Selective Hydrogenation of Formamide to Methanol Over Supported Platinum Catalysts
Amine–CO2 adducts can be hydrogenated to formamides and subsequently to methanol under mild conditions (<150°C), establishing an integrated CO2 capture‐and‐conversion route in a heterogeneous system that directly links amine sorbent cycling with methanol synthesis.
Xuetao Qin +6 more
wiley +2 more sources
Optical Properties of ZnP2 Nanoparticles in Zeolite [PDF]
We report that for the first time the nanoparticles of II-V semiconductor (ZnP2) were prepared and studied. ZnP2 nanoparticles were prepared by incorporation into zeolite Na-X matrix. Absorption, diffuse reflection (DR) and photoluminescence (PL) spectra
Armelao +20 more
core +1 more source
Hierarchically Soft Porous MOF‐Polymer Monolith for Fast and Large‐Scale Moisture Buffering
A soft, hierarchical porous monolith that combines metal–organic frameworks (MOFs) with a thermoresponsive polymer matrix enables rapid, large‐scale moisture buffering. The synergistic interface facilitates high‐capacity water capture and low‐energy release for sustainable indoor dehumidification.
Guangxin Ma +9 more
wiley +1 more source
Preparation and wastewater treatment performance of zeolite-modified ecological concrete
This study developed a zeolite-modified ecological concrete and investigated the effects of zeolite content and particle size on its physical and mechanical properties, as well as its degradation performance.
Liu Zhiwu +4 more
doaj +1 more source
Zeolites have been hydrothermally synthesized using alumina and silica based deposits (kaolin, bauxite, silica and feldspar) sampled from three regions in Ghana and the chemical compositions of the zeolites varied by batch formulations.
Emmanuel Nyankson +6 more
doaj +1 more source
Radiation‐Resistant Kr‐Selective MOF With Record Kr/Xe Selectivity at Elevated Pressure
ABSTRACT The separation of Kr/Xe from spent nuclear fuel off‐gas is critical, yet most current adsorbents exhibit Xe‐Kr co‐adsorption under elevated pressures, posing challenges for industrial pressure swing adsorption processes. Herein, we present and evaluate a metal‐organic framework, CALF‐20M‐w, engineered for molecular sieving separation of Kr/Xe ...
Qihang Tian +6 more
wiley +1 more source
Consequences of Medium‐Pore Zeolite Constraints for Alkene Cracking—The Case of n‐Pentene
Alkene cracking in medium‐pore zeolites is governed by a balance of enthalpic and entropic effects. Intrinsic barriers are quantified and shown to be lower than for alkanes due to stabilization of carbenium‐ion‐like transition states. Confinement and extra‐framework aluminum modulate reactivity by tuning transition‐state energetics, providing a ...
Ruixue Zhao +4 more
wiley +2 more sources
Autogenous shrinkage of zeolite cement pastes with low water-binder ratio [PDF]
Self-desiccation is one common phenomenon of high-performance cementitious materials characterized by low water to cementitious material ratio (w/c).
De Schutter, Geert +3 more
core +1 more source
Efficient approach for the computational study of alcohol and nitrile adsorption in H-ZSM-5 [PDF]
Since many industrially important processes start with the adsorption of guest molecules inside the pores of an acidic zeolite catalyst, a proper estimate of the adsorption enthalpy is of paramount importance.
Hemelsoet, Karen +4 more
core +2 more sources
Autonomous and Continuous Atmospheric Water Harvesting Using Modified Wood
A rigid, hydroxyl‐rich wood skeleton with graded channels is used as a multifunctional host to co‐incorporate a PNipam/PAA network and LiCl, creating a high‐performance sorbent for atmospheric water harvesting. The composite achieves rapid sorption, efficient low‐temperature desorption, and stable cycling, enabling a solar‐powered device with a high ...
Shiheng He +7 more
wiley +1 more source

