Results 11 to 20 of about 3,914,198 (256)

Stereospecific cationic RAFT polymerization of bulky vinyl ethers and stereoblock poly(vinyl alcohol) via mechanistic transformation to radical RAFT polymerization of vinyl acetate

open access: yesGiant, 2021
The simultaneous control of molecular weight and tacticity in cationic polymerization remains challenging. Here, we propose a new approach for stereospecific living cationic polymerization by combining cationic reversible addition-fragmentation chain ...
Mineto Uchiyama   +2 more
doaj   +1 more source

An isatin aldol adduct as a precursor to α,α’-difunctionalized methyl vinyl ketones

open access: yesResults in Chemistry, 2022
Isatin-methyl vinyl ketone aldol adducts underwent efficient Morita–Baylis–Hillman (MBH) and Rauhut–Currier (RC) reactions under mild conditions to bring about a functionalization of the olefinic α-carbon, and thereby α,α’-difunctionalization of methyl ...
Ajit Kumar Jha   +3 more
doaj   +1 more source

Aqueous DMSO Mediated Conversion of (2-(Arylsulfonyl)vinyl)iodonium Salts to Aldehydes and Vinyl Chlorides

open access: yesMolecules, 2016
Vinyl(aryl)iodonium salts are useful compounds in organic synthesis but they are under-utilized and their chemistry is under-developed. Herein is described the solvolysis of some vinyl(phenyl)iodonium salts, bearing an arylsulfonyl group, in aqueous DMSO
Eman Zawia, Wesley J. Moran
doaj   +1 more source

Proton-Electron Hyperfine Coupling Constants of the Chlorophyll a Cation Radical by ENDOR Spectroscopy [PDF]

open access: yes, 1977
In this paper we describe the assignment of the major coupling constants in monomer chlorophyll a cation free radical by ENDOR spectroscopy. To facilitate chemical manipulation methylpyrochlorophyllide a has been used as a stand-in, and a suite of six ...
Katz, J. J., Norris, J. R., Scheer, Hugo
core   +1 more source

Variability in Bulb Organosulfur Compounds, Sugars, Phenolics, and Pyruvate among Greek Garlic Genotypes: Association with Antioxidant Properties

open access: yesAntioxidants, 2020
In order to assess the diversity of Greek garlic (Allium sativum L.) landraces, 34 genotypes including commercial ones were grown in the same field and their content in organosulfur compounds, pyruvate, total sugars, and total phenolics, alongside ...
Ioanna Avgeri   +5 more
doaj   +1 more source

Synthesis and Study of the Antimicrobial Activity of Modified Polyvinyl Alcohol Films Incorporated with Silver Nanoparticles

open access: yesمجلة بغداد للعلوم, 2023
       A new class of biologically active nanocomposites and modified polymers based on poly (vinyl alcohol) (PVA) with some organic compounds [II, IV, V and VI] were synthesized using silver nanoparticles (Ag-NPs).
Basma J. Ahmed   +2 more
doaj   +1 more source

Synthesis and Anticancer Activity of Some New S-Glycosyl and S-Alkyl 1,2,4-Triazinone Derivatives

open access: yesMolecules, 2011
A series of S-glycosyl and S-alkyl derivatives of 4-amino-3-mercapto-6-(2-(2-thienyl)vinyl)-1,2,4-triazin-5(4H)-one (1) were synthesized using different halo compounds such as preacetylated sugar bromide, 4-bromobutylacetate, 2-acetoxyethoxy-methyl ...
Hosam A. Saad, Ahmed H. Moustafa
doaj   +1 more source

Photostabilization of Poly(vinyl chloride) by Organotin(IV) Compounds against Photodegradation

open access: yesMolecules, 2019
Poly(vinyl chloride) (PVC), a polymer widely used in common household and industrial materials, undergoes photodegradation upon ultraviolet irradiation, leading to undesirable physicochemical properties and a reduced lifetime.
Angham G. Hadi   +6 more
semanticscholar   +1 more source

Mn(iii)-Catalyzed Radical Reactions of 1,3-Dicarbonyl Compounds and Cyclopropanols with Vinyl Azides for Divergent Synthesis of Azaheterocycles

open access: yesCHIMIA, 2012
Mn(iii)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols.
Shunsuke Chiba
doaj   +1 more source

Fire Retardancy of Vinyl Ester Nanocomposites: Synergy with Phosphorus-Based Fire Retardants [PDF]

open access: yes, 2005
Vinyl ester (PVE) nanocomposites were prepared using both clay and polyhedral oligosilsesquioxanes (POSS) as the nano-dimensional material. From cone calorimetric data, it was shown that both POSS and clay affect the flammability of the nanocomposites to
Chigwada, Grace   +3 more
core   +2 more sources

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