The coordination chemistry of benzimidazole ligands combines σ donation and π backbonding. Owing to this electronic flexibility, benzimidazole ligands stabilize both electron deficient and electron-rich transition states in the catalytic cycle of Ziegler-
Nelson N. dos Santos +4 more
doaj +1 more source
Control of a Fluidized Bed Polyethylene Reactor [PDF]
In present paper, dynamic behavior and control of a fluidized bed reactor for polyethylene production has been considered. A double active sites model for Ziegler-Natta catalysts is used for simulation of polymerization reaction. Hydrodynamic behavior of
Omid Vahidi +2 more
doaj
Nanocrystalline TiO2 and halloysite clay mineral composite films prepared by sol-gel method:Synergistic effect and the case of silver modification to the photocatalytic degradation of basic blue- 41 azo dye in water [PDF]
Tubular halloysite clay mineral and nanocrystalline TiO2 were incorporated in the preparation of nanocomposite films on glass substrates via sol-gel method at 450 °C.
Kaplani, E. +4 more
core
Influence of the Ethanol Content of Adduct on the Comonomer Incorporation of Related Ziegler-Natta Catalysts in Propylene (Co)polymerizations. [PDF]
Mehdizadeh M +10 more
europepmc +1 more source
Heterogeneity of Active Sites in the Polymer Chain Transfer Reactions at Olefin Polymerization over Multisite Supported Ziegler-Natta Catalysts. [PDF]
Matsko M, Zakharov V.
europepmc +1 more source
Neste trabalho foi utilizado um sistema catalítico composto por hidreto de diisobutilalumínio (DIBAH), versatato de neodímio (NdV) e um agente de cloração para avaliar a influência da fonte de cloro e da razão molar Cl:Nd nas características da reação de
Cintia N. Ferreira +2 more
doaj +1 more source
Synthesis of Early Transition Metal Bisphenolate Complexes and Their Use as Olefin Polymerization Catalysts [PDF]
Bisphenolate ligands with pyridine- and benzene-diyl linkers have been synthesized and metalated with group 4 and 5 transition metals. The solid-state structures of some of the group 4 complexes have been solved.
Bercaw, John E., Golisz, Suzanne R.
core +1 more source
A produção em larga escala de materiais poliméricos de elevado interesse industrial, provenientes da polimerização estereoespecífica de olefinas, tornou-se possível depois do advento dos catalisadores Ziegler-Natta.
Fabricio Machado, José Carlos Pinto
doaj
Synthesis of poly(sulfonate ester)s by ADMET polymerization [PDF]
Many hydrocarbon polymers containing heteroatom defects in the main chain have been investigated as degradable polyethylene-like materials, including aliphatic polyesters.
Balog, Sandor +3 more
core
Nobelova nagrada za kemiju 2006. [PDF]
Ovogodišnju Nobelovu nagradu za kemiju podijelila su trojica dobitnika: Francuz Yves Chauvin, Amerikanci Robert H. Grubbs i Richard R. Schrock. Prema obrazloÞenju Kraljevske švedske akademije znanosti, Nobelova nagrada dodijeljena im je za razvoj ...
L. Frkanec, T. Portada
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