A produção em larga escala de materiais poliméricos de elevado interesse industrial, provenientes da polimerização estereoespecífica de olefinas, tornou-se possível depois do advento dos catalisadores Ziegler-Natta.
Fabricio Machado, José Carlos Pinto
doaj
Heterogeneity of Active Sites in the Polymer Chain Transfer Reactions at Olefin Polymerization over Multisite Supported Ziegler-Natta Catalysts. [PDF]
Matsko M, Zakharov V.
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DFT and ONIOM Simulation of 1,3-Butadiene Polymerization Catalyzed by Neodymium-Based Ziegler-Natta System. [PDF]
Masliy AN +3 more
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Impact of Traces of Hydrogen Sulfide on the Efficiency of Ziegler-Natta Catalyst on the Final Properties of Polypropylene. [PDF]
Hernández-Fernández J +2 more
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Theoretical-Experimental Study of the Action of Trace Amounts of Formaldehyde, Propionaldehyde, and Butyraldehyde as Inhibitors of the Ziegler-Natta Catalyst and the Synthesis of an Ethylene-Propylene Copolymer. [PDF]
Hernández-Fernández J +2 more
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Aliphatic Anion Exchange Ionomers with Long Spacers and No Ether Links by Ziegler-Natta Polymerization: Properties and Alkaline Stability. [PDF]
Becerra-Arciniegas RA +5 more
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Removing trace acetylene from ethylene streams is critical to protect Ziegler–Natta polymerization. Eggshell Pd–Ag/θ-Al2O3 spheres (0.03 wt% Pd, 0.13 wt% Ag) were promoted with 1 wt% alkaline-earth additives to suppress green oil and improve ethylene ...
Farnaz Rahbar Shamskar +2 more
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Coordination copolymerization monitoring of ethylene and alfa-olefins by in-line Raman spectroscopy. [PDF]
Comparán-Padilla VE +6 more
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Correction: In-chain functionalized syndiotactic 1,2-polybutadiene by a Ziegler-Natta iron(iii) catalytic system. [PDF]
Liang S +6 more
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Organische Trägermaterialien für Ziegler-Natta-Katalysatoren
Ziel dieser Arbeit war die Entwicklung eines auf einem organischen Trägermaterial basierenden Ziegler-Natta-Katalysatorsystems, welches die erforderliche Fragmentierbarkeit in möglichst kleine Fragmente aufweist. Hierfür sah das Konzept dieser Arbeit eine direkte Bildung der aktiven Zentren auf fein dispergierten, Hydroxy-funktionalisierten Polystyrol ...
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