Results 81 to 90 of about 162,188 (303)

Selective Hydrogenation of Formamide to Methanol Over Supported Platinum Catalysts

open access: yesAngewandte Chemie, EarlyView.
Amine–CO2 adducts can be hydrogenated to formamides and subsequently to methanol under mild conditions (<150°C), establishing an integrated CO2 capture‐and‐conversion route in a heterogeneous system that directly links amine sorbent cycling with methanol synthesis.
Xuetao Qin   +6 more
wiley   +2 more sources

Optical Properties of ZnP2 Nanoparticles in Zeolite [PDF]

open access: yes, 2004
We report that for the first time the nanoparticles of II-V semiconductor (ZnP2) were prepared and studied. ZnP2 nanoparticles were prepared by incorporation into zeolite Na-X matrix. Absorption, diffuse reflection (DR) and photoluminescence (PL) spectra
Armelao   +20 more
core   +1 more source

Hierarchically Soft Porous MOF‐Polymer Monolith for Fast and Large‐Scale Moisture Buffering

open access: yesAdvanced Science, EarlyView.
A soft, hierarchical porous monolith that combines metal–organic frameworks (MOFs) with a thermoresponsive polymer matrix enables rapid, large‐scale moisture buffering. The synergistic interface facilitates high‐capacity water capture and low‐energy release for sustainable indoor dehumidification.
Guangxin Ma   +9 more
wiley   +1 more source

Preparation and wastewater treatment performance of zeolite-modified ecological concrete

open access: yesOpen Chemistry
This study developed a zeolite-modified ecological concrete and investigated the effects of zeolite content and particle size on its physical and mechanical properties, as well as its degradation performance.
Liu Zhiwu   +4 more
doaj   +1 more source

Synthesis and characterisation of zeolite-A and Zn-exchanged zeolite-A based on natural aluminosilicates and their potential applications

open access: yesCogent Engineering, 2018
Zeolites have been hydrothermally synthesized using alumina and silica based deposits (kaolin, bauxite, silica and feldspar) sampled from three regions in Ghana and the chemical compositions of the zeolites varied by batch formulations.
Emmanuel Nyankson   +6 more
doaj   +1 more source

Radiation‐Resistant Kr‐Selective MOF With Record Kr/Xe Selectivity at Elevated Pressure

open access: yesAdvanced Science, EarlyView.
ABSTRACT The separation of Kr/Xe from spent nuclear fuel off‐gas is critical, yet most current adsorbents exhibit Xe‐Kr co‐adsorption under elevated pressures, posing challenges for industrial pressure swing adsorption processes. Herein, we present and evaluate a metal‐organic framework, CALF‐20M‐w, engineered for molecular sieving separation of Kr/Xe ...
Qihang Tian   +6 more
wiley   +1 more source

Consequences of Medium‐Pore Zeolite Constraints for Alkene Cracking—The Case of n‐Pentene

open access: yesAngewandte Chemie, EarlyView.
Alkene cracking in medium‐pore zeolites is governed by a balance of enthalpic and entropic effects. Intrinsic barriers are quantified and shown to be lower than for alkanes due to stabilization of carbenium‐ion‐like transition states. Confinement and extra‐framework aluminum modulate reactivity by tuning transition‐state energetics, providing a ...
Ruixue Zhao   +4 more
wiley   +2 more sources

Autogenous shrinkage of zeolite cement pastes with low water-binder ratio [PDF]

open access: yes, 2015
Self-desiccation is one common phenomenon of high-performance cementitious materials characterized by low water to cementitious material ratio (w/c).
De Schutter, Geert   +3 more
core   +1 more source

Efficient approach for the computational study of alcohol and nitrile adsorption in H-ZSM-5 [PDF]

open access: yes, 2012
Since many industrially important processes start with the adsorption of guest molecules inside the pores of an acidic zeolite catalyst, a proper estimate of the adsorption enthalpy is of paramount importance.
Hemelsoet, Karen   +4 more
core   +2 more sources

Autonomous and Continuous Atmospheric Water Harvesting Using Modified Wood

open access: yesAdvanced Science, EarlyView.
A rigid, hydroxyl‐rich wood skeleton with graded channels is used as a multifunctional host to co‐incorporate a PNipam/PAA network and LiCl, creating a high‐performance sorbent for atmospheric water harvesting. The composite achieves rapid sorption, efficient low‐temperature desorption, and stable cycling, enabling a solar‐powered device with a high ...
Shiheng He   +7 more
wiley   +1 more source

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