Toward Chromoselective Transformations in Biological Systems: Perspectives and Challenges
Controlling biological systems with small‐molecule chromophores has evolved into a powerful strategy and is applied from chemical biology to medicine. However, the complexity of in vivo systems cannot be matched by a single wavelength of light. Developing methods to combine and individually control multiple chromophores is crucial.
Nadja A. Simeth
wiley +1 more source
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve +4 more
wiley +1 more source
Polysilane‐Supported Nickel as an Efficient Catalyst for the Hydrogenation of Aromatic Compounds†
A Ni/Si catalyst obtained from the reaction of poly(monohydro)silane with Ni(cod)2 serves as an effective heterogeneous catalyst for the hydrogenation of arenes under reaction conditions that are significantly milder than those required for conventional nickel‐based catalysts such as Raney nickel.
Hiromu Baba, Yusuke Sunada
wiley +1 more source
From the exchange extraction constants corresponding to the general equilibrium M3+(aq) + 3H+(nb) M3+(nb) + 3H+(aq) occurring in the two-phase water-nitrobenzene system (M3+ = Sc3+, Y3+, La3+, Ce3+, Pr3+, Nd3+, Sm3+, Eu3+, Gd3+, Tb3+, Dy3+, Ho3+, Er3+, Tm3+, Yb3+, Lu3+; aq = aqueous phase, nb = nitrobenzene phase), the individual extraction constants ...
Makrlík, Emanuel, Vaňura, Petr
openaire +2 more sources
Toward Sustainable Carbonylation Reactions Enabled by CO Surrogates in Green Solvents
Carbonylation reactions offer a sustainable route to valuable carbonyl compounds. This review highlights methodologies that exploit carbonylative coupling to drastically enhance process sustainability, avoiding the direct use of CO through CO surrogates and promoting syntheses in green solvents potentially derived from renewable and sustainable sources.
Francesco Messa +2 more
wiley +1 more source
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis +2 more
wiley +1 more source
The recent progress in the catalytic conversion of nitroarene into amino arene catalyzed by heterogeneous metal based nano catalyst. [PDF]
Manzoor T +7 more
europepmc +1 more source
Water-Mediated Isomerization in the Stepwise Hydration of the Nitrobenzene Radical Cation with 1-6 Water Molecules. [PDF]
Christensen ZA +4 more
europepmc +1 more source
Phenazine-Based Homogeneous Photocatalysts for Visible-Light-Driven Hydrogenation of Nitroarenes Under Mild Conditions. [PDF]
Dao V, Vuong TH, Nga NK, Mejía E.
europepmc +1 more source
Eco-Friendly Synthesis of AuPd Bimetallic Nanoparticles Using <i>Alpinia zerumbet</i> for Efficient Reduction of Nitro Compounds. [PDF]
de Souza APN +10 more
europepmc +1 more source

