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Elimination of Zinc Dendrites by Graphene Oxide Electrolyte Additive for Zinc-Ion Batteries
ACS Applied Energy Materials, 2021Zinc-ion batteries have drawn tremendous attention in the electrochemical energy storage market because of their merits of high safety and low cost, however, the dendrites issue of zinc anodes rema...
Jin Cao, Dongdong Zhang, Xinyu Zhang
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Growth of zinc dendrites in acidic zinc chloride solutions
Electrochimica Acta, 1982Abstract The heights and widths of zinc dendrites were measured in pure zinc chloride solutions in the concentration and pH range prevailing in zinc-halogen load leveling batteries. At constant overpotential the height increases linearly with time, indicating a constant growth rate.
Y. Oren, U. Landau
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The Mechanism of the Dendritic Electrocrystallization of Zinc
Journal of The Electrochemical Society, 1969Measurements have been made of the growth rate of zinc dendrites in alkaline zincate solutions as a function of overpotential (η), concentration , and temperature . The tip radii have been measured by electron microscopy. At constant potential, an initiation time of between 5 and 100 min is observed, depending on η, c, and T.
J. W. Diggle +2 more
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Cooperativity in Chiroptical Sensing with Dendritic Zinc Porphyrins
Journal of the American Chemical Society, 2005Zinc porphyrin-appended dendrimers, 12PZn, 18PZn, 24PZn, and 36PZn, containing 12, 18, 24, and 36 zinc porphyrin units, respectively, were synthesized using zinc porphyrin dyad (2PZn) and triad (3PZn) as precursors. Although these dye-functionalized dendrimers all serve as chiroptical sensors for an asymmetric bipyridine (RR- and SS-Py2), the sensing ...
Wei-Shi, Li +3 more
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Interfacial Design of Dendrite‐Free Zinc Anodes for Aqueous Zinc‐Ion Batteries
Angewandte Chemie, 2020AbstractAqueous zinc‐ion batteries have rapidly developed recently as promising energy storage devices in large‐scale energy storage systems owing to their low cost and high safety. Research on suppressing zinc dendrite growth has meanwhile attracted widespread attention to improve the lifespan and reversibility of batteries. Herein, design methods for
Qi Zhang +4 more
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Review of zinc dendrite formation in zinc bromine redox flow battery
Renewable and Sustainable Energy Reviews, 2020Abstract The zinc bromine redox flow battery (ZBFB) is a promising battery technology because of its potentially lower cost, higher efficiency, and relatively long life-time. However, for large-scale applications the formation of zinc dendrites in ZBFB is of a major concern.
Xu, Zhicheng +5 more
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Dendrite Suppression Membranes for Rechargeable Zinc Batteries
ACS Applied Materials & Interfaces, 2018Aqueous batteries with zinc metal anodes are promising alternatives to Li-ion batteries for grid storage because of their abundance and benefits in cost, safety, and nontoxicity. However, short cyclability due to zinc dendrite growth remains a major obstacle.
Byoung-Sun Lee +8 more
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The critical overpotential for zinc dendrite formation
Journal of Applied Electrochemistry, 1979The critical overpotential for zinc dendrite growth is determined as 173 mV by the method described by Popovet al. [1]. It was shown that this procedure can be applied successfully to metal deposition processes when there is a large codeposition of hydrogen.
Popov, K. I. +3 more
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Additives for Suppressing Zinc Dendrites in Rechargeable Zinc Metal Batteries
ECS Meeting Abstracts, 2015Rechargeable zinc-based battery systems hold great promise for future energy storage devices due to their low cost and high theoretical energy density.1 However, the development of portable or stationary rechargeable zinc batteries has been hindered by several critical issues.
Stephen J Banik, Rohan Akolkar
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Revealing the Two‐Dimensional Surface Diffusion Mechanism for Zinc Dendrite Formation on Zinc Anode
Small, 2021AbstractAqueous zinc‐ion battery is regarded as one of the promising devices for large‐scale energy storage systems owing to its high safety, cost‐effectiveness, and competitive electrochemical properties. However, the dendrite growth on zinc metal anodes dramatically hinders its further practical applications, and the internal mechanism of dendrite ...
Zefang Yang +7 more
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