Results 11 to 20 of about 2,167 (208)
Structural Characterization of Electron Donors in Ziegler-Natta Catalysts. [PDF]
J Phys Chem C Nanomater Interfaces, 2018 Ziegler-Natta catalysis is a very important industrial process for the production of polyolefins. However, the catalysts are not well-understood at the molecular level. Yet, atomic-scale structural information is of pivotal importance for rational catalyst development.
Blaakmeer ESM +5 more
europepmc +9 more sources
Preactive Site in Ziegler–Natta Catalysts [PDF]
The Journal of Physical Chemistry C, 2019 Ziegler–Natta catalysts are one of the most important industrial catalysts for the production of isotactic polypropylene, yet they are still not properly understood at the molecular level.
E. S. (Merijn) Blaakmeer +4 more
openaire +3 more sources
Ziegler–Natta Catalysts: Regioselectivity and “Hydrogen Response”
ACS Catalysis, 2019 Advanced High Throughput Experimentation (HTE) methods were applied to quantify the regioselectivity and the so-called “hydrogen response” in propene polymerization of four Ziegler–Natta catalysts ...
Vittoria A. +4 more
core +4 more sources
Synthesizing polypropylene with percolation network catalyzed by inorganic nanoparticles-functionalized Ziegler-Natta catalyst [PDF]
Polyolefins JournalPolypropylene is one of the most widely used synthetic resins, which is mainly synthesized with Ziegler-Natta catalysts. In this paper, the functionalized Ziegler-Natta catalyst is applied to prepare high-performance polypropylene.
Tingting Yang +3 more
doaj +2 more sources
Hecheng xiangjiao gongyeThe precursor MgCl2 · nROH of supported Ziegler Natta catalyst was prepared by chemical activation method, and different pre catalysts TiCl4/MgCl2 (C-Cat) were prepared by loading TiCl4.
FAN Xun-zhang, ZHAO Yuan-jin, LUO Shu-fang, HE Ai-hua?
doaj +2 more sources
Design of stereoselective Ziegler–Natta propene polymerization catalysts [PDF]
Proceedings of the National Academy of Sciences, 2006 After five decades of largely serendipitous (albeit formidable) progress, catalyst design in Ziegler–Natta olefin polymerization, i.e., the rational implementation of new active species to target predetermined polyolefin architectures, has ultimately become a realistic ambition, thanks to a much deeper fundamental understanding and major ...
BUSICO, VINCENZO +5 more
openaire +4 more sources
Sixtieth Anniversary of Ziegler-Natta Catalysts and Stereospecific Polymerization [PDF]
Kemija u Industriji, 2015 This review article highlights the history of the discoveries of organometallic catalysts and stereospecific polymerization of α-olefins, dienes and a number of vinyl monomers by Karl Ziegler and Giulio Natta sixty years ago, their developments and ...
Janović Z. , Veksli Z.
doaj +1 more source
Paramagnetic species in Ziegler Natta catalysts
, 2023 Abstract: This doctoral thesis investigates the nature and behavior of paramagnetic Ti(III) species in industrial Ziegler-Natta catalysts (ZNCs) used for the polymerization of polyethylene and polypropylene and is the result of a collaborative effort between the EPR laboratories of the University of Torino, the University of Antwerp and the Giulio ...
Podvorica, Leonora
openaire +3 more sources
Química Nova, 1997 The Ziegler-Natta catalyst and the polymerization thereof are systems which require careful handling and special treatment of chemicals. In spite of the use of inert atmosphere and dry chemicals, some Ziegler-Natta systems may present low activities or ...
Thaís H. S. Costa +4 more
doaj +2 more sources
A Study on the Effect of Catalyst Types on Microstructure of Ethylene/1-Hexene Copolymer by Thermal Fractionation [PDF]
علوم و تکنولوژی پلیمر, 2015 Olefinic copolymers of ethylene/1-hexene were synthesized by three main types of supported catalysts, including Philips, Ziegler-Natta and metallocene catalysts, and the specific microstructural features delivered by each class of the catalysts were ...
Seyed Mohammad Mehdi Mortazavi
doaj +1 more source