Immobilizing metallocene by solid polymethylaluminoxane “sMAO” for slurry-phase ethylene-1-hexene copolymerization [PDF]
MATEC Web of Conferences, 2022 In the field of olefin catalytic polymerization, metallocene catalysts show higher activity than traditional Ziegler-Natta catalysts. In this study, benzoic acid catalyzed the controlled hydrolysis of trimethylaluminum (TMA) to methylaluminoxane (MAO ...
Wu Chaofan +5 more
doaj +1 more source
Structural Characterization of the EtOH–TiCl4–MgCl2 Ziegler–Natta Precatalyst [PDF]
, 2016 The Ziegler–Natta polymerization is one major example of application of catalysis in industry. Since the first discovery of Ziegler and Natta, several modifications of the catalyst have been developed, in order to improve its performance.
D. Gajan (2925687) +9 more
core +2 more sources
Fine Tuning of Catalyst Active Sites to Access Advanced Ultrahigh‐Melting Polyolefins
Angewandte Chemie, EarlyView.A redesign of the active site of the pyridylamido hafnium (Hf) catalysts can enhance the performance of this catalyst family and unlock previously inaccessible polymer structures. When the catalyst is precontacted with allyltrimethylsilane the active species is modified and the catalyst experiences a new life becoming able to polymerize sterically ...
Fabio De Stefano +3 more
wiley +2 more sources
Organische Trägermaterialien für Ziegler-Natta-Katalysatoren [PDF]
, 2017 Ziel dieser Arbeit war die Entwicklung eines auf einem organischen Trägermaterial basierenden Ziegler-Natta-Katalysatorsystems, welches die erforderliche Fragmentierbarkeit in möglichst kleine Fragmente aufweist.
Nietzel, Sven Ingo
core +1 more source
Characterization of phthalate internal donor in MgCl2 supported Ziegler-Natta catalyst by solid state 13C NMR [PDF]
Polyolefins Journal, 2022 Ziegler-Natta catalyst for propylene polymerization, which TiCl4 and di-alkyl phthalate were supported on MgCl2, was analyzed by solid state 13C NMR. It was confirmed that the spin-lattice relaxation time (“relaxation time” hereafter) of carbonyl group ...
Masayoshi Saito +4 more
doaj +1 more source
, 2023 The performance of isopropyl myristate, methyl trimethylacetate, and dibutyl sebacate (IPM, MTMA, and DBS respectively) as activity limiting agents (ALA) were evaluated using a post phthalate Ziegler Natta catalyst system...
Albeladi, Abdulrahman +5 more
core +1 more source
Stereospecific Living Ziegler−Natta Polymerization of 1-Hexene
, 2016 Stereospecific Living Ziegler−Natta Polymerization of 1 ...
Kumudini C. Jayaratne (2443618) +1 more
core +1 more source
Development of Ziegler-Natta catalysts for the synthesis of polyolefins
, 2022 reservedLo scopo di questa tesi è la visione dello sviluppo di catalizzatori Ziegler-Natta per la sintesi di olefine. Vedremo cos'è un catalizzatore e nello specifico uno di tipo Ziegler-Natta, considerando i suoi componenti, gli effetti che hanno, l ...
MARCELLAN, GIOVANNI
core
Determination of Optimal Reaction Temperature and Hydrogen Amount for Propylene Polymerization by a Mathematical Model [PDF]
Kemija u Industriji, 2019 Regarding the complexity of Ziegler-Natta catalyst kinetics in polypropylene polymerization, so far, there is no adequate model to determine the best process conditions for predicting average molecular weight and dispersity as the most crucial final ...
Gholam Hossain Varshouee +3 more
doaj +1 more source
DIENES POLYMERISATION WITH METATHESIS AND ZIEGLER-NATTA HOMOGENEOUS CATALYSTS
, 1991 IN THIS THESIS THE POLYMERISATION OF DIENES WITH ZIEGLER-NATTA AND METATHESIS CATALYSTS IS DESCRIBED AND THE RELATION BETWEEN THE TWO TYPES OF POLYMERISATION IS EXAMINED.
Μπόκαρης, Ευθύμιος
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