Results 81 to 90 of about 3,491 (200)

Accelerating Materials Discovery: A Review of Machine Learning in X‐Ray Absorption Spectroscopy

Advanced Intelligent Systems, EarlyView.
This review systematically details how machine learning transforms X‐ray absorption spectroscopy (XAS) analysis. It covers advanced deep learning architectures for structure‐spectra mapping and inverse tasks, while discussing key challenges like the simulation‐to‐reality gap.
Melaku Lake Tegegne, Haodong Yao, Liyuan Wu, Yihe Pang, Fazhi Qi, Lina Zhao   +5 more
wiley   +1 more source

Role of Graphene Oxide in the Nucleation and Growth of Gold Nanoparticles Revealed by Operando Time‐Resolved Studies

Angewandte Chemie, EarlyView.
Graphene oxide accelerates AuCl4− reduction under irradiation and directs edge‐selective nucleation and quasi‐one‐dimensional organization of gold nanoparticles at oxygen‐rich boundaries. Operando SAXS and UV–vis spectroscopy, supported by pulse radiolysis and DFT, reveal how progressive conversion of GO to rGO removes interfacial constraints, shifting
Liran Hu, Carine Clavaguéra, Zhenpeng Cui, Zhiwen Jiang, Thomas Bizien, Filippo Ferdeghini, Nguyen‐Thi Van‐Oanh, Michel Goldmann, François Muller, Samy Remita   +9 more
wiley   +2 more sources

Epitaxial Oxide Interfaces Create Poison‐Resistant CuO Sites for Environmental Catalysis

Angewandte Chemie, EarlyView.
An epitaxially stabilized CuO overlayer on Ti1−xInxO2 creates electron‐poor, high‐symmetry Cu–O sites that activate interfacial lattice‐oxygen redox. This interface promotes NOx reduction through an Eley–Rideal pathway, diverts sulfate formation, and sustains CH3SH deep oxidation via a Mars–van Krevelen cycle, offering a route to poison‐resistant ...
Lupeng Han, Yanqing Li, Yongjie Shen, Huijun Yu, Evangelina Pensa, Xuehui Yang, Yanqi Chen, Xiaonan Hu, Xiyang Wang, Song Li, Gaowu Qin, Wenqiang Qu, Ming Xie, Emiliano Cortés, Dengsong Zhang   +14 more
wiley   +2 more sources

Decouple H2O2 Electrosynthesis From Microenvironmental Decomposition via Atomic Site Density Engineering

Angewandte Chemie, EarlyView.
Using defect‐rich Co‐N2O2 single‐atom catalysts as a model system, this work reveals that atomic site density governs the competition between H2O2 electrosynthesis and microenvironmental decomposition during 2e−‐ORR. Optimised site isolation suppresses HPRR and HDR, thereby establishing a site‐density principle to balance H2O2 formation and ...
Junwen Chen, Hongyu Zhou, Qiming Zhang, Shuang Zhong, Wei Ren, Lei Shi, Li Gao, Shaobin Wang, Xiaoguang Duan   +8 more
wiley   +2 more sources

Rerouting Oxygen Evolution Through Interfacial Carbonate Chemistry in Near‐Neutral Seawater Electrolysis

Angewandte Chemie, EarlyView.
Carbonate species play a previously overlooked role in near‐neutral seawater electrocatalysis. By coupling electrochemical hydrodynamics with mesoscopic simulations, we reveal a plausible carbonate‐mediated route in which carbonate functions as an interfacial proton acceptor and water as the oxygen donor, showing a possible mechanistic picture of ...
Miao Wang, Masaki Takeguchi, Ken Sakaushi   +2 more
wiley   +2 more sources

In situ photothermal catalytic cell for X-ray absorption fine structure spectroscopy measurement

Materials Today Catalysis
The burgeoning field of photothermal catalysis has garnered increasing interest due to the synergistic effects of light and thermal activation. Understanding the intrinsic reaction dynamics and structural evolution during the photothermal catalytic ...
Bingbao Mei, Di Shen, Yao Wei, Jingyuan Ma, Fanfei Sun   +4 more
doaj   +1 more source

Recent advances in battery characterization using in situ XAFS, SAXS, XRD, and their combining techniques: From single scale to multiscale structure detection

Exploration
Revealing and clarifying the chemical reaction processes and mechanisms inside the batteries will bring a great help to the controllable preparation and performance modulation of batteries.
Weidong Cheng, Mengyuan Zhao, Yuecheng Lai, Xin Wang, Huanyan Liu, Peng Xiao, Guang Mo, Bin Liu, Yunpeng Liu   +8 more
doaj   +1 more source

Uranium Mineral Transport in the Peña Blanca Desert: Dissolution or Fragmentation? Simulation in Sediment Column Systems

Applied Sciences
The Sierra Peña Blanca (SPB) region in Chihuahua, Mexico contains a significant uranium deposit representing about 40% of the country’s reserves. Common uranium minerals in this area include uranophane, schoepite, and weeksite/boltwoodite, with several ...
Victoria Pérez-Reyes, Rocio M. Cabral-Lares, Jesús G. Canche-Tello, Marusia Rentería-Villalobos, Guillermo González-Sánchez, Blanca P. Carmona-Lara, Cristina Hernández-Herrera, Fabián Faudoa-Gómez, Yair Rodríguez-Guerra, Gregorio Vázquez-Olvera, Jorge Carrillo-Flores, Ignacio A. Reyes-Cortés, Daniel Hernández-Cruz, René Loredo-Portales, María E. Montero-Cabrera   +14 more
doaj   +1 more source

Effect of Cu incorporation in silicate and modified borate bioglass materials for health applications: insights from synchrotron-based x-ray absorption spectroscopy

Discover Materials
This contribution investigates the effect of variable copper incorporation (x = 0.2, 1.0, 2.0, and 4.0) in silicate (45 SiO2, 24.5 CaO, 24.5 Na2O, 6P2O5 wt%) and modified borate (45 B2O3, 24.5 CaO, 24.5 Na2O, 6P2O5 wt%) bioglass materials to be used for ...
N. G. Imam, Messaoud Harfouche, A. M. Abdelghany, Jan Ingo Flege   +3 more
doaj   +1 more source

Design and development of fluorescence gas detector for X-ray absorption fine structure

He jishu
BackgroundThe gas ionization chamber is a kind of intensity monitoring detector widely used in Synchrotron Radiation Facility. Lytle detector is often used to measure the fluorescence signal from the element of interest in the fluorescent mode XAFS (X ...
CHEN Yu, WANG Jiandong, PU Shijie, GAO Qian, GAN Tao, HUANG Yuying, ZHANG Shuo, LI Jiong   +7 more
doaj   +1 more source