A produção em larga escala de materiais poliméricos de elevado interesse industrial, provenientes da polimerização estereoespecífica de olefinas, tornou-se possível depois do advento dos catalisadores Ziegler-Natta.
Fabricio Machado, José Carlos Pinto
doaj
Heterogeneity of Active Sites in the Polymer Chain Transfer Reactions at Olefin Polymerization over Multisite Supported Ziegler-Natta Catalysts. [PDF]
Matsko M, Zakharov V.
europepmc +1 more source
DFT and ONIOM Simulation of 1,3-Butadiene Polymerization Catalyzed by Neodymium-Based Ziegler-Natta System. [PDF]
Masliy AN +3 more
europepmc +1 more source
In the first part of this thesis, a pre-commercial industrial catalyst was treated with different hydrocarbon solvents and mixtures thereof with titanium tetrachloride to enhance its activity in the polymerization of propylene. In the second part of this
Hanisch, Christian
core
Impact of Traces of Hydrogen Sulfide on the Efficiency of Ziegler-Natta Catalyst on the Final Properties of Polypropylene. [PDF]
Hernández-Fernández J +2 more
europepmc +1 more source
Theoretical-Experimental Study of the Action of Trace Amounts of Formaldehyde, Propionaldehyde, and Butyraldehyde as Inhibitors of the Ziegler-Natta Catalyst and the Synthesis of an Ethylene-Propylene Copolymer. [PDF]
Hernández-Fernández J +2 more
europepmc +1 more source
Aliphatic Anion Exchange Ionomers with Long Spacers and No Ether Links by Ziegler-Natta Polymerization: Properties and Alkaline Stability. [PDF]
Becerra-Arciniegas RA +5 more
europepmc +1 more source
Structure and Stability of Aluminum Alkyl Cocatalysts in Ziegler−Natta Catalysis
The structure of organoaluminum(halide) complexes, used as cocatalysts in Ziegler−Natta catalysis, is investigated by experimental far-infrared spectroscopy and by quantum simulations.
Betty B. Coussens (1588993) +6 more
core +1 more source
Coordination copolymerization monitoring of ethylene and alfa-olefins by in-line Raman spectroscopy. [PDF]
Comparán-Padilla VE +6 more
europepmc +1 more source
Removing trace acetylene from ethylene streams is critical to protect Ziegler–Natta polymerization. Eggshell Pd–Ag/θ-Al2O3 spheres (0.03 wt% Pd, 0.13 wt% Ag) were promoted with 1 wt% alkaline-earth additives to suppress green oil and improve ethylene ...
Farnaz Rahbar Shamskar +2 more
doaj +1 more source

