Results 191 to 200 of about 40,331 (294)

Spin‐State Modulation of Atomic Iron Sites Enables Efficient CO2 Electroreduction in Acid Medium

open access: yesAngewandte Chemie, EarlyView.
An axial oxygen ligand was added to shift the spin state of the single‐atom Fe site from low to medium spin. This change reduces the interfacial interaction with H3O+ and decreases the *CO desorption energy, thus enhancing CO2RR in acidic media.
Shanhe Gong   +13 more
wiley   +2 more sources

In Situ X-ray Absorption Fine Structure Spectroscopy Measurement of Suspended Cobalt Oxide Nanoparticle Water Oxidation Catalyst. [PDF]

open access: yesJ Phys Chem Lett
Okazaki M   +11 more
europepmc   +1 more source

Riesige Magnetostriktion im Ferrimagnet SmFe5As3

open access: yesAngewandte Chemie, EarlyView.
SmFe5As3 ist ein neu entdecktes ferrimagnetisches Material, das ungewöhnliche volumetrische Effekte in Abhängigkeit von der Temperatur zeigt. Aufgrund zweier magnetischer Teilstrukturen – eines mit d$d$‐Elektronen des Fe und eines mit f$f$‐Elektronen des Sm – zeigen SmFe5As3‐Einkristalle negative (blau), positive (rosa) sowie konstante (beige ...
Oksana Karychort   +21 more
wiley   +1 more source

Solar‐Driven Ammonia Synthesis From Nitrate Reduction Paired With CO2 Capture for Sustainable Agriculture via a Robust CuPd Heterojunction

open access: yesAngewandte Chemie, EarlyView.
Laser‐assisted synthesis of CuPd amorphous/crystalline heterojunction demonstrates >80% Faradaic efficiency for nitrate‐to‐ammonia electroreduction across wide potential windows. The integrated solar‐powered electrolyzer achieves 6% solar‐to‐ammonia energy efficiency at 0.4 sun, 6–20 mg h−1 CO2 capture rate, and stability exceeding 100 h.
Weihua Guo   +18 more
wiley   +2 more sources

Circularly Polarized Luminescent and Melt‐Processable Copper(I)‐Organic Glasses Based on 2,2′‐Bis(diphenylphosphino)‐1,1′‐binaphthyl

open access: yesAngewandte Chemie, EarlyView.
Homochiral Cu(I) cyanide complexes based on 2,2’‐bis(diphenylphosphino)‐1,1’‐binaphthyl (BINAP) form melt‐quenched and desolvation‐derived metal–organic glasses that exhibit circularly polarized thermally activated delayed fluorescence (TADF) at room temperature, enabling processable chiroptical materials.
Zeyu Fan   +5 more
wiley   +2 more sources

Quantifying Trace Metals in Gunflint Microfossils by 3D Correlative X-ray Nanoimaging. [PDF]

open access: yesAnal Chem
Lemelle L   +15 more
europepmc   +1 more source

Convergent Valorization via Scalable C═N Bond Electrosynthesis Through Metal‐Dopant Interfacial Engineering in a Flow Electrolyzer

open access: yesAngewandte Chemie, EarlyView.
This study establishes an innovative approach to synthesize organonitrogens featuring C═N bonds efficiently using non‐precious metal‐doped MoS2 in a flow electrolyzer. Fe dopant significantly enhances Faradaic efficiency and yield rate, achieving over 81% and 2630 mmol h−1 g−1 for formaldoxime production. This platform upcycles pollutants into valuable
Ruijie Yi   +9 more
wiley   +2 more sources

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