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Confinement of Zinc Salt in Ultrathin Heterogeneous Film to Stabilize Zinc Metal Anode
Small, 2021AbstractAqueous zinc metal batteries (AZMBs) have drawn great attention due to the high theoretical capacity, low redox potential, and abundance reserves. However, the practical application of rechargeable AZMBs are hindered by the poor reversibility of Zn metal anode, owing to easy dendrite growth and serious side reactions. Herein, the preparation of
Junya Cui +4 more
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Angewandte Chemie International Edition, 2023
AbstractCrystallography modulation of zinc (Zn) metal anode is promising to promote Zn reversibility in aqueous electrolytes, but efficiently constructing Zn with specific crystallographic texture remains challenging. Herein, we report a current‐controlled electrodeposition strategy to texture the Zn electrodeposits in conventional aqueous electrolytes.
Wentao Yuan +6 more
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AbstractCrystallography modulation of zinc (Zn) metal anode is promising to promote Zn reversibility in aqueous electrolytes, but efficiently constructing Zn with specific crystallographic texture remains challenging. Herein, we report a current‐controlled electrodeposition strategy to texture the Zn electrodeposits in conventional aqueous electrolytes.
Wentao Yuan +6 more
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Monolayer Thiol Engineered Covalent Interface toward Stable Zinc Metal Anode
ACS Nano, 2022Interface engineering of zinc metal anodes is a promising remedy to relieve their inferior stability caused by dendrite growth and side reactions. Nevertheless, the low affinity and additional weight of the protective coating remain obstacles to their further implementation.
Shiqiang Wei +14 more
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Tailoring desolvation kinetics enables stable zinc metal anodes
Journal of Materials Chemistry A, 2020The solvation structure of Zn2+ is regulated through incorporating acetonitrile (AN) into the electrolyte, elevating nucleation sites and stablizing zinc metal anode, as revealed by the complementary theoretical and experimental studies.
Zhen Hou +5 more
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Surface Engineering on Zinc Anode for Aqueous Zinc Metal Batteries
ChemSusChemAbstractRechargeable aqueous zinc metal batteries (AZMBs) are considered as a potential alternative to lithium‐ion batteries due to their low cost, high safety, and environmental friendliness. However, the Zn anodes in AZMBs face severe challenges, such as dendrite growth, metal corrosion, and hydrogen evolution, all of which are closely related to the
Huili Peng +5 more
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Bulk‐Phase Reconstruction Enables Robust Zinc Metal Anodes for Aqueous Zinc‐Ion Batteries
Angewandte Chemie, 2023AbstractAqueous zinc‐ion batteries are inherently safe, but the severe dendrite growth and corrosion reaction on zinc anodes greatly hinder their practical applications. Most of the strategies for zinc anode modification refer to the research of lithium metal anodes on surface regulation without considering the intrinsic mechanisms of zinc anode ...
Zefang Yang +8 more
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Inorganic Hybrid Interfacial Layer for a Stable Zinc Metal Anode
ACS Applied Materials & Interfaces, 2023In aqueous zinc-ion batteries (AZIBs), the zinc metal anode faces serious problems such as dendrite growth, interface corrosion, and byproduct accumulation, which hinder the commercialization process of AZIBs. Herein, an inorganic hybrid interfacial layer ZnF2/ZnSe (ZnFS) including the insulating interfacial phase (ZnF2) and conductive interfacial ...
Zhenhua Hou +3 more
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Oriented Metal Stripping for Highly Reversible Zinc Anode
SmallAbstractAqueous zinc metal batteries are a viable candidate for next‐generation energy storage systems, but suffer from poor cycling efficiency of the Zn anode. Emerging approaches aim to regulate zinc plating behavior to suppress uncontrolled dendrites, while the stripping process is seldom considered.
Shimeng Zhang +5 more
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Achieving highly reversible zinc metal anode via surface termination chemistry
Science Bulletin, 2023An oxidation layer on a Zn surface is considered to play a negative role in hindering the practical applications of aqueous zinc ion batteries (AZBs). Herein, we demonstrate the importance of Zn-surface termination on the overall electrochemical behavior of AZBs by revisiting the well-known bottleneck issues.
Yu, Liu +11 more
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Metallic Particles‐Induced Surface Reconstruction Enabling Highly Durable Zinc Metal Anode
Advanced Functional Materials, 2023AbstractAqueous zinc batteries usher in a renaissance due to their intrinsic security and cost effectiveness, bespeaking vast application foreground for large‐scale energy storage system. However, uncontrolled dendrite growth along with hydrogen evolution severely restricts its reversibility and stability for practical application.
Wen Liu +10 more
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