Synthesis, Characterisation, Crystal Structure, DFT, and Hirshfeld Surface Study of a Slightly Distorted Tetrahedral Zn(II) Complex Based on Triphenylphosphanol [PDF]
An intriguing novel complex, [ZnCl2(Ph3POH)2], containing two equivalents of triphenylphosphanol (Ph3POH), was synthesized by reacting anhydrous ZnCl2 with triphenylphosphine in methanol, yielding a dichlorobis(triphenylphosphanol)-zinc(II) complex with ...
Karwan Ali, Nabil Fakhre, Salim Saber
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The Zn(II)-pyrazinamide complex compound is currently being developed as an antibacterial agent. To obtain the Zn(II)-pyrazinamide complex effectively, many factors must be considered, including the type of zinc(II) salt and the mole ratio.
Naila Azmi Adiba +2 more
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Cobalt(II), Nickel(II), copper(II) and zinc(II) complexes of thiazolidine
AbstractThe reactions of thiazolidine with anhydrous metal halides of Co (II), Cu(II), Zn(II) and NiCl2.6H2O were studied in ethanolic solutions. Complexes of the type MLX2 (M=Ni (II), X=Cl, M=Cu (II), X=Cl, Br), ML2X2 (M=Co(II), X=Cl, Br, M=Cu(II), X=Cl, M=Zn(II), X=Cl), ML3X2 (M=Ni(II), X=Br, M=Co(II), X=Br) were isolated and characterized from these
Louloudi, M. +2 more
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Voltammetric Investigations of 2,2'-Azobispyridine Zinc(II) and Nickel(II) Complexes
The electrochemical behaviour of 2,2'-Azobispyridine (abpy) has been studied by using voltammetric techniques. From obtained data, electrochemical reaction mechanism of the azo compound has been suggested. At the same time, zinc(II) and nickel(II) complexes of the azo compound have been investigated in different solution media.
Karaman Y. +3 more
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Crystal structures of zinc(II) coordination complexes with isoquinoline N-oxide
The reaction of one equivalent of zinc(II) halide salts with two equivalents of isoquinoline N-oxide (iQNO; C9H7NO) in methanol yields compounds of the general formula [ZnX2(iQNO)2], with X = Cl− (I), Br− (II) and I− (III). However, starting with zinc(II)
Erin N. Groneck +3 more
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(4′-Chloro-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)bis(nitrato-κO)zinc(II)
In the title complex, [Zn(C15H10ClN3)(NO3)2], the central zinc(II) atom is pentacoordinated by two O-bonded nitrate ions and three N atoms of the 4′-chloro-2,2′:6′,2′′-terpyridine ligand in a slightly distorted trigonal–bipyramidal shape.
Rafael A. Adrian +2 more
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Synthesis and spectral characterization of 1,2-bis(5-methyl/chloro-1H-benzimidazol-2-yl)ethanols and their Co(II), Pd(II) and Zn(II) complexes [PDF]
1,2-Bis(5-methyl/chloro-1H-benzimidazol-2-yl)ethanols (1 and 2), asymmetric bis-benzimidazoles, and their complexes with CoCl2, PdCl2 and ZnCl2 were synthesized and characterized by elemental analysis, molar conductivity, magnetic moment, TGA, FT-IR (mid-
Tavman Aydin, Gurbuz Demet, Cinarli Adem
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Zinc(II) oxide (ZnO) nanoparticles were easily produced in this research by thermal decomposition of the Zn(II) Schiff base complex. The ligand was synthesized via condensation of benzylamine with 2-hydroxybenzaldehyde. The Zn(II) Schiff base complex was
Hadeer Mohammed Subhi +2 more
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Protein pyrophosphorylation by inositol pyrophosphates — detection, function, and regulation
Protein pyrophosphorylation is an unusual signaling mechanism that was discovered two decades ago. It can be driven by inositol pyrophosphate messengers and influences various cellular processes. Herein, we summarize the research progress and challenges of this field, covering pathways found to be regulated by this posttranslational modification as ...
Sarah Lampe +3 more
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Synthesis and Structure of bis(Dibutyldithiocarbamate)zinc(II): Zn2[(n-Bu)2NCSS]4
The binuclear zinc (II) complex Zn2[(n-Bu)2NCSS]4 has been prepared, and its crystal and molecular structure have been determined by x-ray diffraction.
Kaibei Yu +4 more
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