Results 91 to 100 of about 11,563 (263)

Solvation‐Mediated Shift From Solvent‐ to Anion‐Derived Solid Electrolyte Interphases for Stable Calcium Metal Anodes

Advanced Science, EarlyView.
An ion‐dipole interaction based strategy is proposed to capture thermodynamically unstable solvents and restructure the coordination environment of calcium ions by introducing ionic liquid co‐solvents, thus suppressing excessive solvent decomposition. Therefore, a smooth and dense solid‐electrolyte interphase dominated by inorganic components is formed
Yunyun Gao, Jinlei Zhang, Shu Yang, Mengyuan Zhou, Ruimin Li, Zhenghui Pan, Zheng‐Long Xu, Xiaowei Yang   +7 more
wiley   +1 more source

Unraveling the Synergistic Activity‐Stability Enhancement of a High‐Entropy Perovskite Air Electrode for Dual Ceramic Electrochemical Cells

Advanced Science, EarlyView.
A high‐entropy air electrode material, Gd0.2Pr0.2Ba0.2Sr0.2Ca0.2FeO3−δ (GPBSCF), is developed for both solid oxide fuel cells and reversible protonic ceramic cells. Its enhanced activity stems from increased oxygen vacancies/holes. The stability improvement is attributed to lattice distortion, while thermal expansion reduction is synergistically due to
Ying Zhang, Yibei Wang, Zhilin Liu, Kuo Hu, Yaowen Wang, Zhen Wang, Xiyang Wang, Bingbing Niu, Wenquan Wang, Tianmin He   +9 more
wiley   +1 more source

Studies on Surface and Interface with X-ray Absorption Fine Structure (XAFS). Microspectroscopy of Semiconductor Surfaces by SCM-XAFS Method.

Hyomen Kagaku, 2002
For a site-selective analysis of trap centers on semiconductor surfaces, a new X-ray absorption spectroscopy using scanning probe detection of capacitance (Scanning capacitance microscope - X-ray absorption fine structure; SCM-XAFS method) is proposed.
openaire   +2 more sources

Nanocurvature‐Activated Dipolar Polarization in M–N4 Single‐Atom Sites for High‐Performance Electromagnetic Wave Absorption

Advanced Science, EarlyView.
Increasing nanocurvature effectively enriches the local electron density of the M–N4 motif, which facilitates electron transfer from the metal center to nitrogen atoms. This electronic behavior intensifies the localization and asymmetric distribution of charge, thereby significantly amplifying the dipole moment and polarizability.
Daohu Sheng, Siyao Cheng, Mengmeng Zhang, Jinglei Zhang, Xufei Zhu, Weijin Li, Bo Zhang, Aming Xie   +7 more
wiley   +1 more source

Debye-Waller factor of Pt in X-ray absorption fine structure analyzed using classical anharmonic correlated Einstein model

Communications in Physics
An analysis of the Debye-Waller (DW) factor in the anharmonic X-ray absorption fine structure (XAFS) of crystalline platinum (Pt) has been conducted under the influence of thermal disorder.
Nguyen Huy Thao, Thuy Nguyen Thi Minh, Le Viet Hoang, Tong Sy Tien   +3 more
doaj   +1 more source

Efficient Electrocatalytic Conversion of CO2 to Pure Formic Acid Solutions via Strain‐Engineered Bismuth Nanosheets

Advanced Science, EarlyView.
Tensile‐strained bismuth nanosheets (TS‐BiNs) achieve a formate Faradaic efficiency of 92% at −1000 mA cm−2 and enable stable production of pure formic acid (HCOOH) in a solid‐state electrolyte reactor. Theoretical calculations reveal that the introduced strain lowers the energy barrier for *OCHO intermediate formation, fundamentally enhancing the ...
Shiqi Li, Yuefeng Zhang, Panzhe Qiao, Cuo Wu, Xinya Tian, Yufeng Xu, Yun Zhang, Peng Wang, Tingting Li, Muhammad Afaq, Xinlin Luo, Tang Wang, Chunxiao Liu, Zi‐You Yu, Chuan Xia, Min‐Rui Gao, Zhen‐Yu Wu   +16 more
wiley   +1 more source

Reinforcing Oxygen Activation of Spinel Oxide via Mn─O Covalency Engineering for VOCs Oxidation

Advanced Science, EarlyView.
A MnCo spinel catalyst with weakened Mn─O covalency was synthesized via a hard‐template method. The reduced Mn─O covalency facilitates localized electron redistribution, promoting the activation of both molecular oxygen and lattice oxygen, and thereby enabling the efficient and complete oxidation of VOCs (ethyl acetate, toluene, and propane).
Gan Li, Ruochen Zhou, Qianqian Chen, Guobo Li, Xiang Tu, Fengbo Yu, Wenming Liu, Jian Ji, Honggen Peng   +8 more
wiley   +1 more source

The Third‐Generation Magnetic Super‐Stable Mineralizer: Complete Removal and Separation of Multiple Heavy Metal Pollutants

Advanced Science, EarlyView.
The 3rd‐generation magnetic super‐stable mineralizer M‐MgAl‐700 features a core‐shell structure, strong superparamagnetism, large surface area, and abundant oxygen defects. It achieves exceptional Cd(II) and As(V) mineralization capacities, reducing both pollutants in co‐contaminated water and soil to meet national standards.
Haoran Wang, Menghan Huang, Ruihua Mao, Xiaohan Zhang, Zhaohui Wu, Xiaofeng Pang, Tong Lin, Dongyuan Cui, Sai An, Yu‐Fei Song   +9 more
wiley   +1 more source

One‐Dimensional RuIrTe Nanotubes with Amorphous Surface as a Highly Active and Stable Electrocatalyst Toward Oxygen Evolution Reaction in Acidic Media

Advanced Science, EarlyView.
A rational etching‐induced reconstruction strategy is demonstrated to fabricate one‐dimensional RuIrTe ternary nanotubes with a unique amorphous‐crystalline heterostructure. This hierarchical architecture synergistically optimizes mass transport and electronic configurations, delivering record‐breaking performance in proton exchange membrane water ...
Zhi Liang Zhao, Zhe Zhang, Shaoxuan Yang, Jie Zhang, Qi Wang   +4 more
wiley   +1 more source

Effects of Cs/Sr intercalation on the structure and electrical conductivity of weathered biotite [PDF]

AIP Advances
Weathered biotite (WB) is a layered clay mineral composed of Si, Al, Fe, and Mg. After molten-salt treatment at temperatures above 700 °C, WB exhibits thermoelectric properties, making it a low-cost and thermally robust candidate for sustainable high ...
Kosetsu Hayakawa, Masakazu Muraguchi, Yumeno Masebo, Yohichiro Kojima, Masato Oda, Rina Yabuta, Hiroyuki Ishii, Mitsunori Honda   +7 more
doaj   +1 more source