Results 21 to 30 of about 5,457 (167)

Contribution to the thermodynamics of 1-(2-thiazolylazo)-2-naphthol in the water-nitrobenzene extraction system [PDF]

Journal of the Serbian Chemical Society, 2000
General relations among thermodynamic parameters characterizing chemical equilibria including species H2A+, HA, H+ and A- in both phases of a two-phase water-nitrobenzene extraction system have been derived.
PETR VANURA, EMANUEL MAKRLIK
doaj  

Degradação de espécies nitroaromáticas e remediação de efluentes da indústria de explosivos, utilizando-se processos redutivos-oxidativos fundamentados no uso de ferro metálico Degradation of nitroaromatic compounds and remediation of residues from the explosive production by reductive-oxidative processes based on zero-valent iron

Química Nova, 2009
In this work the potentiality of reductive-oxidative processes based on zero-valent iron was studied aiming the degradation of nitroaromatic compounds and the remediation of residues from the explosive industry.
Luiz Fernando Rocha Cavalotti, Patricio Peralta-Zamora, Marcio Barreto Rodrigues, Teresa Cristina Brazil de Paiva   +3 more
doaj   +1 more source

Recent Advances in Carbon Cathode Materials toward High‐Performing Zinc‐Ion Hybrid Supercapacitors

Advanced Science, EarlyView.
Aqueous zinc‐ion hybrid supercapacitors (ZHSCs) have emerged as promising next‐generation electrochemical energy‐storage devices. Porous carbon materials have been extensively studied as cathodes, with advances in tailoring pore structures and material properties to enhance performance.
Take Hirooka, Zhaolin Liu, Ivan P. Parkin, Guanjie He   +3 more
wiley   +1 more source

Molecular Design Strategies for High‐Voltage Organic Cathodes

Advanced Energy Materials, EarlyView.
This work proposes molecular engineering strategies for high‐voltage organic cathode materials for Li‐ion batteries: (1) increase Li‐O coordination number (CN), (2) achieve a greater increase in aromaticity upon reduction (∆Aromaticity), and (3) add an electron‐withdrawing group (EWG), through a combined experimental and computational study on reported
Sungil Hong, Alae Eddine Lakraychi, Artur Lyssenko, Abhishek Ashwin Panchal, Harshan Reddy Gopidi, Pieremanuele Canepa, Rafael Gómez‐Bombarelli, Yan Yao, Rajeev Surendran Assary   +8 more
wiley   +1 more source

Molecular Engineering of Polytriphenylamine: A Fluorinated Cathode for High‐Voltage, Ultrafast, and Stable Sodium‐Ion Batteries

Advanced Energy Materials, EarlyView.
Fluorination of polytriphenylamine lowers the HOMO energy, enabling high‐voltage operation of the PFTPA cathode. Electron‐withdrawing F substituents stabilize the nitrogen redox center and suppress polarization, leading to fast kinetics. The optimized polymer delivers ∼3.75 V vs.
Natalia Voronina, Irina A. Chuyko, Michael D. Khitrov, Koji Yazawa, Hitoshi Yashiro, Yuriy N. Luponosov, Seung‐Taek Myung   +6 more
wiley   +1 more source

N,N,N’,N’-Tetrabutyl-1,10-phenanthroline-2,9-dicarboxamide as Very Effective Extraction Agent for Trivalent Europium and Americium

Acta Chimica Slovenica, 2017
Solvent extraction of microamounts of Eu3+ and Am3+ from water into nitrobenzene by means of a mixture of hydrogen dicarbollylcobaltate (H+B-) and N,N,N’,N’-tetrabutyl-1,10-phenanthroline-2,9-dicarboxamide (L) was studied.
Emanuel Makrlík, Petr Vaňura, Pavel Selucký, Vasily Babain, Dmitriy Dar'in, Mikhail Alyapyshev   +5 more
doaj   +1 more source

Extraction of Alkali-Metal Picrates by Calixarene Esters in the Water–Nitrobenzene Solvent System. The Medium Effect on the Partition and Extraction Processes

Supramolecular Chemistry, 2006
Based on distribution data involving alkali-metal (Na+, K+, Rb+ and Cs+) picrates in the presence and in the absence of calix[n]arene (n = 4, 6) esters, the extraction ability of these macrocycles in the water-nitrobenzene solvent system is established. Thus, partition and distribution constants in the mutually saturated solvents and ion-pair formation
Maria A. Pugliese, Maria T. Goitia, Mirta E. Montero, Alberto R. Casal, Angela F. Danil de Namor   +4 more
openaire   +2 more sources

Eco‐Friendly Synthesis of Cobalt Phthalocyanine for High‐Efficiency CO2${\rm CO}_{2}$ Electroreduction

Chemistry – A European Journal, EarlyView.
A sustainable synthesis of cobalt phthalocyanine (CoPc) using low‐impact solvents yields high‐performance electrocatalysts with reduced waste (E‐factor 18.6). When integrated into gas diffusion electrodes, CoPc achieves up to 12% Faradays efficiency for CO2‐to‐methanol and 65% CO2‐to‐CO conversion, aligning with state‐of‐the‐art materials and enabling ...
Gloria Zanotti, Federica Palmeri, Venanzio Raglione, Abdolhamid Khodadadi, Camille Tabaries, Jerome Capitolis, Mathieu Prevot, Laurent Piccolo, Mahmoud Zendehdel, Roberto Flammini, Giorgio Contini   +10 more
wiley   +1 more source

Extraction and DFT Study on the Complexation of Zn2+ with Beauvericin

Acta Chimica Slovenica, 2014
From extraction experiments and γ-activity measurements, the exchange extraction constant corresponding to the equilibrium Zn2+(aq) + 1 . Sr2+(nb) ⇔1 .
Emanuel Makrlík, Petr Toman, Petr Vanŭra   +2 more
doaj  

Solvent extraction of some univalent cations into nitrobenzene solution of dicarbollylcobaltate and extractants containing two or three oxyamide groups

Results in Chemistry
Stability constants of the complexes of some commercially available ligands, containing two or three oxyamide groups in nitrobenzene have been determined from the extraction data.
Petr Vaňura, Pavel Selucký
doaj   +1 more source