlights new strategies and methods using this compound to produce heterocycles and other organic compounds.
Gholami F +3 more
europepmc +3 more sources
A sustainable strategy for the straightforward preparation of 2H-azirines and highly functionalized NH-aziridines from vinyl azides using a single solvent flow-batch approach [PDF]
Beilstein Journal of Organic Chemistry, 2021 The reported flow-batch approach enables the easy preparation of 2H-azirines and their stereoselective transformation into highly functionalized NH-aziridines, starting from vinyl azides and organolithium compounds.
Michael Andresini +2 more
doaj +2 more sources
Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides [PDF]
Nature Communications, 2019 Vinyl azides generally act as 3-atom synthon through the fast release of molecular nitrogen, whereas keeping the azide group intact is more challenging. Here, the authors show a copper-catalyzed enantioselective cycloaddition of two types of vinyl azides
Nuligonda Thirupathi +3 more
doaj +2 more sources
Mn(iii)-Catalyzed Radical Reactions of 1,3-Dicarbonyl Compounds and Cyclopropanols with Vinyl Azides for Divergent Synthesis of Azaheterocycles [PDF]
CHIMIA, 2012 Mn(iii)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols.
Shunsuke Chiba
doaj +2 more sources
[3 + 2]-Cycloadditions of nitrile ylides after photoactivation of vinyl azides under flow conditions [PDF]
Beilstein Journal of Organic Chemistry, 2013 The photodenitrogenation of vinyl azides to 2H-azirines by using a photoflow reactor is reported and compared with thermal formation of 2H-azirines. Photochemically, the ring of the 2H-azirines was opened to yield the nitrile ylides, which underwent a [3
Stephan Cludius-Brandt +2 more
doaj +2 more sources
Multistep flow synthesis of vinyl azides and their use in the copper-catalyzed Huisgen-type cycloaddition under inductive-heating conditions [PDF]
Beilstein Journal of Organic Chemistry, 2011 The multistep flow synthesis of vinyl azides and their application in the synthesis of vinyltriazoles is reported. The synthesis relies on a stable polymer-bound equivalent of iodine azide that serves to carry out 1,2-functionalization of alkenes in a ...
Lukas Kupracz +4 more
doaj +2 more sources
α-Substituted vinyl azides: An emerging functionalized alkene [PDF]
Chemical Society Reviews, 2017 Vinyl azides are highly versatile synthons that provide access to numerous N-heterocycles and other functional groups. a-Substituted vinyl azides (azido vinylidenes) are a special class that display unique reactivity, able to react not only as azides ...
Xihe Bi +7 more
core +6 more sources