Surface compounds of transition metals. - Part XIII : Nature of the polymer to chromium bond in Phillips catalysts [PDF]
Two independent experiments show that in polymerization catalysts of the Phillips type the growing hydrocarbon chain is attached to the metal via a ...
Krauss, H. L., Schmidt, Helmut K.
core +2 more sources
Technology Strategies in the Knowldge Economy. The Licensing Activity of Himont [PDF]
The exchange of technologies and technological knowledge - through joint-ventures, partnerships, licensing, cross-licensing, R&D contracts - and the upsurge of markets for technology are main features of the "knowledge-based" economy.
Fabrizio Cesaroni
core
Carbon Dioxide, a Solvent and Synthon for Green Chemistry [PDF]
Carbon dioxide is a renewable resource of carbon when we consider the reuse of existing CO2 as a carbon source for producing chemicals. The development of new applications is of major interest from the point of view of carbon dioxide sequestration and ...
Ballivet-Tkatchenko, D +2 more
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The influence of magnesium dichloride as support on molecular weights of the polyethylenes produced by Ziegler-Natta catalyst [PDF]
The paper presents data on the effect exerted by magnesium dichloride in Ziegler-Natta catalysts on the activity and molecular weight of polyethylene (PE) produced by ethylene polymerization in the absence or presence of hydrogen.
Tatiana Mikenas +3 more
doaj +1 more source
Silicoaluminates as “support activator” systems in olefin polymerization processes [PDF]
In this work we report the polymerization behaviour of natural clays (montmorillonites, MMT) as activating supports. These materials have been modified by treatment with different aluminium compounds in order to obtain enriched aluminium clays and to ...
Alba Carranza, María Dolores +4 more
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Innovative catalytic systems driving sustainable olefin polymerization: Recent advances and green chemistry approaches [PDF]
This mini-review addresses the burgeoning requirements for environmentally friendly processes in the polymer industry, focusing on recent progress in developing catalytic systems for sustainable olefin polymerization.
Farabi Hossain, Md Enamul Hoque
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Carbon-hydrogen and carbon-carbon bond activation with highly electrophilic transition metal complexes [PDF]
Highly electron deficient scandocene derivatives of the types (η^5-C_5Me_5)_2ScR, {(η^5-C_5Me_4)_2SiMe_2}ScR and {(η^5-C_5H_3CMe_3)_2SiMe_2}ScR catalyze the polymerization of ethylene, the head-to-tail dimerization of α olefins, the cyclization of α,ω ...
Bercaw, John E.
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Effects Of Electron Beam Irradiation On The Mechanical Properties Of Ethylene Octene Copolymer, Polypropylene and Trimethylolpropane Triacrylate Blends [PDF]
The effect of electron beam irradiation on blends of ethylene-octene copolymer (EOC) and polypropylene (PP) with and without trimethylolpropane triacrylate (TMPTA) at various ratios was studied.
Raj Kumar, Harris C.
core
A Silicon-Bridged Bis(substituted Cp) Yttrium Complex [PDF]
rac-Bis(tetrahydrofuran)lithium [bis(2-trimethylsilyl-4-tert-butyl-η^5-cyclopentadienyl)dimethylsilane] dichloroyttrate, [Li(C_4H_80)_2][Y(C_(26)H_(48)-Si_3)Cl_2], M_r= 755.87, triclinic, Pl, ɑ = 13.110 (8), b = 17.163 (15), c = 20.623 (14) Å, ɑ= 104.02 (
Bercaw, John E. +3 more
core +1 more source
Ziegler–Natta Catalysts: Applications in Modern Polymer Science
Keshav Taruneshwar Jha +2 more
doaj +1 more source

