Synthesis of Polysubstituted N-H Pyrroles from Vinyl Azides and 1,3-Dicarbonyl Compounds
, 2016 Two synthetic methods for tetra- and trisubstituted N-H pyrroles are presented: (i) the thermal pyrrole formation by the reaction of vinyl azides with 1,3-dicarbonyl compounds via the 1,2-addition of 1,3-dicarbonyl compounds to 2H-azirine intermediates ...
Guillaume Lapointe (2168788) +3 more
core +6 more sources
Taming Unhindered Alkyl Azides by Intramolecular Hydrogen-Azide Interaction for Discriminative Conjugation onto Alkyl Diazides [PDF]
, 2021 We report herein the unique reactivities of α-azido secondary acetamides (α-AzSAs) as minimal and unhindered azide structures. The NH–azide interaction in the α-AzSAs, supposed by DFT calculation, allowed selective conjugation in the presence of other ...
Koshiro, Maegawa +5 more
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Molecules, 2020 Synthesis of new chromium(II) complexes with chelating bis(alkoxide) ligand [OO]Ph (H2[OO]Ph = [1,1′:4′,1′’-terphenyl]-2,2′’-diylbis(diphenylmethanol)) and their subsequent reactivity in the context of catalytic ...
Sudheer S. Kurup +3 more
doaj +1 more source
Allylic Azides: Versatile Building Blocks to Heterocycles [PDF]
, 2021 University of Minnesota Ph.D. dissertation. May 2021. Major: Chemistry. Advisor: Joseph Topczewski. 1 computer file (PDF); x, 99 pages + 1 supplementary file.Organic azides are versatile building blocks because they can be derivatized to a variety of ...
Liu, En-Chih
core
TfNN15N: A γ-15N‑Labeled Diazo-Transfer Reagent for the Synthesis of β-15N‑Labeled Azides
, 2021 Azides are infrared (IR) probes that are important for structure and dynamics studies of proteins. However, they often display complex IR spectra owing to Fermi resonances and multiple conformers.
Minhaeng Cho +7 more
core +1 more source
Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides
Nature Communications, 2019 Vinyl azides generally act as 3-atom synthon through the fast release of molecular nitrogen, whereas keeping the azide group intact is more challenging. Here, the authors show a copper-catalyzed enantioselective cycloaddition of two types of vinyl azides
Nuligonda Thirupathi +3 more
doaj +1 more source
Recent Applications and Developments of Organic Azides in Total Synthesis of Natural Products
Natural Product Communications, 2013 Organic azides have been exploited since their discovery because of their high reactivities. Various organic reactions using azides have been synthetically applied in chemical biology pharmaceuticals medicinal and agricultural areas.
Hiroki Tanimoto, Kiyomi Kakiuchi
doaj +1 more source
Beilstein Journal of Organic Chemistry, 2010 The reactions of group 13 metal trichlorides with aromatic azides were examined by CW EPR and pulsed ENDOR spectroscopies. Complex EPR spectra were obtained from reactions of aluminium, gallium and indium trichlorides with phenyl azides containing a ...
Giorgio Bencivenni +4 more
doaj +1 more source
Overview of 1,5-Selective Click Reaction of Azides with Alkynes or Their Synthetic Equivalents
Molecules, 2023 Nowadays, the click reaction of azides with alkynes has evolved rapidly and become one of the most efficient methods to synthesize 1,2,3-triazoles, which are an important class of N-containing heterocycles.
Yaqi Zhao +3 more
doaj +1 more source
TfNN15N: A -15NLabeled Diazo-Transfer Reagent for the Synthesis of -15NLabeled Azides
, 2021 Azides are infrared (IR) probes that are important for structure and dynamics studies of proteins. However, they often display complex IR spectra owing to Fermi resonances and multiple conformers.
Hyeok-Jun Kwon +9 more
core +1 more source