Determination of kinetic parameters for ethylene polymerization (with and without hydrogen) by Ziegler-Natta catalyst. [PDF]
Polyolefins Journal, 2020 In this study, slurry polymerization kinetics of ethylene with TiCl4/Mg(OEt)2/AlR3 Ziegler-Natta catalysts in various conditions using the model of sum square error (SSE) (method I) and model of least square error (LSE) (Method II) was investigated.
Seyed Mehdi Ghafelebashi Zaranda +1 more
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The charge percolation mechanism and simulation of Ziegler-Natta polymerizations, part VI: Mechanism of ethylene polymerization by supported chromium oxide [PDF]
Journal of the Serbian Chemical Society, 2007 Despite intensive research over the last 50 years, many questions concerning ethylene polymerization by supported chromium oxide are still unanswered. Hence, the very fundamental issues of this polymerization are discussed in this paper. It is shown that
Stoiljković Dragoslav +4 more
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A Study on the Effect of Catalyst Types on Microstructure of Ethylene/1-Hexene Copolymer by Thermal Fractionation [PDF]
علوم و تکنولوژی پلیمر, 2015 Olefinic copolymers of ethylene/1-hexene were synthesized by three main types of supported catalysts, including Philips, Ziegler-Natta and metallocene catalysts, and the specific microstructural features delivered by each class of the catalysts were ...
Seyed Mohammad Mehdi Mortazavi
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Transition Metal–(μ-Cl)–Aluminum Bonding in α-Olefin and Diene Chemistry
Molecules, 2022 Olefin and diene transformations, catalyzed by organoaluminum-activated metal complexes, are widely used in synthetic organic chemistry and form the basis of major petrochemical processes.
Ilya E. Nifant’ev +2 more
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Polietileno: principais tipos, propriedades e aplicações [PDF]
Polímeros, 2003 A estrutura de cada polímero tem influência direta sobre a sua densidade e suas propriedades mecânicas. Ramificações longas, como as presentes no polietileno de baixa densidade, por exemplo, aumentam a resistência ao impacto, diminuem a densidade e ...
Fernanda M. B. Coutinho +2 more
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A Mathematical Model for Investigating the Effect of Reaction Temperature and Hydrogen Amount on the Catalyst Yield during Propylene Polymerization [PDF]
Kemija u Industriji, 2019 In this study, the effect of reaction temperature and hydrogen amount, as the most effective process variables on the Ziegler-Natta catalysts yield during propylene polymerization, was investigated with the aid of a validated mathematical model.
Gholam Hossain Varshouee +3 more
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Addition of a second alcohol in magnesium ethoxide synthesis as a way to vary the pore architecture of Ziegler-Natta catalysts [PDF]
Polyolefins Journal, 2015 In Ziegler-Natta olefin polymerization, the pore architecture of catalysts plays a crucial role in catalytic performances and polymer properties. While the type of preparation routes (such as chemical reaction and solution precipitation) greatly affects ...
Toshiaki Funako +3 more
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Synthesis of Isotactic Polybutene-1 with Ziegler-Natta Catalyst [PDF]
علوم و تکنولوژی پلیمر, 2022 Hypothesis: Butene-1 is in excess in the polyolefin plants of Iran. Considering the properties of isotactic polybutene-1, including high creep and environmental stress cracking resistances, excellent elastic reversibility and good chemical abrasion ...
shokoufeh Hakim +2 more
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Preactive Site in Ziegler–Natta Catalysts [PDF]
The Journal of Physical Chemistry C, 2019 Ziegler–Natta catalysts are one of the most important industrial catalysts for the production of isotactic polypropylene, yet they are still not properly understood at the molecular level.
E. S. (Merijn) Blaakmeer +4 more
openaire +2 more sources
Immobilizing metallocene by solid polymethylaluminoxane “sMAO” for slurry-phase ethylene-1-hexene copolymerization [PDF]
MATEC Web of Conferences, 2022 In the field of olefin catalytic polymerization, metallocene catalysts show higher activity than traditional Ziegler-Natta catalysts. In this study, benzoic acid catalyzed the controlled hydrolysis of trimethylaluminum (TMA) to methylaluminoxane (MAO ...
Wu Chaofan +5 more
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