Results 191 to 200 of about 10,638 (258)

Tailoring High‐Valent Iron‐Oxo Species Redox via Extended π‐Fe3d–O2p Orbital Overlapping Toward Chemical‐Efficient Water Purification

Angewandte Chemie, EarlyView.
We address the long‐standing challenge of reactivity–selectivity trade‐off by precisely tuning the redox properties of Fe(IV), rather than simply accelerating its formation, to enable chemically efficient and low‐emission water treatment. ABSTRACT High‐valent iron oxo species (Fe(IV)) are attractive for wastewater treatment because of their high ...
Hongyu Zhou, Junwen Chen, Jiuyi Wang, Xinhao Wang, Qiming Zhang, Shiying Ren, Xuning Li, Li Gao, Shaobin Wang, Xiaoguang Duan   +9 more
wiley   +1 more source

Hierarchical Environmental Exposure Transforms Zeolitic Imidazolate Framework-8 and Increases Toxicity in <i>Daphnia magna</i>. [PDF]

ACS Nano
Chakraborty S, Mikulska I, Boseley R, Pham S, Bhadane P, Dhumal P, Majumder S, Mandal J, Geraki T, Misra SK, Pfrang C, Lynch I.   +11 more
europepmc   +1 more source

Step‐Associated Cu‐Ceria Interfaces Enhance Catalytic Activity and Selectivity

Angewandte Chemie, EarlyView.
The catalytic activity and selectivity of supported Cu nanoparticles depends on their interfacial environments, with Cu nanoparticles at step‐associated environments converting CO2 to methanol much faster than those on terrace facets, indicating that step sites create more active metal–oxide interfaces.
Shuxuan Feng, Shan Jiang, Chengyu Song, Chaochao Dun, Yang Deng, Hao Xu, Zihao Zhang, Xiong He, Temitayo Ojuetimi Ikuerowo, Mark R. Hoffmann, Jeffrey T. Miller, Yong Wang, Weixin Huang   +12 more
wiley   +1 more source

Correction. [PDF]

Redox Rep
europepmc   +1 more source

Operando Investigation of Mechanochemically Synthesized Ni-Based Metal-Organic Frameworks for Electrocatalytic Alcohol Oxidation. [PDF]

ChemSusChem
Roy A, Vaneberck X, Rodriguez CG, Butyrin S, Al-Sabbagh D, Das C, Meyer K, Feldmann I, Radnik J, Guilherme Buzanich A, Emmerling F, Bhattacharya B.   +11 more
europepmc   +1 more source

Epitaxial Oxide Interfaces Create Poison‐Resistant CuO Sites for Environmental Catalysis

Angewandte Chemie, EarlyView.
An epitaxially stabilized CuO overlayer on Ti1−xInxO2 creates electron‐poor, high‐symmetry Cu–O sites that activate interfacial lattice‐oxygen redox. This interface promotes NOx reduction through an Eley–Rideal pathway, diverts sulfate formation, and sustains CH3SH deep oxidation via a Mars–van Krevelen cycle, offering a route to poison‐resistant ...
Lupeng Han, Yanqing Li, Yongjie Shen, Huijun Yu, Evangelina Pensa, Xuehui Yang, Yanqi Chen, Xiaonan Hu, Xiyang Wang, Song Li, Gaowu Qin, Wenqiang Qu, Ming Xie, Emiliano Cortés, Dengsong Zhang   +14 more
wiley   +1 more source

XFM and HERFD-XAS studies of selenium in tissues and whole blood from mice supplemented with potentially therapeutic selenocompounds. [PDF]

Redox Rep
Baker AT, Ortiz-Cerda T, Xie K, Hunter J, Dragutinovic I, Morris JC, Vogt LI, George GN, Sokaras D, Howard DL, Witting PK, Harris HH.   +11 more
europepmc   +1 more source

Unlocking Zn‐Ion Diffusion in Disordered Rocksalt Cathodes for Nonaqueous Zn‐Ion Batteries

Angewandte Chemie, EarlyView.
Developing viable cathode materials for multivalent battery chemistries is challenging due to the intrinsic sluggish diffusion kinetics. A disordered rocksalt oxide host was found to “lock” the cycling of zinc ions from nonaqueous electrolyte. We unlock zinc ion diffusion in the disordered rocksalt by introduction of a percolating vacancy network ...
Zixuan Li, Rui Qi, Yee Chit Wong, Longlong Wang, Jun Chen, Yi Yuan, Reinhard J. Maurer, Robert A. House, Nicholas D. M. Hine, Peter G. Bruce, Alex W. Robertson   +10 more
wiley   +1 more source

Strategies for Tuning the Electrical Properties of La₂NiTiO₆ Perovskite Derivatives and Their Evaluation as Potential Air Electrodes in Reversible Solid Oxide Cells. [PDF]

Energy Fuels
Natoli A, Azcondo MT, Pérez-Flores JC, Muñóz-Noval A, García-Alvarado F, Amador U.   +5 more
europepmc   +1 more source

Spectroscopic Fingerprinting of Coordination-driven Spin States in Metal-organic Architectures. [PDF]

Chemistry
Grisan Qiu YY, Carlotto S, Mearini S, Baranowski D, Cojocariu I, Jugovac M, Zamborlini G, Gargiani P, Valvidares M, Feyer V, Schneider CM.   +10 more
europepmc   +1 more source