Results 11 to 20 of about 146,026 (303)
Investigations on vinylene carbonate, 2. Copolymerization with N-vinyl-2-pyrrolidone and ethyl vinyl ether [PDF]
Functional monomers and polymers have received considerable attention in recent years, especially in the biomedical field. In this respect, poly(viny1ene carbonate) is very interesting, because the reactive carbonate groups offer the possibility of ...
Bantjes, Adriaan +3 more
core +7 more sources
Vinyl(aryl)iodonium salts are useful compounds in organic synthesis but they are under-utilized and their chemistry is under-developed. Herein is described the solvolysis of some vinyl(phenyl)iodonium salts, bearing an arylsulfonyl group, in aqueous DMSO
Eman Zawia, Wesley J. Moran
doaj +1 more source
In order to assess the diversity of Greek garlic (Allium sativum L.) landraces, 34 genotypes including commercial ones were grown in the same field and their content in organosulfur compounds, pyruvate, total sugars, and total phenolics, alongside ...
Ioanna Avgeri +5 more
doaj +1 more source
A new class of biologically active nanocomposites and modified polymers based on poly (vinyl alcohol) (PVA) with some organic compounds [II, IV, V and VI] were synthesized using silver nanoparticles (Ag-NPs).
Basma J. Ahmed +2 more
doaj +1 more source
Synthesis and Anticancer Activity of Some New S-Glycosyl and S-Alkyl 1,2,4-Triazinone Derivatives
A series of S-glycosyl and S-alkyl derivatives of 4-amino-3-mercapto-6-(2-(2-thienyl)vinyl)-1,2,4-triazin-5(4H)-one (1) were synthesized using different halo compounds such as preacetylated sugar bromide, 4-bromobutylacetate, 2-acetoxyethoxy-methyl ...
Hosam A. Saad, Ahmed H. Moustafa
doaj +1 more source
Mn(iii)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols.
Shunsuke Chiba
doaj +1 more source
Vinyl sulfones: selective and tunable covalent warheads against challenging enzyme targets [PDF]
Over the past several decades there has been a growing recognition of the role that covalent drug candidates have played in the drug development process. With this recognition, compounds that are capable of selectively and irreversibly inactivating their
Ronald E. Viola
doaj +1 more source
Vinyl Polymerizationby Organocalcium Compound.
カルシウムテトラエチル亜鉛CaZn(C2H5)4が,スチレン,メタクリル酸メチルおよびアクリロニトリルなどのビニル化合物に対して有効な重合触媒となることがわかった。カルシウムテトラエチル亜鉛は,Gilmanの方法によって,ジェチル亜鉛とカルシウム金属とから合成した。酢酸ビニル,塩化ビニル,アクリル酸メチルなどはこの触媒では重合しなかった。酸素,キノン類などはこの重合を抑制した。メタクリル酸メチルとスチレンとの共重合では,典型的な「陰イオン的」単量体反応性比が見出された。動力学的研究の結果,見かけの活性化エネルギーの値はかなり小であり,また1分子停止機構が妥当と考えられる。これらの事実の重合反応が陰イオン機構によっていることを支持する。この触媒によって得られたポリスチレンについて,赤外吸収スペクトル ...
Junji Furukawa +3 more
openaire +2 more sources
Phosphoranaloga von Aminosäuren und Peptiden: Kettenverlängerung von Carbonylverbindungen
Synthesis of carbonyl compounds 5 involving the Wittig-Horner reaction of diethyl-1-isocyanoalkylphosphonate 1 with carbonyl compounds 2 and subsequent hydrolysis of the vinyl isocyanides 3 formed is reported.
Janusz Rachoń
doaj +1 more source
Oxycyanation of Vinyl Compounds
イソプチレン, スチレン, 塩化ビニル, アクリロニトリルならびにベンゼンのナキシシアン化反応を行なった。イソブチレンからはβ,β-ジメチルアクリロニトリルが生成した。イソブチレンのオキシシアン化反応の動力学的挙動はエチレンに似ている。スチレンからは cis-β-ならびに trans-β-フェニルアクリロニトリルが生成した。塩化ビニルからはα-, cis-β- ならびに trans-β-クロロアクリロニトリルが得られた。β-クロロアクリロニトリルより逐次的にフマロニトリルが生成した。アクリロニトリルのオキシシアン化によりフマロニトリルが得られたが, その量は塩化ビニルのオキシシアン化により得られたフマロニトリルよりぎわめて少なかった。ベンゼンよりベンゾニトリルが得られた ...
Naoya KOMINAMI +3 more
openaire +2 more sources

