Results 61 to 70 of about 117,309 (167)

Ethylene Homopolymerization by Ziegler-Natta (TiCl4/MgCl2) Catalyst through Full Factorial Experimental Design [PDF]

علوم و تکنولوژی پلیمر, 2009
Full factorial experimental design (23) for the evaluation of slurry ethylene polymerization in the presence of an industrial TiCl4/MgCl2 Ziegler-Natta catalyst was employed.
S. Hakim, M.M. Mortazavi, L. Moballegh, M. Nekoomanesh Haghighi   +3 more
doaj   +1 more source

Potential of Thermoset Polyolefins for FRP Concrete Reinforcing Bars

Polymer Composites, Volume 47, Issue 18, Page 16155-16176, 20 September 2026.
Overview of XLPO and pDCPD resins for FRP reinforcing bars, highlighting resin chemistry, key performance characteristics, fiber sizing interactions, and principal degradation mechanisms in concrete environments. ABSTRACT Although thermoset polyolefins offer resistance to hydrolytic degradation and favorable processing characteristics, their potential ...
Osama Omar, Farzaneh Mahmoudi, Leonidas G. Bachas, Francisco De Caso, Brahim Benmokrane, Antonio Nanni   +5 more
wiley   +1 more source

Unlocking the Potential of Organoaluminum Reagents for Versatile C─C Couplings Using YPhos‐Pd Catalysts

Advanced Synthesis &Catalysis, Volume 368, Issue 18, 19 September 2026.
A general C─C cross‐coupling method employing earth‐abundant organoaluminium nucleophiles is enabled by electronically highly donating and sterically demanding ylide‐substituted phosphine (YPhos) ligands under Pd catalysis. This protocol represents an organoaluminium cross‐coupling that operates with a single catalyst system across all carbon ...
Nicolas Kaiser, Julius Busse, Ben Wichmann, Viktoria H. Gessner   +3 more
wiley   +1 more source

Visible‐Light Driven Acetylene Semi‐Hydrogenation to Ethylene With a Copper Photosensitizer and a Cobaloxime Catalyst

Chemistry – A European Journal, Volume 32, Issue 33, 1 September 2026.
A fully noble‐metal‐free photocatalytic system that couples cobaloxime catalysis with Cu photosensitizer for HAT‐driven acetylene‐to‐ethylene conversion is reported. ABSTRACT The purification of ethylene streams from acetylene impurities remains a key industrial challenge, for which light‐powered strategies are emerging as sustainable alternatives to ...
Anna Fortunato, Sharon Silloni, Brando Adranno, Marianna Barbieri, Luka Đorđević, Francesca Arcudi   +5 more
wiley   +1 more source

From Cages to Sheets: Computational Elucidation of Methylaluminoxane Structure and Reactivity

ChemPlusChem, Volume 91, Issue 8, August 2026.
Methylaluminoxane (MAO), the dominant cocatalyst in metallocene‐based olefin polymerization, has resisted structural characterization for decades. This review traces the computational journey from early cage and nanotube proposals to the identification of two‐dimensional aluminoxane sheets as the thermodynamically preferred motif, and how this ...
Mikko Linnolahti, Perttu Hanhisalo, Aleksi Vähäkangas   +2 more
wiley   +1 more source

Synthesis of polyethylene/exfoliated MoS₂ nanocomposites by in situ exfoliation polymerization using Ziegler–Natta catalyst intercalated MoS₂

, 2017
A new synthetic route for polyethylene (PE)/exfoliated MoS2 (EMoS2) nanocomposites using novel Ziegler–Natta catalyst intercalated MoS2 was designed.
He-Xin Zhang, Keun-Byoung Yoon, Hao Zhang   +2 more
core   +1 more source

Tailoring polypropylene properties by package of internal/external donor in Ziegler Natta catalysts [PDF]

Polyolefins Journal
Insights have been developed into the influence of different structures, including bismethoxymethylfluorene (B) and 2,2-diisopropyl succinate (I), on both internal donor (ID) and external donor (ED) roles on the performance of MgCl2/ID/TiCl4.
Nona Ghasemi Hamedani, Fatemeh Poorsank, Hassan Arabi, Seyed Mehdi Ghafelehbashi   +3 more
doaj   +1 more source

Acyclic Hydrocarbon α,ω‐Dienes: From Biomass and Plastic Upcycling to Carbocycles, Precision Polymers, and Cross‐Linked Elastomers

ChemSusChem, Volume 19, Issue 14, 29 July 2026.
Hydrocarbon α,ω‐dienes are mainly produced from steam‐cracking derivatives, but high costs, complexity, and environmental impact limit their use. This review highlights sustainable paths from biomass and plastic upcycling, and surveys catalytic transformations into carbocycles and specialty polymers, emphasizing their role as modular building blocks ...
Rosa Villaccio, Giuseppe Leone
wiley   +1 more source

Generation of Homogeneous (sp³-C₁)-Bridged Cp/Amido and Cp/Phosphido Group 4 Metal Ziegler−Natta Catalyst Systems

, 2016
Generation of Homogeneous (sp3-C1)-Bridged Cp/Amido and Cp/Phosphido Group 4 Metal Ziegler−Natta Catalyst ...
Klaus Kunz (2720305), Gerhard Erker (1443580), Steve Döring (2720311), Roland Fröhlich (2430502), Gerald Kehr (1443583)   +4 more
core   +1 more source

Polimerização 1,4 - cis de butadieno com o sistema catalítico tetracloreto de titânio/triisobutilalumínio/iodo 1,4 cis-Polymerization of butadiene by the catalyst system titanium tetrachloride/triisobutylaluminium/iodine

Polímeros, 2000
Foi utilizado o sistema catalítico tipo Ziegler-Natta modificado, constituído por TiCl4/I2/Al(i-Bu)3 para a síntese de polibutadieno com alto teor de unidades 1,4-cis.
Neusa M. T. Pires, Marcos A. S. Costa, Fernanda M. B. Coutinho   +2 more
doaj   +1 more source