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Individual extraction constants of some organic cations in the two-phase water–nitrobenzene system
Journal of Radioanalytical and Nuclear Chemistry, 2010From extraction experiments and c-activity measurements, the exchange extraction constants corre- sponding to the general equilibrium C ? (aq) ? Cs ? (nb) , C ? (nb) ? Cs ? (aq) taking part in the two-phase water- nitrobenzene system (C ? = organic cation; aq = aqueous phase, nb = nitrobenzene phase) were evaluated.
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From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+(aq) + NaL+(nb) ⇔ ML+(nb) + Na+(aq) taking place in the two–phase water–nitrobenzene system (M+ = Li+, K+, Rb+, Cs+; L = benzo-18-crown-6; aq = aqueous phase, nb = nitrobenzene phase) were evaluated.
E. Makrlík, P. Vaňura
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