Results 191 to 200 of about 25,590 (253)

Decoupling Chemical and Mechanical Contributions to Capacity Fading in Ni‐Rich Cathodes for Sulfide‐Based All‐Solid‐State Batteries

Advanced Energy Materials, EarlyView.
Ni‐rich cathodes in sulfide‐based ASSBs undergo intertwined (electro)chemical and mechanical degradation. Here, a new diagnostic framework is presented to decouple each contribution by partitioning capacity fading into charge and discharge fading.
Jangwhan Seok, Chanyou Chung, Hyunbeom Lee, Subin Ahn, Seongeun Lee, Sangbin Park, Sunhyun Hwang, Jaeyoung Kim, Jeonghyun Seo, Sungwoo Noh, Juyeong Seong, Sangheon Lee, Won‐Sub Yoon   +12 more
wiley   +1 more source

Universal Oxychlorination Strategy in Halide Solid Electrolytes for All‐Solid‐State Batteries

Advanced Energy Materials, EarlyView.
A WO2Cl2‐driven oxychlorination strategy enables bulk oxygen incorporation into close‐packed LixMCl6 (M = Zr, Y, Er, In) halide lattices. Oxygen is selectively anchored by W6+ as lattice‐integrated [WO2Cl4]2− units, regulating the anionic framework, diversifying Li coordination, and weakening Li–Cl interactions.
Jae‐Seung Kim, Heeju Park, Hae‐Yong Kim, Eunryeol Lee, Heewon Kim, Soeul Lee, Jinyeong Choe, Jiwon Seo, Hyeon‐Jong Lee, Hojoon Kim, Jemin Yeon, Yoon Seok Jung, Kyung‐Wan Nam, Dong‐Hwa Seo   +13 more
wiley   +1 more source

Synchrotron cryo-soft X-ray microscopy reveals bacterial interactions with nanostructured calcium phosphate substrates. [PDF]

Nat Commun
Iglesias-Fernandez M, Pérez-Berná AJ, Pereiro E, Ginebra MP, Espanol M.   +4 more
europepmc   +1 more source

Oxygen‐Driven Structural Reorganization by Trace Water Enabling Fast Li‐Ion Transport in a Pliable Solid Electrolyte

Advanced Energy Materials, EarlyView.
Trace water is acting as a constructive mediator in 2LiCl–GaF3, markedly increasing ionic conductivity while reorganizing local coordination. Hydration creates localized Li+ solvation environments and partially dissociates ion pairs, enhancing Li‐ion mobility.
Youngkyung Kim, Jae‐Seung Kim, Kwang Ho Shin, Jingyu Choi, Beom Jin Park, Jinyeong Choe, Jiwon Seo, Chanhyun Park, Jeongjae Lee, Dong‐Hwa Seo, Sung‐Kyun Jung   +10 more
wiley   +1 more source

One-dimensional anionic radical chains based on M₂P₂ rings (M = Ti, Zr, Hf). [PDF]

Chem Sci
Sun X, Yadav R, Hinz A, Göttlicher J, Vitova T, Dinauer S, Scheer M, Roesky PW.   +7 more
europepmc   +1 more source

Degradation Pathways of Silicon‐Based Anodes in Lithium‐Ion Batteries

Advanced Energy Materials, EarlyView.
Silicon‐based anodes undergo degradation through five primary pathways: (1) mechanical and structural deterioration of the active material, (2) loss of electrode integrity and electrical contact, (3) mechanical instability of the solid electrolyte interphase (SEI), characterized by repetitive fracture and deformation, (4) chemical instability of the ...
Yoon Jeong Choi, Ji‐Youn Bae, Ga‐On Park, Seung‐Ho Yu   +3 more
wiley   +1 more source

XAFS measurement system using undulator synchronized on-the-fly monochromator scan at SPring-8 BL36XU. [PDF]

J Synchrotron Radiat
Ishiguro N, Uruga T, Kaneko T, Tanaka T, Joti Y, Motomura K, Yamazaki H, Senba Y, Ohashi H, Yabashi M, Takahashi Y.   +10 more
europepmc   +1 more source

Investigation of Moisture‐Induced Degradation Mechanisms and a Reviving Strategy for Sulfide‐Based Solid Electrolytes in All‐Solid‐State Composite Cathode

Advanced Energy Materials, EarlyView.
Moisture exposure induces the formation of reductive solid phases on argyrodite Li6PS5Cl, which destabilize Ni‐rich cathodes by extracting lattice oxygen and inducing surface reconstruction. A brief oxygen‐assisted annealing treatment quenches these reductive phases, restores interfacial stability, and enables effective regeneration and reuse of ...
Yujeong Hwang, Hwiho Kim, Sungjae Seo, Mingyuan Ge, Yongjun Jang, Jongwoo Lim   +5 more
wiley   +1 more source

Pressure-Induced Stabilization of Terbium(IV) in CsTb(CrO₄)₂ Characterized by X-ray Absorption Spectroscopy. [PDF]

J Am Chem Soc
Hines TW, Amidani L, Beck NB, Mendoza KN, Sahle C, Sperling JM, Vasala S, Kvashnina KO, Albrecht TE.   +8 more
europepmc   +1 more source

Deciphering Intricacies in Directional CO2 Conversion From Electrolysis to CO2 Batteries

Advanced Energy Materials, EarlyView.
This review will delve into the inherent connections and distinctions of CO2‐directed conversion in ECO2RR and CO2 batteries, in terms of product types, catalyst selection, catalytic mechanisms, and electrochemical performances, while proposing a benchmarking framework for the evaluation of CO2 batteries and innovative CO2 battery configurations for ...
Changfan Xu, Huaping Zhao, Lizhuang Chen, Weidong Shi, Guosheng Shao, Yong Lei   +5 more
wiley   +1 more source