Results 21 to 30 of about 5,840 (188)

Continuous multistep synthesis of 2-(azidomethyl)oxazoles

open access: yesBeilstein Journal of Organic Chemistry, 2018
An efficient three-step protocol was developed to produce 2-(azidomethyl)oxazoles from vinyl azides in a continuous-flow process. The general synthetic strategy involves a thermolysis of vinyl azides to generate azirines, which react with bromoacetyl ...
Thaís A. Rossa   +4 more
doaj   +1 more source

Intramolecular Azide to Alkene Cycloadditions for the Construction of Pyrrolobenzodiazepines and Azetidino-Benzodiazepines [PDF]

open access: yes, 2014
The coupling of proline- and azetidinone-substituted alkenes to 2-azidobenzoic and 2-azidobenzenesulfonic acid gives precursors that undergo intramolecular azide to alkene 1,3-dipolar cycloadditions to give imine-, triazoline- or aziridine-containing ...
Antonow   +9 more
core   +2 more sources

Click Chemistry in Materials Science [PDF]

open access: yes, 2014
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/106803/1/adfm201302847 ...
Bowman, Christopher N.   +3 more
core   +1 more source

Reactive precursor particles as synthetic platform for the generation of functional nanoparticles, nanogels, and microgels [PDF]

open access: yes, 2019
Precise control of the chemical functionality of polymer nanoparticles is a key requirement in tailoring their (dynamic) colloidal properties toward advanced applications.
Gruber, Alexandra   +2 more
core   +1 more source

Azetidinylideneketenimines as a Multimodal Synthetic Platform: Coordination Chemistry and Cycloaddition‐Triggered Transformations

open access: yesAngewandte Chemie, EarlyView.
Cross‐coupling/homologation sequence between a stable three‐membered‐ring carbene and isocyanides enables facile and rapid access to novel methyleneketenimines and the first bis(methyleneketenimine). Reactivity studies gave rise to the first methyleneketenimine‐transition metal complexes, unique multimodal reactivity ranging from CO2, isocyanate ...
Taichi Koike   +3 more
wiley   +2 more sources

Core-Clickable PEG-Branch-Azide Bivalent-Bottle-Brush Polymers by ROMP: Grafting-Through and Clicking-To [PDF]

open access: yes, 2011
The combination of highly efficient polymerizations with modular "click" coupling reactions has enabled the synthesis of a wide variety of novel nanoscopic tructures.
Burts, Alan O.   +8 more
core   +2 more sources

Expeditious diastereoselective synthesis of elaborated ketones via remote Csp3–H functionalization

open access: yesNature Communications, 2017
C-H activation is a powerful method to form functionalised molecules, but is particularly challenging for unactivated sp3sites. Here the authors report a directing-group-free radical cascade process for converting vinyl azides and carboxylic acids to ...
Wei Shu   +3 more
doaj   +1 more source

Sulfonylative and azidosulfonylative cyclizations by visible-light-photosensitization of sulfonyl azides in THF [PDF]

open access: yes, 2017
The generation of sulfonyl radicals from sulfonyl azides using visible light and a photoactive iridium complex in THF is described. This process was used to promote sulfonylative and azidosulfonylative cyclizations of enynes to give several classes of ...
Angnes   +45 more
core   +1 more source

Water-mediated synthesis of disubstituted 5-aminopyrimidines from vinyl azides under microwave irradiation

open access: yesGreen Chemistry Letters and Reviews, 2018
An efficient and ecofriendly method for the synthesis of disubstituted 5-aminopyrimidines from vinyl azides and urea or thiourea was developed. This reaction proceeds under microwave irradiation conditions in the presence of water as a solvent.
Oussama Dehbi   +8 more
doaj   +1 more source

Copper Nanoparticles in Click Chemistry [PDF]

open access: yes, 2015
Conspectus: The challenges of the 21st century demand scientific and technological achievements that must be developed under sustainable and environmentally benign practices.
Alonso, Francisco   +2 more
core   +2 more sources

Home - About - Disclaimer - Privacy