Results 41 to 50 of about 31,045 (265)

On the feasibility of N2 fixation via a single-site FeI/FeIV cycle: Spectroscopic studies of FeI(N2)FeI, FeIV=N, and related species [PDF]

, 2006
The electronic properties of an unusually redox-rich iron system, [PhBPR 3]FeNx (where [PhBPR 3] is [PhB(CH2PR2)3]−), are explored by Mössbauer, EPR, magnetization, and density-functional methods to gain a detailed picture regarding their oxidation ...
Barney, Barney, Betley, Betley, Betley, Brown, Brown, Brown, Burgess, C. C. Lu, Daida, Dance, Eady, Grapperhaus, Hinnemann, Howard, Huniar, Igarashi, J. C. Peters, Jenkins, K  stner, Lee, M. P. Hendrich, M. P. Mehn, M. T. Green, MacKay, Neese, R. K. Behan, Stoian, Stoian, T. A. Betley, Vrajmasu, W. Gunderson, Yandulov, Yandulov, Yandulov, Yang, Zhang   +37 more
core   +2 more sources

Synthesis of Zero Valent Iron Nanoparticles (nZVI) and its Efficiency in Arsenic Removal from Aqueous Solutions [PDF]

آب و فاضلاب, 2011
The aim of this study to synthesize nanoparticle zero valent iron and to determine its efficiency in arsenic removal from aqueous solutions. Nanoparticles were synthesized by reduction of ferric chloride using sodium borohydrid.
Ali Reza Rahmani, Hamid Reza Ghafari, Mohammad Taghi Samadi, Mansour Zarabi   +3 more
doaj  

Zero-Valent Metal Emulsion for Reductive Dehalogenation of DNAPLs [PDF]

, 2006
A zero-valent metal emulsion is used to dehalogenate solvents, such as pooled dense non-aqueous phase liquids (DNAPLs), including trichloroethylene (TCE).
Brooks, Kathleen, Clausen, Christian, Gelger, Cherie L., Quinn, Jacqueline, Reinhart, Debra R.   +4 more
core   +1 more source

Iron-Catalyzed, Highly Regioselective Synthesis of alpha-Aryl Carboxylic Acids from Styrene Derivatives and CO2 [PDF]

, 2012
The iron-catalyzed hydrocarboxylation of aryl alkenes has been developed using a highly active bench-stable iron(II) precatalyst to give alpha-aryl carboxylic acids in excellent yields and with near-perfect regioselectivity. Using just 1 mol % FeCl2, bis(
Greenhalgh, Mark D., Thomas, Stephen P.
core   +1 more source

Enhancing CoFe Catalysts with V2CTX MXene‐Derived Materials for Anion Exchange Membrane Electrolyzers

Advanced Functional Materials, EarlyView.
MXene dervied CoFe composites show increased initial Oxygen Evolution Reaction (OER) activity compared to the pure CoFe and MXene in an Anion Exchange Membrane device. Vanadium vacancies in the MXene plays a role in increased OER activity and hinders Fe leaching in the AEM device over using the pure V2C MXene as a support material for the CoFe ...
Can Kaplan, Karuppasamy Dharmaraj, Thorsten Schultz, Leiqiang Qin, Ningjun Chen, Danielle A. Douglas‐Henry, Bastian Schmiedecke, Merve Buldu‐Akturk, Axel Zuber, Iris Dorbandt, Maximilian Reinhardt, Yael Rodriguez‐Ayllon, Yan Lu, Valeria Nicolosi, Norbert Koch, Johanna Rosen, Michelle P. Browne   +16 more
wiley   +1 more source

Mineralisation of 2,4-dichlorophenoxyacetic acid by acoustic or hydrodynamic cavitation in conjunction with the advanced Fenton process [PDF]

, 2008
The mineralisation of 2,4-dichlorophenoxyacetic acid (2,4-D) in the presence of zero-valent iron and hydrogen peroxide (the Advanced Fenton process – AFP) whilst being subjected to acoustic or hydrodynamic cavitation is reported.
Bremner, David H., Chakinala, Anand G., Cravotto, Giancarlo, Di Carlo, Stefano   +3 more
core   +3 more sources

Electroactive Metal–Organic Frameworks for Electrocatalysis

Advanced Functional Materials, EarlyView.
Electrocatalysis is crucial in sustainable energy conversion as it enables efficient chemical transformations. The review discusses how metal–organic frameworks can revolutionize this field by offering tailorable structures and active site tunability, enabling efficient and selective electrocatalytic processes.
Irena Senkovska, Yutong Luo, Ruyan Zhao, Jianjun Zhang, Mingchao Wang, Xinliang Feng, Eike Brunner, Stefan Kaskel   +7 more
wiley   +1 more source

Tuning the Electronic Structure and Spin State of Fe─N─C Catalysts Using an Axial Oxygen Ligand and Fe Clusters for High‐Efficiency Rechargeable Zinc–Air Batteries

Advanced Functional Materials, EarlyView.
A FeN4─O/Clu@NC‐0.1Ac catalyst containing atomically‐dispersed FeN4─O sites (medium‐spin Fe2+) and Fe clusters delivered a half‐wave potential of 0.89 V for ORR and an overpotential of 330 mV at 10 mA cm−2 for OER in 0.1 m KOH. When the catalyst was used in a rechargeable Zn–air battery, a power density of 284.5 mW cm−2 was achieved with excellent ...
Yongfang Zhou, Yu Mao, Mengyao Chang, Ziyun Wang, Wenke Xie, Cuizhu Ye, Shanghai Wei, Lars Thomsen, Geoffrey I. N. Waterhouse   +8 more
wiley   +1 more source

Plaster of Paris containing zero valent iron particles: Designing a permeable reactive barrier, used for remediation of 4-nitroaniline pollution

Journal of Sustainable Construction Materials and Technologies, 2021
Permeable reactive barrier (PRB) containing zero valent iron (ZVI), plaster and additives to make a porous composite structure, was tested to remove an organic nitro compound as model pollutant.
Patrick Sharrock, Marina Fıallo, Farida Fernane, Saliha Boudıa   +3 more
doaj   +1 more source

Synthesis and application of zeolite and glass fiber supported zero valent iron nanoparticles as membrane component for removal nitrate and Cr (+6) ions [PDF]

, 2017
In the present paper the synthesis and characterization of zeolite and glass fiber supported zero valent iron nanoparticles (Ze-ZVI, GF-ZVI NPs) are reported.ZVI, Ze-ZVI and GF-ZVI NPs size, composition and morphology were characterized by Scanning ...
Allahverdiyeva, Gunel R., DI PALMA, Luca, Hasanova, Ulviyya A., Maharramov, Abel M., Ramazanov, Mahammadali A.   +4 more
core   +1 more source