Cobalt‐Catalyzed [2σ+2π] Cycloaddition via Site‐Selective Capture of Bicyclobutane Diradical
We report a Co(II)‐catalyzed strategy that combines thermal activation of bicyclo[1.1.0]butane (BCBs) with site‐selective radical capture to furnish head‐to‐head fused bicyclo[2.1.1]hexanes via [2σ+2π] cycloaddition with indoles. Detailed mechanistic studies (31P NMR, EPR, CV, and DFT) support the catalytic pathway, while phosphine‐oxide trapping and X‐
Tanmayee Nanda +8 more
wiley +1 more source
Enhanced photostability of vitamin B<sub>2</sub> incorporated nanofibrous membrane via covalent modification for antimicrobial photodynamic inactivation. [PDF]
Ma Y +9 more
europepmc +1 more source
Gold Single‐Atom Catalysts Enable Selective Shuttle Hydrochlorination of Alkynes
Gold single‐atom catalysts on activated carbon enable heterogeneous shuttle hydrochlorination of terminal alkynes to vinyl chlorides with high chemo‐ and stereo‐selectivity thanks to cooperation between Au(I) sites and the support. The catalytic system combines broad substrate compatibility, simplified separation, and recoverability, paving the way for
Marc‐Eduard Usteri +8 more
wiley +1 more source
Maternal supplementation of vitamin B<sub>12</sub> in predominantly vegetarian pregnant women improves their vitamin B<sub>12</sub> status and the neurodevelopment of their infants: the MATCOBIND multicentric double-blind randomised control trial. [PDF]
Nagpal J +15 more
europepmc +1 more source
Vitamin B supplementation enhances the efficacy of non-steroidal anti-inflammatory drugs in patients with painful foot and ankle conditions: A multicenter, prospective, randomized controlled trial. [PDF]
Song MG +4 more
europepmc +1 more source
Scottish Seaweeds as Sustainable Sources of Micronutrients: Mineral Composition, Vitamin B<sub>12</sub> Content, and Safety Assessment. [PDF]
Almosa I, Bashir S, Sneddon AA.
europepmc +1 more source
A vitamin B<sub>3</sub>-driven root bacterial metabolite primes systemic immunity in <i>Arabidopsis</i>. [PDF]
Wang X +14 more
europepmc +1 more source
Vitamin B<sub>12</sub> deficiency in long-term metformin use and clinician awareness: a scoping review. [PDF]
Parsonage I, Wainwright D, Barratt J.
europepmc +1 more source
Identification, functional characterization of a novel flavohemoglobin from Ensifer adhaerens and its application to enhancing vitamin B<sub>12</sub> production. [PDF]
Zhu J +6 more
europepmc +1 more source
Associations between Biomarkers of Vitamin B<sub>12</sub> Status and Gut Microbial Guilds in a Cohort of Australian Adults. [PDF]
Rittmann M +7 more
europepmc +1 more source

