How can pH value during catalyst preparation affect the performance of vanadium-modified (SiO2/MgO/ MgCl2)•TiClx Ziegler-Natta polyethylene catalysts [PDF]
Vanadium-modified (SiO2/MgO/MgCl2)•TiClx Ziegler-Natta catalysts were prepared through co-impregnation of water-soluble magnesium and vanadium salts under different pH values.
Ting Fu +5 more
doaj +1 more source
Schematic representation of the REMD‐RM method, which integrates the Red Moon (RM) method and the replica‐exchange molecular dynamics (REMD) method. By enhancing molecular reconfiguration and diffusion in the reactant system, the REMD‐RM method can efficiently explore a wide phase space and effectively accelerate the search for reaction candidates ...
Kentaro Matsumoto +4 more
wiley +1 more source
Stereospecific Living Ziegler−Natta Polymerization of 1-Hexene
Stereospecific Living Ziegler−Natta Polymerization of 1 ...
Kumudini C. Jayaratne (2443618) +1 more
core +1 more source
Olefin Polymerizations Oriented by Rational Designs of Group‐13 Compounds
In coordination olefin polymerization chemistry, boron and aluminum compounds play important roles in both catalyst components and monomers. This personal account introduces our recent progress on the development of catalyst systems featured by the design of group‐13 counteranions, as well as the application of boronic acid‐crosslinked polyolefins to ...
Ryo Tanaka, Yu Zou
wiley +1 more source
Sixtieth Anniversary of Ziegler-Natta Catalysts and Stereospecific Polymerization [PDF]
This review article highlights the history of the discoveries of organometallic catalysts and stereospecific polymerization of α-olefins, dienes and a number of vinyl monomers by Karl Ziegler and Giulio Natta sixty years ago, their developments and ...
Janović Z. , Veksli Z.
doaj
Design of stereoselective Ziegler–Natta propene polymerization catalysts [PDF]
After five decades of largely serendipitous (albeit formidable) progress, catalyst design in Ziegler–Natta olefin polymerization, i.e., the rational implementation of new active species to target predetermined polyolefin architectures, has ultimately become a realistic ambition, thanks to a much deeper fundamental understanding and major ...
BUSICO, VINCENZO +5 more
openaire +3 more sources
PEDOT:PSS—A Key Material for Bioelectronics
PEDOT:PSS ‐ Poly(3,4‐ethylenedioxythiophene) polystyrene sulfonate ‐ is typically processed from water dispersions to form multifunctional and multidimensional constructs with tunable electronic and ionic conductivity. Throught processing engineering, PEDOT:PSS is intergrated in bioelectronic devices that operate efficiently in physiological conditions
Alan Eduardo Ávila Ramírez +5 more
wiley +1 more source
Since its emergence over 50 years ago, the structure of surface sites in Ziegler-Natta catalysts, which are responsible for a major fraction of the world’s supply of polyethylene (PE) and polypropylene (PP), has remained elusive.
Sebastian, Sabisch +4 more
core +1 more source
Study on the Effects of Temperature, Time and the Policy of Prepolymerization on Particle Morphology in Propylene Slurry Polymerization with Heterogeneous Ziegler-Natta Catalysts [PDF]
The effects of temperature, time and the strategy of prepolymerization were studied on the morphology of polypropylene particles. propylene polymerization was carried out in slurry phase using 4th generation of Ziegler-Natta Catalyst, cyclohexylmethyl ...
G. Pircheraghi +2 more
doaj +1 more source
The coordinative state of aluminium alkyls in Ziegler–Natta catalysts [PDF]
Multinuclear solid-state NMR provides insight in the interactions of aluminium alkyl based cocatalysts in MgCl2-supported Ziegler–Natta catalysts.
E. S. (Merijn) Blaakmeer +2 more
openaire +2 more sources

