Reduced graphene oxide/SiO2 (RGO/SiO2) serving as a novel spherical support for Ziegler-Natta (Z-N) catalyst is reported. The surface and interior of the support has a porous architecture formed by RGO/SiO2 sandwich structure.
Enqi Su +7 more
doaj +1 more source
Atualmente, há uma grande demanda pelo polibutadieno com alto teor de unidades 1,4-cis, devido às suas excelentes propriedades físicas, tais como alta resistência à abrasão, baixo desenvolvimento de calor, baixa resistência ao rolamento, maior ...
Denise S. S. Nunes +2 more
doaj +1 more source
Foi utilizado o sistema catalítico tipo Ziegler-Natta modificado, constituído por TiCl4/I2/Al(i-Bu)3 para a síntese de polibutadieno com alto teor de unidades 1,4-cis.
Neusa M. T. Pires +2 more
doaj +1 more source
Evaluation of the Reactivity of Methanol and Hydrogen Sulfide Residues with the Ziegler-Natta Catalyst during Polypropylene Synthesis and Its Effects on Polymer Properties. [PDF]
Hernández-Fernández J +2 more
europepmc +1 more source
Modeling and Optimization of propylene polymerization with branching [PDF]
A kinetic model has been proposed to fit the experimental data (2003) available from the open literature for branched propylene polymerization system. The present system considered is a binary catalyst system, in which the first catalyst produces the ...
Majumdar, S +2 more
core +2 more sources
Experimental-Density Functional Theory (DFT) Study of the Inhibitory Effect of Furan Residues in the Ziegler-Natta Catalyst during Polypropylene Synthesis. [PDF]
Hernández-Fernández J +2 more
europepmc +1 more source
Impact of Traces of Hydrogen Sulfide on the Efficiency of Ziegler-Natta Catalyst on the Final Properties of Polypropylene. [PDF]
Hernández-Fernández J +2 more
europepmc +1 more source
Theoretical-Experimental Study of the Action of Trace Amounts of Formaldehyde, Propionaldehyde, and Butyraldehyde as Inhibitors of the Ziegler-Natta Catalyst and the Synthesis of an Ethylene-Propylene Copolymer. [PDF]
Hernández-Fernández J +2 more
europepmc +1 more source
Coordination copolymerization monitoring of ethylene and alfa-olefins by in-line Raman spectroscopy. [PDF]
Comparán-Padilla VE +6 more
europepmc +1 more source
Nanocrystalline TiO2 and halloysite clay mineral composite films prepared by sol-gel method:Synergistic effect and the case of silver modification to the photocatalytic degradation of basic blue- 41 azo dye in water [PDF]
Tubular halloysite clay mineral and nanocrystalline TiO2 were incorporated in the preparation of nanocomposite films on glass substrates via sol-gel method at 450 °C.
Kaplani, E. +4 more
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