Results 181 to 190 of about 40,331 (294)

Disorder‐Driven Fast Na+ Transport: From Crystalline to Amorphous Networks in the Mixed‐Anion NaTaOxCl6−2x Oxychlorides

Advanced Energy Materials, EarlyView.
Oxygen substitution in NaTaOxCl6‐2x drives structural evolution from isolated [TaCl6]– octahedra, through oxygen‐bridged [Ta2OCl10]2– dimers, toward extended trans‐[TaO2Cl4]3– chain‐like arrangements. At intermediate compositions, zero‐dimensional corner‐sharing motifs are proposed to create a flexible, disordered framework that peaks ionic ...
Justin Leifeld, Abigail C. Parsons, Alexandra Morscher, Xabier Martinez de Irujo‐Labalde, Marvin A. Kraft, Oskar G. Soulas, Bibek Samanta, Wiebke Zielasko, Neelam Yadav, Kyra Strotmann, Niina Jalarvo, Bruno V. M. Rodrigues, Adam Slabon, Philipp Adelhelm, Michael Ryan Hansen, David O. Scanlon, Wolfgang G. Zeier, Alexander G. Squires   +17 more
wiley   +1 more source

Band Gap Tuneability in Antiperovskite‐Based Nitrides AE3PnN and Imides AE5Pn2(NH)2 (AE = Ca, Sr; Pn = As, Sb, Bi)

Angewandte Chemie, EarlyView.
A series of imide‐based defect antiperovskites AE5Pn2(NH)2 (AE = Ca, Sr; Pn = As, Sb, Bi) has been synthesized using the ammonothermal method. DFT calculations and spectroscopy revealed direct band gaps suitable for photovoltaic absorber materials. The discovered compounds can further be used as precursors for the synthesis of AE3PnN antiperovskites as
Thanh G. Chau, Florian Wolf, Dan Han, Saloni, Teak D. Boyko, Stefan S. Rudel, Thomas Bein, Hubert Ebert, Alexander Moewes, Wolfgang Schnick   +9 more
wiley   +2 more sources

Ultra‐Low‐Strain Calcium and Magnesium Ion Storage Enabled by Tunnel‐Structured MoO3 Positive Electrode

Advanced Energy Materials, EarlyView.
A hexagonal tunnel‐structured MoO3 is nanoparticulated via hydrothermal synthesis followed by ball‐milling. As a positive electrode in Ca and Mg batteries, it delivers superior capacity and structural reversibility, enabling divalent cation intercalation with minimal lattice distortion and no phase transitions.
Reona Iimura, M. D. Hashan C. Peiris, Takashi Yabu, Toshihiko Mandai, Ruijie Zhu, Akira Nasu, Saneyuki Ohno, Masaki Matsui, Itaru Honma, Manuel Smeu, Hiroaki Kobayashi   +10 more
wiley   +1 more source

Selective Hydrogenation of Formamide to Methanol Over Supported Platinum Catalysts

Angewandte Chemie, EarlyView.
Amine–CO2 adducts can be hydrogenated to formamides and subsequently to methanol under mild conditions (<150°C), establishing an integrated CO2 capture‐and‐conversion route in a heterogeneous system that directly links amine sorbent cycling with methanol synthesis.
Xuetao Qin, XinXin Tian, Shou Qiu, Han Yan, Haijun Jiao, Henrik Junge, Matthias Beller   +6 more
wiley   +2 more sources

Strain‐Directed Ru Redistribution to Form RuO2/Pt Mosaic Heterointerfaces for Acid‐Stable Water Oxidation

Advanced Energy Materials, EarlyView.
Strain‐driven Ru inward migration creates confined RuO2/Pt mosaic heterointerfaces within a PtNi multiframe. These interfaces enable redox‐asymmetric Pt–Ru coupling that stabilizes Ru4+, suppresses lattice oxygen participation, and promotes highly durable acidic oxygen evolution.
Yeji Park, Doyeop Kim, Jungho Kim, Ho Yeon Jang, Minseon Cha, Subeen Lee, Tae Kyung Lee, Taekyung Kim, Hionsuck Baik, Jinwon Choi, Taehyun Kwon, Seoin Back, Sung Jong Yoo, Kwangyeol Lee   +13 more
wiley   +1 more source

Structure and Spectroscopic Characterisation of Phenanthroline‐Based Iodobismuthate(III) Complexes Utilised for Raw Acoustic Signal Classification

Advanced Intelligent Discovery, EarlyView.
Memristors based on trimethylsulfonium (phenanthroline)tetraiodobismuthate have been utilised as a nonlinear node in a delayed feedback reservoir. This system allowed an efficient classification of acoustic signals, namely differentiation of vocalisation of the brushtail possum (Trichosurus vulpecula).
Ewelina Cechosz, Gisya Abdi, Andrzej Sławek, Marlena Gryl, Konrad Szaciłowski   +4 more
wiley   +1 more source

Catalysis AI Agent Guides Discovering the Universal Design Principle of Cu‐Based Single‐Atom Alloy Catalysts for CO2 Electroreduction

Angewandte Chemie, EarlyView.
Artificial intelligence (AI) enables the systematic analysis and comparative evaluation of experimental and theoretical data, optimizes the catalytic reaction research workflow, and accelerates the discovery of high‐performance electrocatalysts. ABSTRACT Copper (Cu)‐based single‐atom alloys (SAAs) represent a promising strategy for optimizing the ...
Xuning Wang, Zhong Li, Di Zhang, Hao Li, Haoxiang Xu, Daojian Cheng   +5 more
wiley   +2 more sources

X-ray absorption spectroscopy of scandium oxide polymorphs. [PDF]

RSC Adv
Duarte-Ruiz D, Saßnick HD, Ferreira De Araujo FM, Gentzmann M, Huthwelker T, Cocchi C.   +5 more
europepmc   +1 more source

Monitoring Redox Pathways and Performance Limitations in Lithium‐Sulfur Batteries Using In Situ 7/6Li and 33S NMR Spectroscopies

Angewandte Chemie, EarlyView.
Lithium‐sulfur (Li‐S) batteries contain various NMR‐active nuclear isotopes, including 7Li, 6Li and 33S, which are sensitive to the different chemical reactions that occur during battery cycling. Herein, we use a combination of lithium and sulfur operando NMR spectroscopy to provide new insights at the molecular level, fundamental understanding being ...
Jana B. Fritzke, Sunita Dey, Christopher A. O’ Keefe, Jeongjae Lee, Kazuhiro Kamiguchi, Daisuke Mori, Yuri Nakayama, Clare P. Grey   +7 more
wiley   +2 more sources

Single-Determinant Ground State in Ce⁴⁺ Imidophosphorane Complexes. [PDF]

Inorg Chem
Tateyama H, Liao C, Wilkinson GR, Ramanathan A, Amidani L, Bazarkina E, Ressnik F, Engle KS, Bacsa J, Sokaras D, Kvashnina KO, Li X, La Pierre HS.   +12 more
europepmc   +1 more source