Results 261 to 270 of about 61,470 (293)
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The Systems Zirconia‐Lanthana and Zirconia‐Neodymia
Journal of the American Ceramic Society, 1955The minimum amounts of lanthana and neodymia required to stabilize zirconia into a cubic form are 30 and 20 mole %, respectively, at 980°C. X‐ray diffraction studies have established the upper limit of the two cubic solid solution regions as approximately 40 mole %.
Frank H. Brown, Pol Duwez
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Stability of cubic zirconia and of stoichiometric zirconia nanoparticles
Physics of the Solid State, 2006Using the electron density functional method, it is shown that the oxygen sublattice of cubic zirconia is unstable with respect to random displacements of oxygen atoms, which results in general instability of bulk cubic zirconia at low temperatures.
V. G. Zavodinsky, A. N. Chibisov
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Nature of hydrous zirconia and sulfated hydrous zirconia
Catalysis Today, 1994Abstract The structure of crystalline hydrous zirconias and their methods of formation are described. A mechanism for the hydrolytic polymerization of Zr IV to obtain the several forms of hydrous oxide is presented. The method by which sulfate ion binds to the surface of zirconia particles is explored.
G.P.D. Serrette+2 more
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State of platinum in zirconia and sulfated zirconia catalysts
Catalysis Letters, 1996Platinum is present in a metallic state following activation in air at 725‡C of both 5 wt% Pt/ZrO2 and 5 wt% Pt/SO 4 2− /ZrO2. Reduction of either catalyst at 725‡C produces a Pt-Zr alloy, and these reduced catalysts, upon recalcination in air at 725‡C, form metallic Pt crystallites.
Dennis E. Sparks+2 more
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ZrO2 can be nitrided partially by nitrogen at temperatures >1400°C. It is possible to describe all the synthesized phases with the general formula ZrO2‐2χN4χ/3 (system ZrO2‐Zr3N4). Parameters–such as nitridation time, temperature, nitrogen pressure, and particle size–have a strong effect on the amount of incorporated nitrogen.
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Effects of zirconia phase on the synthesis of higher alcohols over zirconia and modified zirconia
Journal of Molecular Catalysis A: Chemical, 2004The catalytic performances of ZrO2-based catalysts were evaluated for the synthesis of higher alcohols from synthesis gas. The crystal phase structures were characterized by X-ray diffraction (XRD) and UV Raman. The results indicated that ZrO2 and Pd modified ZrO2 catalysts were effective catalysts in the synthesis of ethanol or isobutanol, and their ...
Can Li+3 more
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Anodic Polarization Related to the Ionic Conductivity of Zirconia at Ni-Zirconia/Zirconia Electrodes
Journal of The Electrochemical Society, 2001To clarify the extension of the triple phase boundary (TPB), which directly affects the electrode polarization behavior, in the cermet layer of the Ni zirconia anode, we studied the anodic polarization properties of four types of Ni-zirconia cermets (Ni-0YZC Ni-3YZC, and Ni-8YZC) on three types of zirconia electrolytes (3YZE, 5YZE, and 8YZE).
Nobuyoshi Nakagawa+2 more
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Creep behaviour of alumina, zirconia and zirconia-toughened alumina
Journal of the European Ceramic Society, 1997no ...
Chevalier, Jérome+3 more
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Refractories, 1995
Phenomenological equations are suggested for describing the processes of disordering in electron and ion subsystems. Dependences of the concentration of point defects on the partial pressure of oxygen for each kind of defect are obtained in the course of the solution of the equations of defect formation due to the Schottky, Frenkel, and anti-Frenkel ...
V. E. Shvaiko-Shvaikovskii+2 more
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Phenomenological equations are suggested for describing the processes of disordering in electron and ion subsystems. Dependences of the concentration of point defects on the partial pressure of oxygen for each kind of defect are obtained in the course of the solution of the equations of defect formation due to the Schottky, Frenkel, and anti-Frenkel ...
V. E. Shvaiko-Shvaikovskii+2 more
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