Results 41 to 50 of about 94,776 (218)

“Naked” Divalent Metal Cations Stabilized by Weakly Coordinating Anions: Syntheses, Properties, and Emerging Applications

European Journal of Inorganic Chemistry, Volume 29, Issue 14, 14 May 2026.
The preparation of soluble and stable metal M2+ dications only stabilized by weakly coordinating anions, that is, M[WCA]2 salts, is an emerging field that, beyond its fundamental interest, holds promise in reactivity due to the high electrophilicity of the central M2+ center.
Samuel Dagorne, Béatrice Jacques, Geetika Gupta, Rudolf J. Wehmschulte   +3 more
wiley   +1 more source

Advantages of an Emulsion‐Produced Ziegler‐Natta Catalyst Over a Conventional Ziegler‐Natta Catalyst

Macromolecular Materials and Engineering, 2005
AbstractSummary: Self‐supported and MgCl2‐supported Ziegler‐Natta catalysts, produced by two catalyst synthesis methods are compared. Borealis Polymers OY (Finland), who supplied the catalysts, developed the catalyst synthesis methods. The first method (Method One) is based on an emulsion system and consists of an in situ single step preparation.
Mohammed Abboud, Peter Denifl, Karl‐Heinz Reichert   +2 more
openaire   +1 more source

Process Modeling for Propylene Polymerization to Transfer Reaction Kinetics From Lab to Plant

Chemie Ingenieur Technik, Volume 98, Issue 5, Page 254-261, May 2026.
The modeling approach combines an industrial model for a fourth‐generation Ziegler–Natta catalyst with lab‐scale derived kinetics of a novel fifth‐generation catalyst. By transferring intrinsic kinetics across scales, polypropylene production can be predicted. Accurate melt flow rate prediction is only obtained with an additional adjustment.
Anna Konopka, Matthias Feigel, Johanna Fernengel, Maximilian Dochnahl, Richard W. Fischer, Olaf Hinrichsen   +5 more
wiley   +1 more source

"Supported Ziegler-Natta catalysts from MgCl2·nROH precursors and its catalytic behaviors for diene copolymerization"

Hecheng xiangjiao gongye
The precursor MgCl2 · nROH of supported Ziegler Natta catalyst was prepared by chemical activation method, and different pre catalysts TiCl4/MgCl2 (C-Cat) were prepared by loading TiCl4.
FAN Xun-zhang, ZHAO Yuan-jin, LUO Shu-fang, HE Ai-hua?
doaj   +1 more source

Electron Microscopy Transfer System to Protect Atmosphere‐Sensitive Materials for Scanning Electron Microscopy Characterization

Microscopy Research and Technique, Volume 89, Issue 5, Page 759-768, May 2026.
SEM–EDX and XRD characterization confirm that pouches made from readily available aluminum foil, used in combination with a commercial cryo‐EM transfer system, effectively protect highly atmosphere‐sensitive and/or hygroscopic materials from contamination during transfer from inert environments to the SEM vacuum chamber.
Louis G. Corcoran, Ellen M. Monzo, Chinomso E. Onuoha, Shivasheesh Varshney, Han Seung Lee, Chris Frethem, Bharat Jalan, Alon V. McCormick, R. Lee Penn   +8 more
wiley   +1 more source

Chemical state analysis of magnesium-supported Ziegler-Natta catalyst by soft X-ray emission spectrometer (SXES) after contact with alkyl aluminum [PDF]

Polyolefins Journal
This report is on the characterization of active Ti center in heterogeneous Ziegler-Natta catalysts with Soft X-ray Emission Spectrometer (SXES). Since titanium in the catalyst has various chemical bonds, it is important to grasp the chemical bond state.
Masayoshi Saito, Hiroshi Kashimura, Takuo Kataoka, Masahide Murata, Yusuke Sakuda, Hiroyuki Yamada, Hideyuki Takahashi   +6 more
doaj   +1 more source

Overcoming Challenges in 3D Printing of Polyolefins and Their Composites: A Review on Strategies for Improved Printability and Performance

Polymer Engineering &Science, Volume 66, Issue 5, Page 3100-3141, May 2026.
This review integrates the molecular fundamentals, key challenges, and mitigation strategies in polyolefin 3D printing, focusing on shrinkage, warpage, and adhesion control. It highlights material design approaches using recycled polyolefins and functional fillers to improve printability, mechanical properties, and sustainability in additive ...
Malik Hassan, Philip McMorran, Marwan Eid, Julia Blair, Amar K. Mohanty, Manjusri Misra   +5 more
wiley   +1 more source

Theoretical Study of the Halogen Concentration Effect on the 1,3-Butadiene Polymerization Catalyzed by the Neodymium-Based Ziegler–Natta System

Reactions
In this work, an attempt is made to theoretically substantiate the experimentally known facts of the influence of halogen concentration on the catalytic properties of the neodymium-based Ziegler–Natta system.
Alexey N. Masliy, Ildar G. Akhmetov, Andrey M. Kuznetsov, Ilsiya M. Davletbaeva   +3 more
doaj   +1 more source

Development of Ziegler-Natta catalysts for the synthesis of polyolefins

, 2022
reservedLo scopo di questa tesi è la visione dello sviluppo di catalizzatori Ziegler-Natta per la sintesi di olefine. Vedremo cos'è un catalizzatore e nello specifico uno di tipo Ziegler-Natta, considerando i suoi componenti, gli effetti che hanno, l ...
MARCELLAN, GIOVANNI
core  

Ti+4 determination in Ziegler–Natta polymerization catalysts via UV‒vis spectroscopy method [PDF]

Polyolefins Journal
The determination of Ti+4 in Ziegler–Natta catalysts is highly relevant for industrial plants that use Ziegler–Natta (ZN) catalysts based on TiCl4 as a source of titanium.
Jonas Biagini, Joao Henrique dos Santos
doaj   +1 more source