Results 61 to 70 of about 25,997 (250)

Resolving passive heat transfer and phase‐change heat in cryogenic CO2 deposition (Desublimation) from CO2/N2 mixtures

open access: yesAIChE Journal, EarlyView.
Abstract In cryogenic CO2 desublimation systems where phase change dominates both heat transfer and separation, conventional lumped thermal‐resistance treatments embed interfacial latent heat into an overall heat‐transfer coefficient, obscuring how phase‐change heat is partitioned between the gas phase and the coolant and limiting diagnostic insight ...
Shengwen Xiao   +2 more
wiley   +1 more source

A Wagner–Meerwein‐Like Rearrangement Generates a Vinyl Group in the Biosynthesis of the Polychlorinated Lipopeptides Fischerazoles

open access: yesAngewandte Chemie, EarlyView.
The fischerazoles, unusual cyanobacterial chlorinated lipopeptides are reported. During their biosynthesis, a linear fatty acyl‐acyl carrier protein (ACP) precursor is rearranged through the action of the S‐adenosyl‐methionine (SAM)‐dependent methyltransferase FshF, to generate a pendant vinyl group.
Sandra A. C. Figueiredo   +8 more
wiley   +2 more sources

Cell Segmentation Beyond 2D—A Review of the State‐of‐the‐Art

open access: yesAdvanced Intelligent Discovery, EarlyView.
Cell segmentation underpins many biological image analysis tasks, yet most deep learning methods remain limited to 2D despite the inherently 3D nature of cellular processes. This review surveys segmentation approaches beyond 2D, comparing 2.5D and fully 3D methods, analyzing 31 models and 32 volumetric datasets, and introducing a unified reference ...
Fabian Schmeisser   +6 more
wiley   +1 more source

Biosynthesis and Genetic Tuning of Guanine Crystals via Metabolic Engineering of Yeast

open access: yesAngewandte Chemie, EarlyView.
We demonstrate how yeast cells can be harnessed as cellular factories for the synthesis of optically functional guanine crystals, where genetic editing is used to tune crystal size, order and optical properties. This demonstrates a powerful new biosynthetic approach for the development of sustainable and biocompatible optical pigments, which utilizes ...
Jerome N. Janssen   +11 more
wiley   +2 more sources

Crisis and Correspondence: Style in the Nineteenth Century

open access: yesArchitectural Histories, 2013
In his manifesto 'Das Kunstwerk der Zukunft' (1850), Richard Wagner characterised the nineteenth century as a time of crisis. Echoing Saint-Simon, he defined this crisis as a discrepancy between the spirit of the age and the actual, historical conditions.
Mari Hvattum
doaj   +1 more source

Integrating developmental and macroevolutionary approaches reveals a staminodial origin of all alternisepalous organs in Caryophyllaceae

open access: yesAmerican Journal of Botany, EarlyView.
Abstract Premise The identity of sterile floral organs in second‐whorl, alternisepalous positions within Caryophyllaceae remains contentious, having been described as staminodes, “petaloids,” or petals homologous with those of other Pentapetalae. Limited ingroup and outgroup sampling and floral developmental data and inadequate phylogenetic comparative
Riley J. Rees   +2 more
wiley   +1 more source

Dyotropic Rearrangement of Hypervalent Iodine Species: Migrative Heterofunctionalization of Quaternary Carbons

open access: yesAngewandte Chemie, EarlyView.
1,2‐Aryl migration involving in situ‐generated alkyl iodine(III) species proceeds through a previously unrecognized 1,2‐C/I(III) dyotropic rearrangement. Migratory aryl fluorination, acetoxylation, and alkoxylation of 2‐alkyl‐2‐aryl‐3‐iodopropanoates provide α‐heterofunctionalized products, accompanied by aryl migration from the α‐ to the β‐position ...
Chen‐Xu Liu   +3 more
wiley   +2 more sources

Max Weber’s Analysis of Plebiscitary Leadership and the Debate on Multiple Modernities

open access: yesСоциология власти
The article considers Max Weber's model of plebiscitary leadership and historical examples of plebiscitary democracy. It is argued that there is no clear distinction between plebiscitary democracy and dictatorship in Weber's writings.
Mikhail V. Maslovskiy
doaj   +1 more source

Unpleasant Operas or French Music Drama as Heard by Corno Di Bassetto

open access: yesCahiers Victoriens et Edouardiens, 2017
The status of George Bernard Shaw as an opera critic—a position he filled under the pen-name ‘Corno Di Bassetto’ in different periodicals such as The Star and The World—has been somewhat overlooked in the canon of late Victorian journalism.
Eduardo Valls Oyarzun
doaj   +1 more source

Application of a novel schema for describing fossil fern foliage and investigating taxonomic and morphological change across the Cretaceous–Paleogene boundary in western North America

open access: yesAmerican Journal of Botany, EarlyView.
Abstract Premise The Chicxulub asteroid impact at the Cretaceous–Paleogene (K–Pg) boundary triggered a mass extinction 66 million years ago. Ferns thrived in the aftermath of the extinction, evidenced by the well‐documented “fern spore spike.” However, fern macrofossil records across the K–Pg boundary are less understood.
Fern B. Holian   +9 more
wiley   +1 more source

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