Results 11 to 20 of about 5,840 (188)

α-Substituted vinyl azides: an emerging functionalized alkene [PDF]

Chemical Society Reviews, 2017
Vinyl azides are highly versatile synthons that provide access to numerous N-heterocycles and other functional groups.
Junkai Fu, Giuseppe Zanoni, Edward A. Anderson, Xihe Bi   +3 more
openaire   +6 more sources

Amide Synthesis by Nucleophilic Attack of Vinyl Azides

Angewandte Chemie, 2014
AbstractA method for the synthesis of amide‐containing molecules was developed using vinyl azides as an enamine‐type nucleophile towards carbon electrophiles, such as imines, aldehydes, and carbocations that were generated from alcohols in the presence of BF3⋅OEt2.
Zhang, Feng-Lian, Wang, Yi-Feng, Lonca, Geoffroy Hervé, Zhu, Xu, Chiba, Shunsuke   +4 more
openaire   +5 more sources

Visible-light sensitization of vinyl azides by transition-metal photocatalysis. [PDF]

Angew Chem Int Ed Engl, 2014
Farney EP, Yoon TP.
europepmc   +2 more sources

Mn(iii)-Catalyzed Radical Reactions of 1,3-Dicarbonyl Compounds and Cyclopropanols with Vinyl Azides for Divergent Synthesis of Azaheterocycles

CHIMIA, 2012
Mn(iii)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols.
Shunsuke Chiba
doaj   +1 more source

Radical cyanomethylation via vinyl azide cascade-fragmentation [PDF]

Chemical Science, 2019
The cyanomethylation of radicals with a vinyl azide reagent is described, via a cascade-fragmentation mechanism.
James R. Donald, Sophie L. Berrell
openaire   +4 more sources

Synthetic chemistry and biological activity of pentafluorosulphanyl (SF5) organic molecules [PDF]

, 2012
Acknowledgements We thank the European Commission for financial support (Industry Academia Partnerships and Pathways project “PET BRAIN”, Contract No 251482). S.A.
Altomonte, Stefano, Zanda, Matteo
core   +1 more source

Bortrifluorid-katalysierte Umsetzung von 2H-Azirinen und Vinylaziden mit Nitrilen

CHIMIA, 1975
The reaction of 2H-azirines or vinyl azides with nitriles in the presence of boron trifluoride etherate, to yield the corresponding imidazoles (see table), is described.
Heinz Bader, Hans-Jürgen Hansen
doaj   +1 more source

Ruthenium-catalyzed azide alkyne cycloaddition reaction: scope, mechanism and applications [PDF]

, 2016
The ruthenium-catalyzed azide alkyne cycloaddition (RuAAC) affords 1,5-disubstituted 1,2,3-triazoles in one step and complements the more established copper-catalyzed reaction providing the 1,4-isomer.
Akimova G., Akimova G., Akimova G., Anna Said Stålsmeden, Bader R. F. W., Chandrasekaran S., Das R., Fan W.-Q., Fokin V. V., Gruchlik A., Huisgen R., Johan R. Johansson, Keicher T., Levin J. I., Murahashi S.-I., Neumajer G., Nina Kann, Palaniraja J., Parsons J. G., Schilling C., Tamás Beke-Somfai, Trabocchi A., Yubo J., Zhou Y. B.   +23 more
core   +2 more sources

Copper-Catalyzed Amination of Vinyl Azides to α-Ketoamides

SynOpen, 2019
An efficient approach for the amination of vinyl azides with N,N-dialkylacylamides has been developed. By using this protocol, structurally important α-ketoamides can be easily synthesized.
Yu Wang, Dongling Zhang, Kaining Zhang, Zhenhua Liu, Jing Lin, Wei Cao, Zhongxue Fang   +6 more
doaj   +1 more source

Advances in chemical protein modification. [PDF]

, 2015
Chemical protein modification has emerged as an invaluable tool for the development of modified proteins. The complementary use of both genetic and chemical methods has provided a large toolbox that allows the preparation of almost unlimited protein ...
Bernardes, Gonçalo JL, Boutureira, Omar
core   +2 more sources