Dataset of energetically accessible structures of MgCl2/TiCl4 clusters for Ziegler-Natta catalysts [PDF]
This data article provides a dataset of the energetically accessible structures including the most stable structures of xMgCl2/yTiCl4 nanoplates (x = 6–19, y = 0–4).
Gentoku Takasao +5 more
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High Melting Point of Linear, Spiral Polyethylene Nanofibers and Polyethylene Microspheres Obtained Through Confined Polymerization by a PPM‐Supported Ziegler‐Natta Catalyst [PDF]
In this work, different types of polyethylene (linear, spiral nanofibers and microspheres) were obtained via confined polymerization by a PPM‐supported Ziegler‐Natta catalyst.
Dr. Yu Xiao +3 more
doaj +2 more sources
Preparation of High-Performance Polyethylene Nanocomposites with Oleic Acid–Siloxene-Supported Ziegler–Natta Catalysts [PDF]
The addition of two-dimensional inorganic nanomaterials can effectively enhance the properties of polyethylene (PE). In the present study, a series of high-performance PE/oleic acid (OA)–siloxene nanocomposites were prepared by in situ polymerization ...
Huan Yue +6 more
doaj +2 more sources
Assessing 1,9-Decadiene/Ethylene Copolymerization with Ziegler–Natta Catalyst to Access Long Chain-Branched Polyethylene [PDF]
Yang Liu, Yawei Qin, Jin-Yong Dong
doaj +2 more sources
The Use of Electron Donors to Increase Stereospecificity in Ziegler-Natta Propylene Polymerization [PDF]
Different chemical components in traditional Ziegler–Natta catalytic system include: (1) titanium and vanadium containing compounds, mostly TiCl4, as an active centre, (2) trialkylaluminium-based Lewis acid compounds, especially triethylaluminium, as ...
Farshid Nouri-Ahangarani +2 more
doaj +1 more source
Imido-modified SiO2-supported Ti/Mg Ziegler-Natta catalysts for ethylene polymerization and ethylene/1-hexene copolymerization [PDF]
A novel imido-modified SiO2-supported Ti/Mg Ziegler-Natta catalyst for ethylene and ethylene/1-hexene polymerization is investigated. The catalyst is prepared by modification of (SiO2/MgO/MgCl2)TiClx Ziegler-Natta catalysts via supporting vanadium ...
Ting Fu +5 more
doaj +1 more source
The Influence of Ziegler-Natta and Metallocene Catalysts on Polyolefin Structure, Properties, and Processing Ability [PDF]
Mohd Azlan Hussain +2 more
exaly +2 more sources
Active site nature of magnesium dichloride-supported titanocene catalysts in olefin polymerization [PDF]
Heterogeneous Ziegler-Natta and homogeneous metallocene catalysts exhibit greatly different active sitenature in olefin polymerization. In our previous study, it was reported that MgCl2-supported titanocenecatalysts can generate both Ziegler-Natta-type ...
Toshiaki Taniike +2 more
doaj +1 more source
Análise de copolímeros de etileno alfa-olefinas por meio de técnicas de fracionamento [PDF]
Este trabalho apresenta a avaliação da heterogeneidade de resinas comerciais de copolímeros de etileno-1-buteno, produzidas por diferentes processos com catalisadores Ziegler-Natta e de resinas de copolímeros de etileno-1-hexeno sintetizadas em ...
Fernanda F. N. Escher +3 more
doaj +1 more source
Determination of kinetic parameters for ethylene polymerization (with and without hydrogen) by Ziegler-Natta catalyst. [PDF]
In this study, slurry polymerization kinetics of ethylene with TiCl4/Mg(OEt)2/AlR3 Ziegler-Natta catalysts in various conditions using the model of sum square error (SSE) (method I) and model of least square error (LSE) (Method II) was investigated.
Seyed Mehdi Ghafelebashi Zaranda +1 more
doaj +1 more source

