Results 41 to 50 of about 651 (134)

Impact of Commercial Polyolefin Architecture and Composition on Its Ability to Compatibilize High‐Density Polyethylene/Isotactic Polypropylene Blends

Journal of Polymer Science, Volume 64, Issue 14, Page 3057-3072, 15 July 2026.
This research elucidates the relationship between the molecular structure of commercially available ethylene–propylene copolymers and an ethylene/1‐olefin copolymer and its ability to compatibilize high‐density polyethylene/isotactic polypropylene blends. These findings indicate that the compatibilization of these blends with random copolymers benefits
Bailey Eberle, Susan K. Houston, Hannah Giffin, Mark Dadmun   +3 more
wiley   +1 more source

An Investigation on Polymerization of Ethylene by Ziegler-Natta Catalyst in the Presence of a Promoter: Polymerization Behavior and Polymer Microstructure

Bulletin of Chemical Reaction Engineering & Catalysis, 2018
The effect of a halocarbon (ethyl chloride) as a promoter on a Ziegler-Natta catalyst composed of‌ T‌iCl4 (catalyst), AlEt3 (activator) and Mg(OEt)2 (support) in the polymerization of ethylene have been investigated.
Yaghoob Gholami, Majid Abdouss, Sadegh Abedi, Farhad Azadi, Pezhman Baniani, Maryam Arsalanfar   +5 more
doaj   +1 more source

Organic Photoelectrochemical Cells Beyond Performance: Interface and Catalyst Engineering for Durability

Advanced Energy Materials, Volume 16, Issue 25, 1 July 2026.
Organic photoelectrochemical cells based on π‐conjugated semiconductors offer a versatile platform for solar fuel generation. This review outlines operating principles, device architectures, and key metrics, and highlights advances in p‐ and n‐type photoelectrodes, interfacial engineering, and catalyst integration.
Jaehyeong Kim, Jung Min Ha, Yeonjeong Lee, Seung Won Oh, Wangyeon Lee, Munsu Kwon, Soonyong Lee, Jin Young Kim, Han Young Woo   +8 more
wiley   +1 more source

MgCl2 Support Preparation Techniques and Their Effects on Ziegler-Natta Catalysts Performance in Propylene Polymerization [PDF]

علوم و تکنولوژی پلیمر, 2013
A primary adduct of MgCl2.3.3EtOH (A0) was prepared by melt quenching and then it was further dealcoholated by thermal and chemical methods. In thermal dealcoholation, two different support samples with MgCl2.2.7EtOH (A1) and MgCl2.1.8EtOH (A2) formulas ...
Najmeh Hadian, Mehdi Nekoomanesh-Haghighi, Shokoofeh Hakim, Naeimeh Bahri-Laleh   +3 more
doaj   +1 more source

Cyclic Olefin Copolymers as Versatile Materials for Advanced Engineering Applications

Advanced Functional Materials, Volume 36, Issue 47, 11 June 2026.
Cyclic olefin copolymers (COCs) are presented as highly versatile materials combining tunable synthesis, excellent optical properties, and mechanical robustness. Their potential spans microfluidics, bioengineering, and advanced electronics, while emerging self‐healing and sustainable solutions highlight future opportunities.
Giulia Fredi, Norma Mallegni, Andrea Dorigato, Mario Milazzo   +3 more
wiley   +1 more source

Sixtieth Anniversary of Ziegler-Natta Catalysts and Stereospecific Polymerization [PDF]

Kemija u Industriji, 2015
This review article highlights the history of the discoveries of organometallic catalysts and stereospecific polymerization of α-olefins, dienes and a number of vinyl monomers by Karl Ziegler and Giulio Natta sixty years ago, their developments and ...
Janović Z. , Veksli Z.
doaj  

Ti+4 determination in Ziegler–Natta polymerization catalysts via UV‒vis spectroscopy method [PDF]

Polyolefins Journal
The determination of Ti+4 in Ziegler–Natta catalysts is highly relevant for industrial plants that use Ziegler–Natta (ZN) catalysts based on TiCl4 as a source of titanium.
Jonas Biagini, Joao Henrique dos Santos
doaj   +1 more source

Study of Ethylene Polymerization Kinetics by TiCl4/Mg(OC2H5)2 Catalyst and Determination of the Active Sites Concentration [PDF]

علوم و تکنولوژی پلیمر, 2008
Ethylene was polymerized in slurry phase over a TiCl4/Mg(OC2H5)2 catalyst activated by Al(C2H5)3. It was shown experimentally that mass transfer resistance has no effect on polymerization kinetics.
S. Hakim, M.M. Mortazavi
doaj   +1 more source

“Naked” Divalent Metal Cations Stabilized by Weakly Coordinating Anions: Syntheses, Properties, and Emerging Applications

European Journal of Inorganic Chemistry, Volume 29, Issue 14, 14 May 2026.
The preparation of soluble and stable metal M2+ dications only stabilized by weakly coordinating anions, that is, M[WCA]2 salts, is an emerging field that, beyond its fundamental interest, holds promise in reactivity due to the high electrophilicity of the central M2+ center.
Samuel Dagorne, Béatrice Jacques, Geetika Gupta, Rudolf J. Wehmschulte   +3 more
wiley   +1 more source

Process Modeling for Propylene Polymerization to Transfer Reaction Kinetics From Lab to Plant

Chemie Ingenieur Technik, Volume 98, Issue 5, Page 254-261, May 2026.
The modeling approach combines an industrial model for a fourth‐generation Ziegler–Natta catalyst with lab‐scale derived kinetics of a novel fifth‐generation catalyst. By transferring intrinsic kinetics across scales, polypropylene production can be predicted. Accurate melt flow rate prediction is only obtained with an additional adjustment.
Anna Konopka, Matthias Feigel, Johanna Fernengel, Maximilian Dochnahl, Richard W. Fischer, Olaf Hinrichsen   +5 more
wiley   +1 more source